GB1073505A - Improvements relating to carbonamides - Google Patents
Improvements relating to carbonamidesInfo
- Publication number
- GB1073505A GB1073505A GB172465D GB172465D GB1073505A GB 1073505 A GB1073505 A GB 1073505A GB 172465 D GB172465 D GB 172465D GB 172465 D GB172465 D GB 172465D GB 1073505 A GB1073505 A GB 1073505A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tert
- alkyl
- polyamide
- specified
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A fibre is produced from a linear polyamide containing 0.05-5% of either <FORM:1073505/C3/1> where R1 = C1- 8 alkyl and R = C4- 8 tert. alkyl or <FORM:1073505/C3/2> wherein R = C1- 8 alkyl and R1 = C4- 8 tert. alkyl as an antioxidant. Compounds specified include those in which R = tert.-butyl and R1 is methyl. Polyamides specified are polycaprolactam, polyundecanolactam, poly(hexamethylene adipamide), poly(hexamethylene sebacamide), and bis-(4-amino cyclohexyl) methane polyamides with dodecane dicarboxylic acid. The polyamide may also contain 2-30% of a polyoxyethylene of at least 600 M.W., which may have methoxy, ethoxy, phenoxy, nonylphenoxy or 2,6-ditertiary butylphenoxy end-groups. 0.1-5% of a U.V. absorbant may also be present. The absorbants may be either an N-[o -(2,1,3-benzotriazol-2-yl)phenyl]-amide, e.g. an amide of pivalic, 2,2,5,5-tetramethyl adipic or 2,3,5,6-tetramethyl terephthalic acid or a 2-(o-hydroxyphenyl)-2,1,3-benzotriazole. The antioxidant may be added to the polyamide monomers before polymerization or to the polymer melt or to flakes of the polymer. The polyoxyethylene and U.V. absorbers may be added at the same time or separately. Other additives may be delusterants, pigments and dyes many dyes being specified, including 1 - amino - 4 - hydroxy - 2 -(2-hydroxyethoxy) anthraquinone. The polyamide composition may be spun into filaments and the polyoxyethylene then partially removed by scouring with water to produce a cellular product.ALSO:The heat and light fastness of dyed polyamide fibres may be improved by adding to the polyamide before spinning a compound of formula: <FORM:1073505/D1-D2/1> where R is C1-8 alkyl and R1 is C4-8 tert.alkyl or: <FORM:1073505/D1-D2/2> wherein R is C4-8 tert.-alkyl and R1 is C1-8 alkyl as antioxidant. The polyamide may also contain 2 - 30% of a polyethylene oxide and 0.1 - 5% of a 2[o-(acylamino) phenyl] 2H-benztriazole or 2(o-hydroxy phenyl) 2H-benztriazole. In Examples polyamides specified are nylon 66 and a polyamide of bis (4-amino-methyl) cyclohexane and dodecadioc acid. Antioxidants specified include 2, 3, 5, 6-tetramethyl-1, 4-di (3, 5- di-tert-butyl-4-hydroxy-benzyl) benzene and 1, 3, 5-trimethyl-2, 4, 6-tri (3, 5- di-tert-butyl-4-hydroxybenzyl) benzene. Polyethylene oxides specified include polyethylene oxide and polyethylene oxide 2, 6-di-tert-butyl phenyl ether and benztriazoles specified are N, N1 bis[o-(2H benztriazol-2-yl) phenyl]-2, 2, 5, 5-tetramethyl adipamide. N, N1bis[o-(2H benztriazol-2-yl)phenyl] 2, 3, 5, 6-tetramethyl terephthalamide and N-o-hydroxyphenyl-2H-benztriazole. Fibres composed of these materials may be dyed in aqueous dispersed dyebath containing a sodium fatty alcohol sulphate, Na3 PO4 and a surface active agent or in an aqueous premetallized dye-bath containing a sodium fatty alcohol sulphate, an ethylene oxide-propylene oxide adduct, NH4OH and (NH4)2SO4. Dyes specified are mixtures of Disperse yellow 3 1-amino-4-hydroxy-2 (2-hydroxyethoxy) anthraquinone, Disperse blue 7, Disperse blue 3, Acid green 25, Acid orange 64 and Acid red 182. In Example IX the dyed fibres are also rendered lightfast by after treatment with CuSO4-SH2O.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36363664A | 1964-04-29 | 1964-04-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1073505A true GB1073505A (en) | 1967-06-28 |
Family
ID=23431040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB172465D Expired GB1073505A (en) | 1964-04-29 | 1965-04-28 | Improvements relating to carbonamides |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1924479U (en) |
GB (1) | GB1073505A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0315407A2 (en) * | 1987-11-03 | 1989-05-10 | Du Pont Canada Inc. | High temperature release sheet for printed circuit boards |
-
1965
- 1965-04-28 GB GB172465D patent/GB1073505A/en not_active Expired
- 1965-04-29 DE DE1965E0021584 patent/DE1924479U/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0315407A2 (en) * | 1987-11-03 | 1989-05-10 | Du Pont Canada Inc. | High temperature release sheet for printed circuit boards |
EP0315407A3 (en) * | 1987-11-03 | 1990-01-17 | Du Pont Canada Inc. | High temperature release sheet for printed circuit boards |
Also Published As
Publication number | Publication date |
---|---|
DE1924479U (en) | 1965-09-30 |
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