GB1058385A - Organosilicon polymer compositions - Google Patents

Organosilicon polymer compositions

Info

Publication number
GB1058385A
GB1058385A GB3352764A GB3352764A GB1058385A GB 1058385 A GB1058385 A GB 1058385A GB 3352764 A GB3352764 A GB 3352764A GB 3352764 A GB3352764 A GB 3352764A GB 1058385 A GB1058385 A GB 1058385A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbon
radical
polyethers
unsaturated
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3352764A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones Corp
Original Assignee
Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corp filed Critical Dow Corning Corp
Publication of GB1058385A publication Critical patent/GB1058385A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C08G65/3322Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0834Compounds having one or more O-Si linkage
    • C07F7/0838Compounds with one or more Si-O-Si sequences
    • C07F7/0872Preparation and treatment thereof
    • C07F7/0876Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878Si-C bond
    • C07F7/0879Hydrosilylation reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0834Compounds having one or more O-Si linkage
    • C07F7/0892Compounds with a Si-O-N linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336Polymers modified by chemical after-treatment with organic compounds containing silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyethers (AREA)

Abstract

The invention comprises a composition consisting of (I) a silicon containing polyether in which (A) the polymer units consist essentially of oxyalkylene units of formula-O(CRR1)m-, wherein m is 1 to 5, each of R and R1 is a hydrogen, hydrocarbon ether, halo-hydrocarbon or -XSi(R11)n(Y)3- n radical in which X is a divalent radical free from acetylenic unsaturation composed of carbon and hydrogen and, optionally, oxygen, the oxygen being in the form of ­COH, ­C-O-, or -O-CO-, X being attached to the alkyleneoxy unit through a C-C bond, R11 is a monovalent hydrocarbon or halohydrocarbon radical, Y is hydrocarbonoxy, halohydrocarbonoxy, acyloxy, halogenated acyloxy, primary, secondary or tertiary amino or dihydrocarbyl-substituted isocyanoxy radical in which the substituents are hydrocarbon or halohydrocarbon radicals, n is 0, 1 or 2; there being not more than one silyl group attached to any one alkylene-oxy unit; and (B) the end-blocking groups are selected from hydrogen, monovalent hydrocarbon, halohydrocarbon and -WXSi(R11)nY3- n, where W is a divalent radical selected from O, -O.CO.O-, -O.CO- and urethane, X, Y, R11 and n being as defined above; there being on average at least two Si atoms, and at least three Y groups per polymer molecule; and (II) a pigment of filler. Many X, Y, R, R1 and R11 radicals are specified. Suitable pigments and fillers are cork, organic fibres, wood, glass, powdered metals, quartz, oxides, carbonates, diatomaceous earth, silica, asbestos, polytetrafluoroethylene, carbon black and organic and inorganic pigments. The organo-silicon polyethers may be prepared by reacting Y3- nSiH(R11)n with polyethers containing C = C bonds in either the terminal or side groups; or by polymerizing silicon-containing epoxides with or without other epoxides. The unsaturated polyethers may be prepared by polymerizing an epoxide in the presence of an alcohol, at least one reactant containing a C = C bond; the polyethers may be modified to yield further unsaturation, e.g. by reacting with an unsaturated epoxide, acetylene or a substituted acetylene, epichlorohydrin and alkali, followed by an unsaturated alcohol, an alkenyl halide and alkali, an alkenyl alcoholate or, a compound of formula X1(O)x.CO.Cl wherein X1 is an unsaturated-hydrocarbon radical, and x is 0 or 1. The compositions may be cured with water or atmospheric moisture, optionally in the presence of an organo- or organosilicontitanate, stannous octoate, dibutyl tin dilaurate or an amine as catalyst. Typical examples describe (1) the reaction of polypropylene glycol and allylchloroformate to form CH2 = CHCH2O . CO . O(C3H6O(68CO . O. CH2CH = CH2 which is condensed with methyl hydrogen diacetoxysilane to yield (CH3CO2)2Si(CH3)(CH2)3 O.CO(C3H6O)68CO.O(CH2)3Si(CH3) (O2CCH3)2; in (4) the oxetane <FORM:1058385/C3/1> is copolymerized with tetrahydrofuran in the presence BF3-etherate; both products are mixed with silica and di-butyl tin dilaurate and cured by exposure to air.
GB3352764A 1963-09-30 1964-08-17 Organosilicon polymer compositions Expired GB1058385A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US31229763A 1963-09-30 1963-09-30

Publications (1)

Publication Number Publication Date
GB1058385A true GB1058385A (en) 1967-02-08

Family

ID=23210809

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3352764A Expired GB1058385A (en) 1963-09-30 1964-08-17 Organosilicon polymer compositions

Country Status (8)

Country Link
JP (1) JPS4836960B1 (en)
AT (1) AT260547B (en)
BE (1) BE653701A (en)
CH (1) CH491983A (en)
DE (1) DE1495543A1 (en)
GB (1) GB1058385A (en)
NL (2) NL6407761A (en)
SE (1) SE319306B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4837401A (en) * 1984-12-12 1989-06-06 Kanegafuchi Chemical Industry, Co., Ltd. Curable polymer composition comprising organic polymer having silicon-contaiing reactive group
EP0368195A2 (en) * 1988-11-07 1990-05-16 OSi Specialties, Inc. Silicone polyether copolymers and process for their preparation
EP0397036A2 (en) * 1989-05-09 1990-11-14 Asahi Glass Company Ltd. Process for producing polyalkylene oxide derivatives
JPH03162414A (en) * 1989-11-06 1991-07-12 Union Carbide Chem & Plast Co Inc Surface active agent comprising silicone/polyether copolymer and its manufacture
US5045571A (en) * 1988-11-07 1991-09-03 Union Carbide Chemicals And Plastics Technology Corporation Silicone polyether copolymers and polyurethane foams prepared therefrom
EP0496109A2 (en) * 1990-12-26 1992-07-29 UNION CARBIDE CHEMICALS &amp; PLASTICS TECHNOLOGY CORPORATION, Three Cristina Centre A process for producing alkoxysilane-terminated polyethers
EP0714953A2 (en) 1994-12-01 1996-06-05 Dow Corning S.A. Moisture curable compositions of silyl-modified polymers
EP0714925A2 (en) 1994-12-01 1996-06-05 Dow Corning S.A. Silyl group-containing organic polymers
EP0718340A2 (en) 1994-12-01 1996-06-26 Dow Corning S.A. Silyl group-containing organic polymers
EP0771855A2 (en) 1995-11-02 1997-05-07 Dow Corning Corporation Crosslinked emulsions of pre-formed silicon-modified organic polymers
EP0867443A2 (en) * 1997-03-25 1998-09-30 Ivoclar Ag Hydrolyzable and polymerizable oxetanesilanes
US20140256844A1 (en) * 2009-07-24 2014-09-11 Evonik Degussa Gmbh Novel silicone polyether copolymers and process for preparation thereof
CN111704864A (en) * 2019-07-19 2020-09-25 广州市高士实业有限公司 Silane modified polyether sealant and preparation method and application thereof

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3408321A (en) * 1965-06-14 1968-10-29 Gen Electric Moisture curable siloxy terminated polyethers
US3448072A (en) * 1965-06-14 1969-06-03 Gen Electric Silylurethane terminated polyester compositions
US3441534A (en) * 1966-01-03 1969-04-29 Gen Electric Curable compositions
US4312993A (en) * 1979-09-10 1982-01-26 Sws Silicones Corporation Silylated polyethers
KR100578737B1 (en) * 2003-06-25 2006-05-12 학교법인 포항공과대학교 Preparation of star-shaped polymers containing reactive end groups and polymer composite film having low dielectric constant using the same
JP4523763B2 (en) * 2003-06-26 2010-08-11 コニシ株式会社 Adhesive composition
DE102009042201A1 (en) 2009-09-18 2011-04-14 Bayer Materialscience Ag Silane-containing polyethers
DE102009042190A1 (en) 2009-09-18 2011-03-24 Bayer Materialscience Ag Silane-containing reactive diluents

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4837401A (en) * 1984-12-12 1989-06-06 Kanegafuchi Chemical Industry, Co., Ltd. Curable polymer composition comprising organic polymer having silicon-contaiing reactive group
EP0368195A2 (en) * 1988-11-07 1990-05-16 OSi Specialties, Inc. Silicone polyether copolymers and process for their preparation
EP0368195A3 (en) * 1988-11-07 1991-04-24 OSi Specialties, Inc. Silicone polyether copolymers and process for their preparation
US5045571A (en) * 1988-11-07 1991-09-03 Union Carbide Chemicals And Plastics Technology Corporation Silicone polyether copolymers and polyurethane foams prepared therefrom
US5223583A (en) * 1989-05-09 1993-06-29 Asahi Glass Company Ltd. Process for producing polyalkylene oxide derivatives
EP0397036A2 (en) * 1989-05-09 1990-11-14 Asahi Glass Company Ltd. Process for producing polyalkylene oxide derivatives
EP0397036A3 (en) * 1989-05-09 1991-03-13 Asahi Glass Company Ltd. Process for producing polyalkylene oxide derivatives
JPH0747630B2 (en) 1989-11-06 1995-05-24 ユニオン・カーバイド・ケミカルズ・アンド・プラスチツクス・カンパニー・インコーポレーテツド Silicone polyether copolymer surfactant
JPH03162414A (en) * 1989-11-06 1991-07-12 Union Carbide Chem & Plast Co Inc Surface active agent comprising silicone/polyether copolymer and its manufacture
EP0496109A3 (en) * 1990-12-26 1992-11-25 Union Carbide Chemicals & Plastics Technology Corporation, Three Cristina Centre A process for producing alkoxysilane-terminated polyethers
EP0496109A2 (en) * 1990-12-26 1992-07-29 UNION CARBIDE CHEMICALS &amp; PLASTICS TECHNOLOGY CORPORATION, Three Cristina Centre A process for producing alkoxysilane-terminated polyethers
EP0714953A3 (en) * 1994-12-01 1996-12-27 Dow Corning Sa Moisture curable compositions of silyl-modified polymers
EP0714925A2 (en) 1994-12-01 1996-06-05 Dow Corning S.A. Silyl group-containing organic polymers
EP0718340A2 (en) 1994-12-01 1996-06-26 Dow Corning S.A. Silyl group-containing organic polymers
EP0714953A2 (en) 1994-12-01 1996-06-05 Dow Corning S.A. Moisture curable compositions of silyl-modified polymers
EP0718340A3 (en) * 1994-12-01 1997-01-02 Dow Corning Sa Silyl group-containing organic polymers
EP0771855A2 (en) 1995-11-02 1997-05-07 Dow Corning Corporation Crosslinked emulsions of pre-formed silicon-modified organic polymers
EP0867443A2 (en) * 1997-03-25 1998-09-30 Ivoclar Ag Hydrolyzable and polymerizable oxetanesilanes
EP0867443A3 (en) * 1997-03-25 2000-06-28 Ivoclar Ag Hydrolyzable and polymerizable oxetanesilanes
US20140256844A1 (en) * 2009-07-24 2014-09-11 Evonik Degussa Gmbh Novel silicone polyether copolymers and process for preparation thereof
CN111704864A (en) * 2019-07-19 2020-09-25 广州市高士实业有限公司 Silane modified polyether sealant and preparation method and application thereof

Also Published As

Publication number Publication date
SE319306B (en) 1970-01-12
BE653701A (en) 1965-03-29
DE1495543A1 (en) 1969-02-27
NL128826C (en)
NL6407761A (en) 1965-03-31
CH491983A (en) 1970-06-15
AT260547B (en) 1968-03-11
JPS4836960B1 (en) 1973-11-08

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