GB1086250A - Silazane compounds and their preparation - Google Patents

Silazane compounds and their preparation

Info

Publication number
GB1086250A
GB1086250A GB17229/65A GB1722965A GB1086250A GB 1086250 A GB1086250 A GB 1086250A GB 17229/65 A GB17229/65 A GB 17229/65A GB 1722965 A GB1722965 A GB 1722965A GB 1086250 A GB1086250 A GB 1086250A
Authority
GB
United Kingdom
Prior art keywords
formula
hydrocarbon radical
silazanes
preparation
novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17229/65A
Inventor
Jacob Silbiger
Joshua Fuchs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yissum Research Development Co of Hebrew University of Jerusalem
Original Assignee
Yissum Research Development Co of Hebrew University of Jerusalem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yissum Research Development Co of Hebrew University of Jerusalem filed Critical Yissum Research Development Co of Hebrew University of Jerusalem
Publication of GB1086250A publication Critical patent/GB1086250A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)

Abstract

Silazanes (some of which are novel) are made by reacting a compound of the formula <FORM:1086250/C3/1> wherein R is a linear saturated unsubstituted or substituted hydrocarbon radical, an unsaturated hydrocarbon radical, H, or a substituted or unsubstituted aromatic hydrocarbon radical; R1 is H or CH3; R1 and R2 (which may be the same or different) are defined as for R or are Cl or Br; n is an integer; n1 is 3 or 4; and the ratio of C:Si in these compounds is 0.5-13:1, with a halosilane of formula <FORM:1086250/C3/2> wherein R and R1 are as defined and X is Cl or Br. The novel silazanes produced have the formula <FORM:1086250/C3/3> wherein R and R1 are as defined, R1 is H or CH3, X is Cl or Br, and if R is CH3, R1 and X are not identical. The reaction may be carried out in the presence of Lewis or ansolve acids (this term is defined) as catalysts at 30-200 DEG C. Specific groups R are Me, Et, Pr, Bu, g -chloropropyl, vinyl, phenyl, tolyl, o- or p-chlorophenyl and p-nitrophenyl.
GB17229/65A 1964-11-12 1965-04-23 Silazane compounds and their preparation Expired GB1086250A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IL22431A IL22431A (en) 1964-11-12 1964-11-12 Process for the production of disilazanes and the products obtained by this method

Publications (1)

Publication Number Publication Date
GB1086250A true GB1086250A (en) 1967-10-04

Family

ID=11043418

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17229/65A Expired GB1086250A (en) 1964-11-12 1965-04-23 Silazane compounds and their preparation

Country Status (6)

Country Link
AT (1) AT270677B (en)
BE (1) BE672101A (en)
FR (1) FR1453660A (en)
GB (1) GB1086250A (en)
IL (1) IL22431A (en)
NL (1) NL6514660A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5196556A (en) * 1988-12-03 1993-03-23 Hoechst Aktiengesellschaft Polysubstituted chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4340619A (en) * 1981-01-15 1982-07-20 Dow Corning Corporation Process for the preparation of poly(disilyl)silazane polymers and the polymers therefrom
US4312970A (en) * 1981-02-20 1982-01-26 Dow Corning Corporation Silazane polymers from {R'3 Si}2 NH and organochlorosilanes
FR2577933B1 (en) * 1985-02-27 1987-02-20 Rhone Poulenc Rech PROCESS FOR THE PREPARATION OF ORGANOPOLYSILAZANES AND ORGANOPOLY (DISILYL) SILAZANES WITH IMPROVED THERMAL RESISTANCE AND THE USE THEREOF IN PARTICULAR AS A CERAMIC PRECURSOR
DE3733727A1 (en) * 1987-10-06 1989-04-20 Hoechst Ag POLYMERS HYDRIDOCHLORSILAZANES AND METHOD FOR THEIR PRODUCTION
EP3929326A3 (en) * 2011-06-03 2022-03-16 Versum Materials US, LLC Compositions and processes for depositing carbon-doped silicon-containing films

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5196556A (en) * 1988-12-03 1993-03-23 Hoechst Aktiengesellschaft Polysubstituted chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture

Also Published As

Publication number Publication date
IL22431A (en) 1968-11-27
BE672101A (en) 1966-03-01
NL6514660A (en) 1966-01-25
FR1453660A (en) 1966-06-03
AT270677B (en) 1969-05-12

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