GB1094723A - Flame-retardant resin materials and new halogen-containing flame-retardant esters - Google Patents

Flame-retardant resin materials and new halogen-containing flame-retardant esters

Info

Publication number
GB1094723A
GB1094723A GB507165A GB507165A GB1094723A GB 1094723 A GB1094723 A GB 1094723A GB 507165 A GB507165 A GB 507165A GB 507165 A GB507165 A GB 507165A GB 1094723 A GB1094723 A GB 1094723A
Authority
GB
United Kingdom
Prior art keywords
flame
retardant
dibromopropyl
halogen
allyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB507165A
Inventor
Joseph Patrick Brown
Francis John Whitby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Original Assignee
Monsanto Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Chemicals Ltd filed Critical Monsanto Chemicals Ltd
Priority to GB507165A priority Critical patent/GB1094723A/en
Publication of GB1094723A publication Critical patent/GB1094723A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/11Esters; Ether-esters of acyclic polycarboxylic acids

Abstract

A normally inflammable synthetic resin is compounded with a flame-retardant which is a halogen-containing ester of an ethylenically unsaturated dicarboxylic acid wherein one or both carboxylic groups are esterified. The resin may be polystyrene which may be dissolved in chloroform together with the flame-retardant e.g. bis(2, 3-dibromopropyl) 2,3-dibromofumarate or bis (2,3-dibromopropyl) maleate.ALSO:An ester having the formula ROOC.CX=CX.COOR1 where X is a halogen, e.g. bromine, R is a 2, 3-dihalopropyl, e.g. dibromopropyl, group and R1 is R or H is claimed and may be produced by the addition of halogen to the allyl group(s) in an allyl ester of formula R2OOC.CX=CX.COOR3 where X is a halogen, R2 is an allyl group and R3 is R2 or H. In examples: (1) allyl alcohol is reacted with dibromomaleic anhydride to form allyl hydrogen 2,3-dibromomaleate which is then treated with bromine to form 2,3-dibromopropyl hydrogen 2,3-dibromomaleate; and (2) allyl alcohol is reacted with dibromomaleic anhydride to form diallyl 2,3-dibromofumarate which is then treated with bromine to form bis-(2,3-dibromopropyl) 2,3-dibromofumarate.
GB507165A 1965-02-05 1965-02-05 Flame-retardant resin materials and new halogen-containing flame-retardant esters Expired GB1094723A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB507165A GB1094723A (en) 1965-02-05 1965-02-05 Flame-retardant resin materials and new halogen-containing flame-retardant esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB507165A GB1094723A (en) 1965-02-05 1965-02-05 Flame-retardant resin materials and new halogen-containing flame-retardant esters

Publications (1)

Publication Number Publication Date
GB1094723A true GB1094723A (en) 1967-12-13

Family

ID=9789215

Family Applications (1)

Application Number Title Priority Date Filing Date
GB507165A Expired GB1094723A (en) 1965-02-05 1965-02-05 Flame-retardant resin materials and new halogen-containing flame-retardant esters

Country Status (1)

Country Link
GB (1) GB1094723A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932181A (en) 1971-08-04 1976-01-13 National Starch And Chemical Corporation Electrophotographic coating compositions having bromine-containing polymer binders
US4113689A (en) 1973-04-24 1978-09-12 Montedison S.P.A. Halogenated esters of polycarboxylic acids and plasticizers for chloro-vinyl polymers based on said esters
US4473371A (en) * 1981-09-04 1984-09-25 Hoechst Aktiengesellschaft Perfluoroalkyl esters, a process for their preparation and their use as a soil-repellant agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932181A (en) 1971-08-04 1976-01-13 National Starch And Chemical Corporation Electrophotographic coating compositions having bromine-containing polymer binders
US4113689A (en) 1973-04-24 1978-09-12 Montedison S.P.A. Halogenated esters of polycarboxylic acids and plasticizers for chloro-vinyl polymers based on said esters
US4473371A (en) * 1981-09-04 1984-09-25 Hoechst Aktiengesellschaft Perfluoroalkyl esters, a process for their preparation and their use as a soil-repellant agent

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