GB1084953A - Copolymers and processes for preparing them - Google Patents
Copolymers and processes for preparing themInfo
- Publication number
- GB1084953A GB1084953A GB4220/64A GB422064A GB1084953A GB 1084953 A GB1084953 A GB 1084953A GB 4220/64 A GB4220/64 A GB 4220/64A GB 422064 A GB422064 A GB 422064A GB 1084953 A GB1084953 A GB 1084953A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propylene
- butene
- catalyst
- copolymer
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A process for the copolymerization of butene-1 with propylene comprises polymerizing a mixture of propylene and butene-1 in the presence of a stereospecific catalyst, which is defined as one which will under equivalent conditions polymerize propylene in the absence of other monomers to polypropylene which is at least 70% insoluble in boiling heptane, and recovering a solid crystalline copolymer of propylene and butene-1 comprising 5 to 50% by wt. of randomly copolymerized propylene (defined). The stereospecific catalyst is preferably a trivalent titanium compound activated with an aluminium alkyl compound. Preferably the copolymer is obtained as a slurry by using a catalyst which has been heated by mutually polymerizing a 1-olefine, e.g. propylene, butene-1 or b -methylbutene-1 in the presence of the catalyst. The weight of polymer formed in this stage is preferably between 1 and 5% by wt. of the total polymer.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4220/64A GB1084953A (en) | 1964-01-31 | 1964-01-31 | Copolymers and processes for preparing them |
BE658969A BE658969A (en) | 1964-01-31 | 1965-01-28 | |
FR3790A FR1425628A (en) | 1964-01-31 | 1965-01-29 | Copolymers and their manufacturing process |
NL6501217A NL6501217A (en) | 1964-01-31 | 1965-01-29 | |
ES0308782A ES308782A1 (en) | 1964-01-31 | 1965-01-30 | Procedure for the preparation of copolymers. (Machine-translation by Google Translate, not legally binding) |
AT88865A AT271871B (en) | 1964-01-31 | 1965-02-01 | Process for the random copolymerization of butene-1 with propylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4220/64A GB1084953A (en) | 1964-01-31 | 1964-01-31 | Copolymers and processes for preparing them |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1084953A true GB1084953A (en) | 1967-09-27 |
Family
ID=9773005
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4220/64A Expired GB1084953A (en) | 1964-01-31 | 1964-01-31 | Copolymers and processes for preparing them |
Country Status (5)
Country | Link |
---|---|
AT (1) | AT271871B (en) |
BE (1) | BE658969A (en) |
ES (1) | ES308782A1 (en) |
GB (1) | GB1084953A (en) |
NL (1) | NL6501217A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55123607A (en) * | 1979-03-14 | 1980-09-24 | Mitsui Petrochem Ind Ltd | Preparation of poly-1-butene |
JPS55127409A (en) * | 1979-03-27 | 1980-10-02 | Mitsui Petrochem Ind Ltd | Preparation of poly-1-butene |
US4600762A (en) * | 1983-08-12 | 1986-07-15 | Mitsui Petrochemical Industries, Ltd. | Randum 1-butene copolymer |
-
1964
- 1964-01-31 GB GB4220/64A patent/GB1084953A/en not_active Expired
-
1965
- 1965-01-28 BE BE658969A patent/BE658969A/xx unknown
- 1965-01-29 NL NL6501217A patent/NL6501217A/xx unknown
- 1965-01-30 ES ES0308782A patent/ES308782A1/en not_active Expired
- 1965-02-01 AT AT88865A patent/AT271871B/en active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55123607A (en) * | 1979-03-14 | 1980-09-24 | Mitsui Petrochem Ind Ltd | Preparation of poly-1-butene |
JPS55127409A (en) * | 1979-03-27 | 1980-10-02 | Mitsui Petrochem Ind Ltd | Preparation of poly-1-butene |
US4600762A (en) * | 1983-08-12 | 1986-07-15 | Mitsui Petrochemical Industries, Ltd. | Randum 1-butene copolymer |
Also Published As
Publication number | Publication date |
---|---|
ES308782A1 (en) | 1965-12-16 |
AT271871B (en) | 1969-06-25 |
NL6501217A (en) | 1965-08-02 |
BE658969A (en) | 1965-07-28 |
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