GB1068953A - Process for preparing a granular episulphide polymer - Google Patents
Process for preparing a granular episulphide polymerInfo
- Publication number
- GB1068953A GB1068953A GB5123466A GB5123466A GB1068953A GB 1068953 A GB1068953 A GB 1068953A GB 5123466 A GB5123466 A GB 5123466A GB 5123466 A GB5123466 A GB 5123466A GB 1068953 A GB1068953 A GB 1068953A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- polymer
- sulphide
- ethylene sulphide
- monomers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A granular polymer composed of units derived from ethylene sulphide alone or with other monomers is formed by polymerizing a first monomer charge, comprising predominantly ethylene sulphide and containing a catalyst, to form a first polymer which is made into dense particles and incorporated as a seed catalyst in a second monomer charge composed of ethylene sulphide, or a mixture of monomers containing a major proportion of ethylene sulphide, and polymerizing the mixture to form a second polymer. Monomers which may be copolymerized with ethylene sulphide include other cyclic alkylene sulphides and their derivatives, thioglycidyl ethers and esters, alkylene oxides and other cyclic ethers and acetals, alkylene imines, olefines, dienes and other vinyl compounds. As catalyst may be used the reaction product of a compound of the formula R2M (R is an alkyl or aryl group and M is Zn, Cd or Hg) and a compound having an active hydrogen atom or carbon disulphide, carbonyl sulphide, oxygen or sulphur. Other catalysts are those described in Specifications 1,059,490, 1,059,491 and 1,059,492. The preferred catalyst is the reaction product of diethyl zinc and water. The polymerization reaction may be carried out in bulk or in an inert solvent or emulsion or in the vapour phase. Uses.-For moulding into pipe, film, filament, rods, bars, gears, pumps or valves.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26760463A | 1963-03-25 | 1963-03-25 | |
| US26760563A | 1963-03-25 | 1963-03-25 | |
| US31284763A | 1963-10-01 | 1963-10-01 | |
| US32307463A | 1963-11-12 | 1963-11-12 | |
| US34979964A | 1964-03-06 | 1964-03-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1068953A true GB1068953A (en) | 1967-05-17 |
Family
ID=27540512
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5123466A Expired GB1068953A (en) | 1963-03-25 | 1964-03-24 | Process for preparing a granular episulphide polymer |
| GB1250664A Expired GB1068952A (en) | 1963-03-25 | 1964-03-24 | Stabilized ethylene sulfide polymer composition and process for stabilizing moldable ethylene sulfide polymer |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1250664A Expired GB1068952A (en) | 1963-03-25 | 1964-03-24 | Stabilized ethylene sulfide polymer composition and process for stabilizing moldable ethylene sulfide polymer |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE645691A (en) |
| DE (1) | DE1569453B1 (en) |
| GB (2) | GB1068953A (en) |
| NL (1) | NL6403189A (en) |
| SE (1) | SE332078B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3209525A1 (en) * | 1981-07-10 | 1983-01-27 | Siemens AG, 1000 Berlin und 8000 München | STABILIZATION OF POLYPHENYLENE SULFIDE AGAINST CORROSIVE OUTGASING |
| US4703088A (en) * | 1981-12-18 | 1987-10-27 | Phillips Petroleum Company | Mold corrosion inhibitors |
| DE3339581A1 (en) * | 1983-11-02 | 1985-05-09 | Bayer Ag, 5090 Leverkusen | POLYARYL SULFIDES WITH REDUCED CORROSION |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE558777A (en) * | 1952-12-23 | |||
| US2936298A (en) * | 1957-10-21 | 1960-05-10 | Celanese Corp | Stabilized polymers |
| BE591578A (en) * | 1959-06-04 | |||
| GB875560A (en) * | 1959-06-13 | 1961-08-23 | Basf Ag | Improvements in the stabilisation of high molecular weight polyformaldehyde |
| NL264328A (en) * | 1959-11-09 |
-
1964
- 1964-03-24 GB GB5123466A patent/GB1068953A/en not_active Expired
- 1964-03-24 SE SE365164A patent/SE332078B/xx unknown
- 1964-03-24 DE DE1964T0025895 patent/DE1569453B1/en active Pending
- 1964-03-24 GB GB1250664A patent/GB1068952A/en not_active Expired
- 1964-03-25 NL NL6403189A patent/NL6403189A/xx unknown
- 1964-03-25 BE BE645691D patent/BE645691A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1569453B1 (en) | 1970-07-23 |
| BE645691A (en) | 1964-09-25 |
| SE332078B (en) | 1971-01-25 |
| GB1068952A (en) | 1967-05-17 |
| NL6403189A (en) | 1964-09-28 |
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