GB1094723A - Flame-retardant resin materials and new halogen-containing flame-retardant esters - Google Patents
Flame-retardant resin materials and new halogen-containing flame-retardant estersInfo
- Publication number
- GB1094723A GB1094723A GB507165A GB507165A GB1094723A GB 1094723 A GB1094723 A GB 1094723A GB 507165 A GB507165 A GB 507165A GB 507165 A GB507165 A GB 507165A GB 1094723 A GB1094723 A GB 1094723A
- Authority
- GB
- United Kingdom
- Prior art keywords
- flame
- retardant
- dibromopropyl
- halogen
- allyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
Abstract
A normally inflammable synthetic resin is compounded with a flame-retardant which is a halogen-containing ester of an ethylenically unsaturated dicarboxylic acid wherein one or both carboxylic groups are esterified. The resin may be polystyrene which may be dissolved in chloroform together with the flame-retardant e.g. bis(2, 3-dibromopropyl) 2,3-dibromofumarate or bis (2,3-dibromopropyl) maleate.ALSO:An ester having the formula ROOC.CX=CX.COOR1 where X is a halogen, e.g. bromine, R is a 2, 3-dihalopropyl, e.g. dibromopropyl, group and R1 is R or H is claimed and may be produced by the addition of halogen to the allyl group(s) in an allyl ester of formula R2OOC.CX=CX.COOR3 where X is a halogen, R2 is an allyl group and R3 is R2 or H. In examples: (1) allyl alcohol is reacted with dibromomaleic anhydride to form allyl hydrogen 2,3-dibromomaleate which is then treated with bromine to form 2,3-dibromopropyl hydrogen 2,3-dibromomaleate; and (2) allyl alcohol is reacted with dibromomaleic anhydride to form diallyl 2,3-dibromofumarate which is then treated with bromine to form bis-(2,3-dibromopropyl) 2,3-dibromofumarate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB507165A GB1094723A (en) | 1965-02-05 | 1965-02-05 | Flame-retardant resin materials and new halogen-containing flame-retardant esters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB507165A GB1094723A (en) | 1965-02-05 | 1965-02-05 | Flame-retardant resin materials and new halogen-containing flame-retardant esters |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1094723A true GB1094723A (en) | 1967-12-13 |
Family
ID=9789215
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB507165A Expired GB1094723A (en) | 1965-02-05 | 1965-02-05 | Flame-retardant resin materials and new halogen-containing flame-retardant esters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1094723A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3932181A (en) | 1971-08-04 | 1976-01-13 | National Starch And Chemical Corporation | Electrophotographic coating compositions having bromine-containing polymer binders |
US4113689A (en) | 1973-04-24 | 1978-09-12 | Montedison S.P.A. | Halogenated esters of polycarboxylic acids and plasticizers for chloro-vinyl polymers based on said esters |
US4473371A (en) * | 1981-09-04 | 1984-09-25 | Hoechst Aktiengesellschaft | Perfluoroalkyl esters, a process for their preparation and their use as a soil-repellant agent |
-
1965
- 1965-02-05 GB GB507165A patent/GB1094723A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3932181A (en) | 1971-08-04 | 1976-01-13 | National Starch And Chemical Corporation | Electrophotographic coating compositions having bromine-containing polymer binders |
US4113689A (en) | 1973-04-24 | 1978-09-12 | Montedison S.P.A. | Halogenated esters of polycarboxylic acids and plasticizers for chloro-vinyl polymers based on said esters |
US4473371A (en) * | 1981-09-04 | 1984-09-25 | Hoechst Aktiengesellschaft | Perfluoroalkyl esters, a process for their preparation and their use as a soil-repellant agent |
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