GB1086021A - Process for the production of aromatic polyketones - Google Patents
Process for the production of aromatic polyketonesInfo
- Publication number
- GB1086021A GB1086021A GB279264A GB279264A GB1086021A GB 1086021 A GB1086021 A GB 1086021A GB 279264 A GB279264 A GB 279264A GB 279264 A GB279264 A GB 279264A GB 1086021 A GB1086021 A GB 1086021A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ferric
- groups
- carbonyl halide
- compound
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aromatic polyketones are prepared by reacting either (i) a mixture of (a) at least one compound containing two aromatically bound carbonyl halide groups and (b) at least one compound containing at least two aromatically bound hydrogen atoms, preferably in substantially equimolar proportions, or (ii) at least one compound containing a single carbonyl halide group and a hydrogen atom each bound to an aromatic ring or (iii) a mixture of the three types of compounds specified in (i) and (ii) above, in the presence of from 0.05 to 6% of the weight of the polymerizable material of a salt of iron which is soluble in the molten polymerizable mixture. The preferred dicarbonyl halides are those of the structure: <FORM:1086021/C3/1> <FORM:1086021/C3/2> <FORM:1086021/C3/3> or substituted derivatives thereof, wherein Y is a divalent bridging radical and is preferably oxygen, sulphur or groups of the structure: <FORM:1086021/C3/4> where K and K1 ar oxygen or sulphur atoms and L is-CO-or SO2 and X is a halogen atom, preferably chlorine. If the benzene ring is to be further substituted then halogen atoms, hydrocarbon, ether and thioether groups and halogen substituted derivatives of these groups are preferred. The compound (b) may suitably be a compound having a structure similar to the dicarbonyl halides but in which the carbonyl halide groups are replaced by hydrogen atoms. At least one of the compounds (a) or (b) should be one containing benzene rings bridged by a divalent radical and the other is preferably one containing benzene rings directly linked to one another. The compounds used in method (ii) may be exactly similar to the dicarbonyl halides (a) but excluding one of the carbonyl halide groups. Ferric chloride is the preferred catalyst, but other ferrous and ferric salts such as ferric fluoride, ferric bromide, ferric iodide, ferric orthophosphate and ferrous and ferric acetoacetonates may also be used.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB279264A GB1086021A (en) | 1964-01-22 | 1964-01-22 | Process for the production of aromatic polyketones |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB279264A GB1086021A (en) | 1964-01-22 | 1964-01-22 | Process for the production of aromatic polyketones |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1086021A true GB1086021A (en) | 1967-10-04 |
Family
ID=9745992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB279264A Expired GB1086021A (en) | 1964-01-22 | 1964-01-22 | Process for the production of aromatic polyketones |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1086021A (en) |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2433278A1 (en) * | 1973-07-12 | 1975-02-13 | Raychem Corp | AROMATIC POLYKETONE |
US3953400A (en) | 1972-01-17 | 1976-04-27 | Raychem Corporation | Polyketones and methods therefor |
DE2549529A1 (en) * | 1975-11-05 | 1977-05-18 | Basf Ag | AROMATIC POLYAETHERSULPHONES |
US4229564A (en) * | 1976-04-26 | 1980-10-21 | Raychem Corporation | Friedel-Crafts polymerization of monomers in the preparation of polyketones and polysulfones |
US4239884A (en) | 1975-08-11 | 1980-12-16 | Raychem Corporation | Process for isolation of solid polymers |
US4247682A (en) * | 1979-05-07 | 1981-01-27 | Raychem Corporation | Aromatic ketone and sulfone polymers and process for the preparation thereof |
US4398020A (en) | 1981-04-29 | 1983-08-09 | Imperial Chemical Industries Plc | Production of aromatic polyketones |
GB2138433A (en) * | 1983-03-31 | 1984-10-24 | Raychem Corp | Preparation of poly (arylene ether ketones) |
US4533417A (en) * | 1983-07-19 | 1985-08-06 | Bicc Public Limited Company | Manufacture of oriented insulated wires and cables |
EP0178871A2 (en) * | 1984-10-11 | 1986-04-23 | RAYCHEM CORPORATION (a Delaware corporation) | Preparation of aromatic polymers |
US4593086A (en) * | 1984-03-29 | 1986-06-03 | Raychem Corporation | Preparation of aromatic ketone-sulfone copolymers |
EP0191839A1 (en) * | 1984-08-20 | 1986-08-27 | Raychem Corp | Aryl ether ketone copolymers. |
US4698393A (en) * | 1983-03-31 | 1987-10-06 | Raychem Corporation | Preparation of poly(arylene ether ketones) |
US4709007A (en) * | 1983-03-31 | 1987-11-24 | Raychem Corporation | Preparation of aromatic polymers |
US4721771A (en) * | 1983-03-31 | 1988-01-26 | Raychem Corporation | Preparation of aromatic polymers |
EP0254431A2 (en) * | 1986-06-26 | 1988-01-27 | E.I. Du Pont De Nemours And Company | Polyether ketone |
US4808693A (en) * | 1984-08-20 | 1989-02-28 | Raychem Corporation | Aryl ether ketone copolymers |
US4820792A (en) * | 1986-04-11 | 1989-04-11 | Raychem Limited | Preparation of aromatic polyketones using a strong acid catalyst with a weaker acid solvent |
US4826947A (en) * | 1987-07-09 | 1989-05-02 | Raychem Corporation | Preparation of poly(arylene ether ketones) |
US4843131A (en) * | 1987-10-20 | 1989-06-27 | Raychem Corporation | Preparation of poly(arylene ether ketones) by sequential oligomerization and polymerization in distinct reaction zones |
US4855387A (en) * | 1987-07-09 | 1989-08-08 | Raychem Corporation | Poly(arylene ether ketones) having biphenylene-4,4'-dicarbonyl groups |
US4879366A (en) * | 1983-03-31 | 1989-11-07 | Raychem Corporation | Preparation of aromatic oligomers |
US4912181A (en) * | 1987-10-20 | 1990-03-27 | Raychem Corporation | Preparation of poly(arylene ether ketones) by sequential oligomerization and polyerization in distinct reaction zones |
US4912195A (en) * | 1983-03-31 | 1990-03-27 | Raychem Corporation | Preparation of aromatic polymers using a specified quantity of Lewis acid |
US4918237A (en) * | 1989-03-13 | 1990-04-17 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,4-bis(4-phenoxybenzoyl)benzene with certain metal-containing catalysts |
WO2003033454A1 (en) * | 2001-10-10 | 2003-04-24 | Jsr Corporation | Norbornene derivative and norbornene polymer obtained therefrom through ring-opening polymerization |
-
1964
- 1964-01-22 GB GB279264A patent/GB1086021A/en not_active Expired
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3953400A (en) | 1972-01-17 | 1976-04-27 | Raychem Corporation | Polyketones and methods therefor |
DE2433278A1 (en) * | 1973-07-12 | 1975-02-13 | Raychem Corp | AROMATIC POLYKETONE |
US4239884A (en) | 1975-08-11 | 1980-12-16 | Raychem Corporation | Process for isolation of solid polymers |
DE2549529A1 (en) * | 1975-11-05 | 1977-05-18 | Basf Ag | AROMATIC POLYAETHERSULPHONES |
US4229564A (en) * | 1976-04-26 | 1980-10-21 | Raychem Corporation | Friedel-Crafts polymerization of monomers in the preparation of polyketones and polysulfones |
US4247682A (en) * | 1979-05-07 | 1981-01-27 | Raychem Corporation | Aromatic ketone and sulfone polymers and process for the preparation thereof |
US4398020A (en) | 1981-04-29 | 1983-08-09 | Imperial Chemical Industries Plc | Production of aromatic polyketones |
GB2138433A (en) * | 1983-03-31 | 1984-10-24 | Raychem Corp | Preparation of poly (arylene ether ketones) |
US4698393A (en) * | 1983-03-31 | 1987-10-06 | Raychem Corporation | Preparation of poly(arylene ether ketones) |
US4912195A (en) * | 1983-03-31 | 1990-03-27 | Raychem Corporation | Preparation of aromatic polymers using a specified quantity of Lewis acid |
US4879366A (en) * | 1983-03-31 | 1989-11-07 | Raychem Corporation | Preparation of aromatic oligomers |
US4721771A (en) * | 1983-03-31 | 1988-01-26 | Raychem Corporation | Preparation of aromatic polymers |
US4709007A (en) * | 1983-03-31 | 1987-11-24 | Raychem Corporation | Preparation of aromatic polymers |
GB2179951A (en) * | 1983-03-31 | 1987-03-18 | Raychem Corp | Preparation of poly (arylene ether ketones) |
US4533417A (en) * | 1983-07-19 | 1985-08-06 | Bicc Public Limited Company | Manufacture of oriented insulated wires and cables |
US4593086A (en) * | 1984-03-29 | 1986-06-03 | Raychem Corporation | Preparation of aromatic ketone-sulfone copolymers |
EP0191839A1 (en) * | 1984-08-20 | 1986-08-27 | Raychem Corp | Aryl ether ketone copolymers. |
EP0191839A4 (en) * | 1984-08-20 | 1987-01-10 | Raychem Corp | Aryl ether ketone copolymers. |
US4808693A (en) * | 1984-08-20 | 1989-02-28 | Raychem Corporation | Aryl ether ketone copolymers |
EP0178871A2 (en) * | 1984-10-11 | 1986-04-23 | RAYCHEM CORPORATION (a Delaware corporation) | Preparation of aromatic polymers |
EP0178871A3 (en) * | 1984-10-11 | 1988-06-15 | RAYCHEM CORPORATION (a Delaware corporation) | Preparation of aromatic polymers |
US4820792A (en) * | 1986-04-11 | 1989-04-11 | Raychem Limited | Preparation of aromatic polyketones using a strong acid catalyst with a weaker acid solvent |
EP0254431A3 (en) * | 1986-06-26 | 1989-01-25 | E.I. Du Pont De Nemours And Company | Polyether ketone |
EP0254431A2 (en) * | 1986-06-26 | 1988-01-27 | E.I. Du Pont De Nemours And Company | Polyether ketone |
US4855387A (en) * | 1987-07-09 | 1989-08-08 | Raychem Corporation | Poly(arylene ether ketones) having biphenylene-4,4'-dicarbonyl groups |
US4826947A (en) * | 1987-07-09 | 1989-05-02 | Raychem Corporation | Preparation of poly(arylene ether ketones) |
US4843131A (en) * | 1987-10-20 | 1989-06-27 | Raychem Corporation | Preparation of poly(arylene ether ketones) by sequential oligomerization and polymerization in distinct reaction zones |
US4912181A (en) * | 1987-10-20 | 1990-03-27 | Raychem Corporation | Preparation of poly(arylene ether ketones) by sequential oligomerization and polyerization in distinct reaction zones |
US4918237A (en) * | 1989-03-13 | 1990-04-17 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,4-bis(4-phenoxybenzoyl)benzene with certain metal-containing catalysts |
WO2003033454A1 (en) * | 2001-10-10 | 2003-04-24 | Jsr Corporation | Norbornene derivative and norbornene polymer obtained therefrom through ring-opening polymerization |
US6846890B2 (en) | 2001-10-10 | 2005-01-25 | Jsr Corporation | Norbornene derivative and norbornene polymer obtained therefrom through ring opening polymerization |
CN1321971C (en) * | 2001-10-10 | 2007-06-20 | Jsr株式会社 | Norbornene derivative and norbornene polymer obtained therefrom through ring opening polymerization |
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