GB1099065A - New nitrogen-containing polymers and process of preparation - Google Patents
New nitrogen-containing polymers and process of preparationInfo
- Publication number
- GB1099065A GB1099065A GB28100/66A GB2810066A GB1099065A GB 1099065 A GB1099065 A GB 1099065A GB 28100/66 A GB28100/66 A GB 28100/66A GB 2810066 A GB2810066 A GB 2810066A GB 1099065 A GB1099065 A GB 1099065A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- hydroxyethyl
- formula
- polymers
- hydrocarbon radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0633—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0627—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyamides (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
The invention comprises polymers of formula <FORM:1099065/C3/1> where R is an aliphatic hydrocarbon radical containing at least 3 carbon atoms or an aromatic or cycloaliphatic hydrocarbon radical and n is an integer. The polymers are obtained by polycondensation of N,N1-bis-b -hydroxyethyl diamines of formula HO.CH2.CH2.NH.R.NH. -CH2.CH2.OH by heating in an inert atmosphere at above 250 DEG C. The starting material may be heated with a catalyst, e.g. orthophosphoric acid, pyrophosphoric acid, iodine, aluminium chloride or boron phosphate. Low molecular weight polymers may be obtained and may be converted to higher molecular weight products by further heating, e.g. at above 300 DEG C., and under reduced pressure, e.g. at below 0.5 mm. Hg. In examples polymers are obtained from N,N1 - bis - (b - hydroxyethyl) - dodecamethylene diamine, from N,N1-bis(b -hydroxyethyl)-m-phenylene diamine, from N,N1-bis-(b -hydroxyethyl)-1, 4-diaminocyclohexane, and from N,N1-bis-(b -hydroxyethyl) hexamethylenediamine.ALSO:The invention comprises compounds of formula <FORM:1099065/C2/1> where R is an aliphatic hydrocarbon radical containing at least 3 carbon atoms or an aromatic or cycloaliphatic hydrocarbon radical and n is an integer. The compounds are obtained by polycondensation of N,N1-bis-b -hydroxyethyl diamines of formula HO.CH2.CH2.NH.R.NH.CH2.CH2.OH by heating in an inert atmosphere at above 250 DEG C. The starting material may be heated with a catalyst, e.g. orthophosphoric acid, pyrophosphoric acid, iodine, aluminium chloride or boron phosphate. The compounds may be converted to higher molecular weight products by further heating, e.g. at above 300 DEG C., and under reduced pressure, e.g. at below 0.5 mm. Hg. In examples compounds are obtained from N,N1 - bis - (b - hydroxyethyl) - dodecamethylene diamine, from N,N1-bis-(b -hydroxyethyl)-m -phenylene diamine, from N,N1 - bis - (b - hydroxyethyl) - 1,4 - diaminocyclohexane, and from N,N1-bis-(b -hydroxyethyl) hexamethylenediamine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR22146A FR1448914A (en) | 1965-06-24 | 1965-06-24 | New nitrogenous polymers and method of preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1099065A true GB1099065A (en) | 1968-01-10 |
Family
ID=8582992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28100/66A Expired GB1099065A (en) | 1965-06-24 | 1966-06-23 | New nitrogen-containing polymers and process of preparation |
Country Status (8)
Country | Link |
---|---|
US (1) | US3532646A (en) |
BE (1) | BE683034A (en) |
CH (1) | CH456954A (en) |
DE (1) | DE1645361A1 (en) |
FR (1) | FR1448914A (en) |
GB (1) | GB1099065A (en) |
LU (1) | LU51381A1 (en) |
NL (2) | NL6608398A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4404362A (en) * | 1981-12-14 | 1983-09-13 | Petrolite Corporation | Block polymers of alkanolamines |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5218708B2 (en) * | 1972-09-13 | 1977-05-24 | ||
US4368137A (en) * | 1981-05-18 | 1983-01-11 | Petrolite Corporation | Polymers of oxyalkylated piperazines and uses thereof |
JPS61204224A (en) * | 1985-03-08 | 1986-09-10 | Sumitomo Electric Ind Ltd | Functional elastomer |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2639284A (en) * | 1953-05-19 | Process of preparing monomethyl | ||
NL293147A (en) * | 1962-05-24 | 1900-01-01 | ||
US3165482A (en) * | 1962-07-13 | 1965-01-12 | Du Pont | Polymers from n-hetero-bicyclo alkanes and process for producing same |
US3207707A (en) * | 1963-04-29 | 1965-09-21 | Gen Electric | Nitrogen containing polymers |
US3370048A (en) * | 1965-03-15 | 1968-02-20 | Eastman Kodak Co | Process for the preparation of new linear condensation polymers |
-
0
- NL NL127436D patent/NL127436C/xx active
-
1965
- 1965-06-24 FR FR22146A patent/FR1448914A/en not_active Expired
-
1966
- 1966-06-16 NL NL6608398A patent/NL6608398A/xx unknown
- 1966-06-22 LU LU51381A patent/LU51381A1/xx unknown
- 1966-06-23 GB GB28100/66A patent/GB1099065A/en not_active Expired
- 1966-06-23 BE BE683034D patent/BE683034A/xx unknown
- 1966-06-24 DE DE19661645361 patent/DE1645361A1/en active Pending
- 1966-06-24 CH CH917266A patent/CH456954A/en unknown
-
1969
- 1969-02-17 US US805096*A patent/US3532646A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4404362A (en) * | 1981-12-14 | 1983-09-13 | Petrolite Corporation | Block polymers of alkanolamines |
Also Published As
Publication number | Publication date |
---|---|
DE1645361A1 (en) | 1970-09-24 |
LU51381A1 (en) | 1966-08-22 |
US3532646A (en) | 1970-10-06 |
FR1448914A (en) | 1966-08-12 |
NL6608398A (en) | 1966-12-27 |
CH456954A (en) | 1968-05-31 |
NL127436C (en) | |
BE683034A (en) | 1966-12-23 |
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