GB1086250A - Silazane compounds and their preparation - Google Patents
Silazane compounds and their preparationInfo
- Publication number
- GB1086250A GB1086250A GB17229/65A GB1722965A GB1086250A GB 1086250 A GB1086250 A GB 1086250A GB 17229/65 A GB17229/65 A GB 17229/65A GB 1722965 A GB1722965 A GB 1722965A GB 1086250 A GB1086250 A GB 1086250A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- hydrocarbon radical
- silazanes
- preparation
- novel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 abstract 1
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 125000003944 tolyl group Chemical group 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Silazanes (some of which are novel) are made by reacting a compound of the formula <FORM:1086250/C3/1> wherein R is a linear saturated unsubstituted or substituted hydrocarbon radical, an unsaturated hydrocarbon radical, H, or a substituted or unsubstituted aromatic hydrocarbon radical; R1 is H or CH3; R1 and R2 (which may be the same or different) are defined as for R or are Cl or Br; n is an integer; n1 is 3 or 4; and the ratio of C:Si in these compounds is 0.5-13:1, with a halosilane of formula <FORM:1086250/C3/2> wherein R and R1 are as defined and X is Cl or Br. The novel silazanes produced have the formula <FORM:1086250/C3/3> wherein R and R1 are as defined, R1 is H or CH3, X is Cl or Br, and if R is CH3, R1 and X are not identical. The reaction may be carried out in the presence of Lewis or ansolve acids (this term is defined) as catalysts at 30-200 DEG C. Specific groups R are Me, Et, Pr, Bu, g -chloropropyl, vinyl, phenyl, tolyl, o- or p-chlorophenyl and p-nitrophenyl.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL22431A IL22431A (en) | 1964-11-12 | 1964-11-12 | Process for the production of disilazanes and the products obtained by this method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1086250A true GB1086250A (en) | 1967-10-04 |
Family
ID=11043418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17229/65A Expired GB1086250A (en) | 1964-11-12 | 1965-04-23 | Silazane compounds and their preparation |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT270677B (en) |
| BE (1) | BE672101A (en) |
| FR (1) | FR1453660A (en) |
| GB (1) | GB1086250A (en) |
| IL (1) | IL22431A (en) |
| NL (1) | NL6514660A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5196556A (en) * | 1988-12-03 | 1993-03-23 | Hoechst Aktiengesellschaft | Polysubstituted chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4340619A (en) * | 1981-01-15 | 1982-07-20 | Dow Corning Corporation | Process for the preparation of poly(disilyl)silazane polymers and the polymers therefrom |
| US4312970A (en) * | 1981-02-20 | 1982-01-26 | Dow Corning Corporation | Silazane polymers from {R'3 Si}2 NH and organochlorosilanes |
| FR2577933B1 (en) * | 1985-02-27 | 1987-02-20 | Rhone Poulenc Rech | PROCESS FOR THE PREPARATION OF ORGANOPOLYSILAZANES AND ORGANOPOLY (DISILYL) SILAZANES WITH IMPROVED THERMAL RESISTANCE AND THE USE THEREOF IN PARTICULAR AS A CERAMIC PRECURSOR |
| DE3733727A1 (en) * | 1987-10-06 | 1989-04-20 | Hoechst Ag | POLYMERS HYDRIDOCHLORSILAZANES AND METHOD FOR THEIR PRODUCTION |
| EP3929326A3 (en) | 2011-06-03 | 2022-03-16 | Versum Materials US, LLC | Compositions and processes for depositing carbon-doped silicon-containing films |
-
1964
- 1964-11-12 IL IL22431A patent/IL22431A/en unknown
-
1965
- 1965-04-23 GB GB17229/65A patent/GB1086250A/en not_active Expired
- 1965-10-29 AT AT982565A patent/AT270677B/en active
- 1965-11-09 BE BE672101D patent/BE672101A/xx unknown
- 1965-11-11 NL NL6514660A patent/NL6514660A/xx unknown
- 1965-11-12 FR FR38161A patent/FR1453660A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5196556A (en) * | 1988-12-03 | 1993-03-23 | Hoechst Aktiengesellschaft | Polysubstituted chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| AT270677B (en) | 1969-05-12 |
| IL22431A (en) | 1968-11-27 |
| NL6514660A (en) | 1966-01-25 |
| BE672101A (en) | 1966-03-01 |
| FR1453660A (en) | 1966-06-03 |
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