GB1095663A - Polyesterimide resins - Google Patents
Polyesterimide resinsInfo
- Publication number
- GB1095663A GB1095663A GB2412665A GB2412665A GB1095663A GB 1095663 A GB1095663 A GB 1095663A GB 2412665 A GB2412665 A GB 2412665A GB 2412665 A GB2412665 A GB 2412665A GB 1095663 A GB1095663 A GB 1095663A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycol
- ethylene glycol
- surplus
- excess
- polycondensation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
- H01B3/306—Polyimides or polyesterimides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/16—Polyester-imides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/307—Other macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Thermosetting polyesterimides are prepared by interacting (a) a polybasic carboxylic acid having at least 3 carboxyl groups attached to an aromatic ring or a reactive derivative thereof, (b) a C2- 6 glycol and (c) a poly-primary amine or reactive derivative thereof in the presence of a surplus of the glycol at least part of the surplus being separated by distillation after polycondensation. Polybasic carboxylic acids specified are trimellitic, and pyromellitic. Terephthalic acid may also be present. Pentaerythritol is specified as a polyhydric alcohol. The polyvalent primary amine may be aromatic, e.g. 4,41-diamino-diphenylmethane. Glycols specified are ethylene glycol, propane-1,2 and 1,3-diols, butylene glycol and diethylene glycol. The reactants (a) to (c) may be used in an at least 20% solution in the glycol to give at least 1 mole surplus of glycol for every ester link in the product. The polymerization may be carried out in the presence of hydroxycarboxylic acids, aminocarboxylic acids, amino-alcohols, polyvalent primary amines containing secondary amino-groups and catalysts, e.g. tin oxalate, Sb2O3 or a titanium compound. A fractionating column may be used to ensure that water only is distilled from the system during polycondensation, the glycol being removed afterwards. In the latter case a reduced pressure may be used. Between removal of the water and removal of the glycol a mixture of pigments, e.g. TiO2, Fe2O3, talcum mica, a consolidating agent, e.g. silica gel or dimethyl di-octa-decyl ammonium montmorillonite and a glycol may be added. The product of the reaction is soluble in cresol/xylol/ aromatic hydrocarbon mixtures. It may be used for coating, e.g. wire insulation, mouldings, laminates, films, foils, spin sintering and flame-spraying. The condensed ethylene glycol may be reused as starting material. In Example (3), a condensate of aniline and formaldehyde in the presence of HCl functions both as a polyamine and as a polyhydric alcohol.ALSO:A polyesterimide useful for coating is prepared by reacting a polybasic carboxylic acid having at least 3 carboxyl groups joined to a benzene ring with a C2-6 glycol and a poly-primary amine, the glycol being present in excess and some of the excess being distilled off after polycondensation. The resin may be applied to electrical copper wiring, or woven fibres in solution or by flame spraying or spin sintered spraying. The resin may be hardened at 180 - 200 DEG C. In Examples: (1) a polymer derived from terephthalic acid, pentaerythritol, ethylene glycol, diaminodiphenylmethane and trimellitic anhydride in the presence of tin oxalate and Sb2O3 is applied to metal sheet; (2) the polymer of Example 1 dissolved in a mixture of cresol, xylol and naphtha is applied to copper wire; (3) a condensate of an aniline/formaldehyde resin, ethylene glycol and trimellitic anhydride dissolved in cycolhexane, DMF, DMA and furfuryl alcohol is used to impregnate electrical windings and (4) a polymer of trimellitic anhydride, ethylene glycol and diaminodiphenylmethane dissolved in excess ethylene glycol is also used to impregnate electrical windings.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1964B0077166 DE1495182C3 (en) | 1964-06-09 | 1964-06-09 | Use of thermosetting polyesterimide resins for solvent-free processing |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1095663A true GB1095663A (en) | 1967-12-20 |
Family
ID=6979354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2412665A Expired GB1095663A (en) | 1964-06-09 | 1965-06-08 | Polyesterimide resins |
Country Status (6)
Country | Link |
---|---|
AT (2) | AT283548B (en) |
DE (1) | DE1495182C3 (en) |
DK (1) | DK121629B (en) |
FR (1) | FR1436978A (en) |
GB (1) | GB1095663A (en) |
SE (1) | SE338164B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4650839A (en) * | 1986-01-23 | 1987-03-17 | Allied Corporation | Thermosettable modified phenolic imide resins |
US4757118A (en) * | 1986-01-23 | 1988-07-12 | Allied Corporation | Thermosettable modified phenolic polyester imide resins |
US4771113A (en) * | 1986-01-23 | 1988-09-13 | Allied Corporation | Thermosettable modified phenolic polyester imide resins |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3880812A (en) * | 1974-01-11 | 1975-04-29 | Standard Oil Co | Poly(alkylenetrimellitate imides) and method of preparation |
DE2522386C3 (en) * | 1975-05-21 | 1984-09-27 | Chemische Fabrik Dr.Wiedeking, 4152 Kempen | Electrical insulating varnish |
AT349113B (en) * | 1976-03-25 | 1979-03-26 | Herberts & Co Gmbh | PROCESS FOR MANUFACTURING HIGH HEAT-RESISTANT INSULATING COVERINGS ON ELECTRIC LADDERS AND MEANS FOR CARRYING OUT THE PROCESS |
DE3121306A1 (en) * | 1981-05-29 | 1982-12-23 | Dr. Beck & Co Ag, 2000 Hamburg | METHOD FOR PRODUCING AQUEOUS HEAT-CURABLE ELECTRO-INSULATING LACQUER AND THE USE THEREOF |
DE102011052518A1 (en) * | 2011-08-09 | 2013-02-14 | Elantas Gmbh | Solvent-free wire enamel composition |
-
1964
- 1964-06-09 DE DE1964B0077166 patent/DE1495182C3/en not_active Expired
-
1965
- 1965-05-07 AT AT04973/67A patent/AT283548B/en not_active IP Right Cessation
- 1965-05-07 AT AT418265A patent/AT267186B/en active
- 1965-06-02 DK DK278465A patent/DK121629B/en unknown
- 1965-06-02 FR FR19262A patent/FR1436978A/en not_active Expired
- 1965-06-08 SE SE747565A patent/SE338164B/xx unknown
- 1965-06-08 GB GB2412665A patent/GB1095663A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4650839A (en) * | 1986-01-23 | 1987-03-17 | Allied Corporation | Thermosettable modified phenolic imide resins |
US4757118A (en) * | 1986-01-23 | 1988-07-12 | Allied Corporation | Thermosettable modified phenolic polyester imide resins |
US4771113A (en) * | 1986-01-23 | 1988-09-13 | Allied Corporation | Thermosettable modified phenolic polyester imide resins |
Also Published As
Publication number | Publication date |
---|---|
FR1436978A (en) | 1966-04-29 |
DE1495182B2 (en) | 1976-12-02 |
DK121629B (en) | 1971-11-08 |
SE338164B (en) | 1971-08-30 |
AT267186B (en) | 1968-12-10 |
AT283548B (en) | 1970-08-10 |
DE1495182A1 (en) | 1969-08-28 |
DE1495182C3 (en) | 1978-03-09 |
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