GB1057233A - Improved polyester additives for hydrocarbon oil compositions - Google Patents

Improved polyester additives for hydrocarbon oil compositions

Info

Publication number
GB1057233A
GB1057233A GB14110/64A GB1411064A GB1057233A GB 1057233 A GB1057233 A GB 1057233A GB 14110/64 A GB14110/64 A GB 14110/64A GB 1411064 A GB1411064 A GB 1411064A GB 1057233 A GB1057233 A GB 1057233A
Authority
GB
United Kingdom
Prior art keywords
polyester
glycol
acid
blocked
ooc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14110/64A
Inventor
Charlotte Lion
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB14110/64A priority Critical patent/GB1057233A/en
Priority to DE19651570503 priority patent/DE1570503A1/en
Priority to SE04374/65A priority patent/SE333362B/xx
Priority to FR11963A priority patent/FR1429103A/en
Priority to CH471465A priority patent/CH463118A/en
Priority to DK174165AA priority patent/DK119886B/en
Priority to BE680840A priority patent/BE680840A/fr
Publication of GB1057233A publication Critical patent/GB1057233A/en
Expired legal-status Critical Current

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    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/08Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/192Macromolecular compounds
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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Lubricants (AREA)

Abstract

An antiwear additive for fuel and lubricant oil is a blocked polyester of the formula (B)HO-[X-OOC-Y-COO]nXOOC-YCO.R1 wherein n is an integer, suitably 1-25, R1 is the residue of a C1-6 aliphatic alcohol or of a primary or secondary amine, Y is the residue of dioleic acid, and X is the residue of a diol of formula <FORM:1057233/C4-C5/1> The polyester may be added to e.g. gasoline, kerosine, and gas oils, and lubricating oils, e.g. marine cylinder oils and automotive lubricating oils, especially in conjunction with "overbased" additives, e.g. alkali and alkaline earth metal salts of sulphonic, naphthenic, salicylic acids or of phenols. In the examples a polyester from dioleic acid and ethylene glycol, blocked with methanol is added to a marine cylinder oil containing an overbased calcium sulphonate; wet and dry kerosine; naphthas; and an oil comprising a paraffin base oil, a V.I. improver (a copolymer of vinyl acetate, N-vinyl pyrrolidone and fumarate esters), and detergents (sulphurized barium phenate, calcium sulphonate and polyisobutylene succinic acid amic adduct).ALSO:A polyester is prepared by esterifying oleic acid dimer with an equimolecular amount of a glycol HO-CHR-(-CHR-)-mCHR-OH, where each R is H or a C1- 20 alkyl group and m is 0 or 1, until between 1 and 2 mols of water have been evolved per mol of acid or glycol, and condensing the product polyester with a C1- 6 aliphatic alcohol or a primary or secondary amine, to give a final product HO-[-X-OOC-Y-COO-]-n X-OOC-Y-CO-R1, where X, Y and R1 are, respectively, the residues of the glycol, the acid, and the alcohol or amine, and n is an integer. In the example the glycol used is ethylene glycol, and the polyester is blocked with methanol.ALSO:A polyester is prepared by esterifying oleic acid dimer with an equimolecular amount of a glycol <FORM:1057233/C3/1> wherein R is H or a C1- 20 alkyl group and m is 0 or 1, until between 1 and 2 mols. of water per mol. of acid or glycol is produced, and condensing the product polyester with a C1- 6 aliphatic alcohol or a primary or secondary amine to give a polyester HO-[-X-OOC-Y-COO-]-nXOOC-Y-COR1 where X, Y, and R are the residues respectively of the glycol, the acid, and the alcohol or amine, and n is an integer. In the example the glycol is ethylene glycol, and the polyester is blocked with methanol. The blocked polyester may be added to hydrocarbon oils as an antiwear agent.
GB14110/64A 1964-04-06 1964-04-06 Improved polyester additives for hydrocarbon oil compositions Expired GB1057233A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
GB14110/64A GB1057233A (en) 1964-04-06 1964-04-06 Improved polyester additives for hydrocarbon oil compositions
DE19651570503 DE1570503A1 (en) 1964-04-06 1965-04-02 Process for the preparation of polyesters of the dimer of linoleic acid
SE04374/65A SE333362B (en) 1964-04-06 1965-04-05
FR11963A FR1429103A (en) 1964-04-06 1965-04-05 Advanced additives for oil compositions derived from hydrocarbons
CH471465A CH463118A (en) 1964-04-06 1965-04-05 Process for the production of polyesters and their use
DK174165AA DK119886B (en) 1964-04-06 1965-04-06 Oil-soluble additive for use in hydrocarbon lubricating and fuel oils.
BE680840A BE680840A (en) 1964-04-06 1966-05-11

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB14110/64A GB1057233A (en) 1964-04-06 1964-04-06 Improved polyester additives for hydrocarbon oil compositions

Publications (1)

Publication Number Publication Date
GB1057233A true GB1057233A (en) 1967-02-01

Family

ID=10035170

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14110/64A Expired GB1057233A (en) 1964-04-06 1964-04-06 Improved polyester additives for hydrocarbon oil compositions

Country Status (5)

Country Link
CH (1) CH463118A (en)
DE (1) DE1570503A1 (en)
DK (1) DK119886B (en)
GB (1) GB1057233A (en)
SE (1) SE333362B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0194718A2 (en) * 1985-03-15 1986-09-17 Shell Internationale Researchmaatschappij B.V. Lubricating-oil compositions

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0194718A2 (en) * 1985-03-15 1986-09-17 Shell Internationale Researchmaatschappij B.V. Lubricating-oil compositions
EP0194718A3 (en) * 1985-03-15 1987-05-13 Shell Internationale Research Maatschappij B.V. Lubricating-oil compositions
US4715973A (en) * 1985-03-15 1987-12-29 Shell Oil Company Lubricating oil compositions

Also Published As

Publication number Publication date
SE333362B (en) 1971-03-15
DE1570503A1 (en) 1970-02-05
DK119886B (en) 1971-03-08
CH463118A (en) 1968-09-30

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