GB1091525A - New titanium compounds and compositions containing them - Google Patents
New titanium compounds and compositions containing themInfo
- Publication number
- GB1091525A GB1091525A GB26803/63A GB2680363A GB1091525A GB 1091525 A GB1091525 A GB 1091525A GB 26803/63 A GB26803/63 A GB 26803/63A GB 2680363 A GB2680363 A GB 2680363A GB 1091525 A GB1091525 A GB 1091525A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anhydride
- wax
- formula
- titanium compound
- residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 10
- 150000003609 titanium compounds Chemical class 0.000 title abstract 7
- 150000008064 anhydrides Chemical class 0.000 abstract 9
- 239000002904 solvent Substances 0.000 abstract 6
- 239000001993 wax Substances 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 4
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 239000012188 paraffin wax Substances 0.000 abstract 3
- 239000005871 repellent Substances 0.000 abstract 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000011449 brick Substances 0.000 abstract 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- -1 masonry Substances 0.000 abstract 1
- 238000000643 oven drying Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 238000009877 rendering Methods 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0004—Coated particulate pigments or dyes
- C09B67/0008—Coated particulate pigments or dyes with organic coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Liquid coating compositions for rendering paper, and like sheet material, masonry, concrete and brick water-repellent comprise a wax and at least one compound of the formula <FORM:1091525/C4-C5/1> where x is 2 and y is 2 or x is 3 and y is 1 and wherein R represents a substituted or unsubstituted alkyl radical and R1 represents the residue of a carboxylic anhydride R1(CO)2O and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene.ALSO:The invention comprises titanium compounds of the formula <FORM:1091525/C2/1> wherein x is 2 and y is 2, or x is 3 and y is 1 and R represents a substituted or unsubstituted alkyl group and R1 represents the residue of a dicarboxylic anhydride having the formula R1(CO)2O, provided that when x is 3 and y is 1, the dicarboxylic anhydride is not phthalic anhydride, and mixtures thereof. The compounds are made by reacting a titanate of the formula Ti(OR)4 with an anhydride R1(CO)2O provided that when the anhydride is phthalic anhydride, the ratio of anhydride and titanate is such that x is 2 and y is 2. Mixtures of the novel compounds can be made by adjusting the proportions of the reactants and/or using a mixture of titanates and/or anhydrides. Preferred values of R are C1- 8 alkyl groups, particularly butyl groups. Specified anhydrides are succinic, citraconic, cyclohexane dicarboxylic, tetrachlorophthalic, camphoric, maleic and phthalic anhydrides. The compounds are used in water-proofing compositions (see Division D1). Examples are provided.ALSO:Textile materials, paper and non-fibrous porous materials are rendered water-repellent by treatment with a composition comprising a wax, a titanium compound of the formula: <FORM:1091525/D1-D2/1> where x is 2 and y is 2, or x is 3 and y is 1, R is a substituted or unsubstituted alkyl group and R\sv represents the residue of a dicarboxylic anhydride R\sv(CO)2O, and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene. The treatment is effected by dipping, preferably followed by oven drying at 50 DEG C. Improved results are obtained by drying the material prior to treatment at 50 DEG C. Examples describe the treatment of cotton and wool fabrics.ALSO:Paper, masonry, brick and concrete are rendered water repellent by coating with a liquid composition comprise a wax, a titanium compound: <FORM:1091525/B1-B2/1> where x is 2 or y is 2 or x is 3 and v is 1, R represents a substituted or unsubstituted alkyl group and R1 represents the residue of a dicarboxylic anhydride R1(CO)2O, and a solvent for the wax and the titanium compound. Preferred compositions comprise paraffin wax. Specified solvents are white spirit, trichloroethylene and perchloroethylene.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB26803/63A GB1091525A (en) | 1963-07-05 | 1963-07-05 | New titanium compounds and compositions containing them |
| BE650036A BE650036A (en) | 1963-07-05 | 1964-07-02 | |
| NL6407597A NL6407597A (en) | 1963-07-05 | 1964-07-03 | |
| FR980708A FR1404767A (en) | 1963-07-05 | 1964-07-03 | New organic titanium compounds, their preparation and applications, in particular for the treatment of pigments |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB26803/63A GB1091525A (en) | 1963-07-05 | 1963-07-05 | New titanium compounds and compositions containing them |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1091525A true GB1091525A (en) | 1967-11-15 |
Family
ID=10249473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26803/63A Expired GB1091525A (en) | 1963-07-05 | 1963-07-05 | New titanium compounds and compositions containing them |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE650036A (en) |
| GB (1) | GB1091525A (en) |
| NL (1) | NL6407597A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4507246A (en) * | 1983-06-09 | 1985-03-26 | General Electric Company | Titanium chelate catalyst |
| US4600789A (en) * | 1984-05-14 | 1986-07-15 | Kenrich Petrochemicals, Inc. | Neoalkoxy organo-titanate useful as coupling and polymer processing agents |
| US4623738A (en) | 1985-04-22 | 1986-11-18 | Kenrich Petrochemicals, Inc. | Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents |
| US5260466A (en) * | 1991-08-08 | 1993-11-09 | Tioxide Specialties Limited | Preparation of titanium derivatives |
-
1963
- 1963-07-05 GB GB26803/63A patent/GB1091525A/en not_active Expired
-
1964
- 1964-07-02 BE BE650036A patent/BE650036A/xx unknown
- 1964-07-03 NL NL6407597A patent/NL6407597A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4507246A (en) * | 1983-06-09 | 1985-03-26 | General Electric Company | Titanium chelate catalyst |
| US4600789A (en) * | 1984-05-14 | 1986-07-15 | Kenrich Petrochemicals, Inc. | Neoalkoxy organo-titanate useful as coupling and polymer processing agents |
| US4623738A (en) | 1985-04-22 | 1986-11-18 | Kenrich Petrochemicals, Inc. | Neoalkoxy organo-titanates and organo-zirconates useful as coupling and polymer processing agents |
| US5260466A (en) * | 1991-08-08 | 1993-11-09 | Tioxide Specialties Limited | Preparation of titanium derivatives |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6407597A (en) | 1965-01-06 |
| BE650036A (en) | 1964-11-03 |
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