GB1056384A - Improvements in high molecular weight polyhydroxy-polyether resins - Google Patents

Improvements in high molecular weight polyhydroxy-polyether resins

Info

Publication number
GB1056384A
GB1056384A GB543164A GB543164A GB1056384A GB 1056384 A GB1056384 A GB 1056384A GB 543164 A GB543164 A GB 543164A GB 543164 A GB543164 A GB 543164A GB 1056384 A GB1056384 A GB 1056384A
Authority
GB
United Kingdom
Prior art keywords
mono
monoglycidyl
bisphenol
formaldehyde
cross
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB543164A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Coatings Co Inc
Original Assignee
Devoe and Raynolds Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Devoe and Raynolds Co Inc filed Critical Devoe and Raynolds Co Inc
Publication of GB1056384A publication Critical patent/GB1056384A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K17/00—Arrangement or mounting of transmissions in vehicles
    • B60K17/04—Arrangement or mounting of transmissions in vehicles characterised by arrangement, location, or kind of gearing
    • B60K17/10—Arrangement or mounting of transmissions in vehicles characterised by arrangement, location, or kind of gearing of fluid gearing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Transportation (AREA)
  • Mechanical Engineering (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

High molecular weight polyhydroxypolyethers of the formula [-CH2CH(OH)CH2OROR1O-]n are prepared by polymerizing one or more mono(hydroxyaliphatic) mono-glycidyl diethers of dihydric phenols of formula <FORM:1056384/C3/1> wherein R is the aromatic residue of a dihydric phenol and R1 is a divalent hydrocarbon or ether group containing at least 2 carbon atoms in the presence of a Lewis acid. Specified R radicals are those derived from resorcinol, hydroquinone and bisphenol. Specified R1 groups are ethyl, isopropyl and -CH2-CH(Ph)-. Suitable Lewis acids are BF3, BF3 complexes, AlCl3, SnCl4, TiCl4 and H2SO4. The reaction is preferably carried out in a ketone, ether or ester solution. The products may be reacted with acid anhydrides, monobasic acids or cross-linking agents, e.g. polyisocyanates, polyepoxides and the reaction products of formaldehyde, or formaldehyde and a alcohol, with urea, melamine, benzoguanamine or phenol. The examples describe the polymerization of (1)-(3) the monoglycidyl mono(hydroxyethyl)-either of bisphenol, (4) the monoglycidyl mono(hydroxypropyl) diether of bisphenol and (7) the monoglycidyl mono(hydroxyethyl)diether of resorcinol. The product of (7) and the mixed product of (1) and (4) were cross-linked with butylated urea formaldehyde, and that of (4) with tolylene diisocyanate.ALSO:Wood, metal and glass are coated with polyhydroxy polyethers comprising polymers of mono (hydroxy-aliphatic) monoglycidyl diethers of dihydric phenols (see Division C3). The polyethers are cross-linked with polyisocyanates, polyepoxides, aminoplast resins alkylated methylol melamine resins, acid anhydrides and unsaturated acids. In Examples (5), (6) and (7) films are prepared on glass and cured by baking.
GB543164A 1963-05-17 1964-02-10 Improvements in high molecular weight polyhydroxy-polyether resins Expired GB1056384A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US28135663A 1963-05-17 1963-05-17

Publications (1)

Publication Number Publication Date
GB1056384A true GB1056384A (en) 1967-01-25

Family

ID=23076942

Family Applications (1)

Application Number Title Priority Date Filing Date
GB543164A Expired GB1056384A (en) 1963-05-17 1964-02-10 Improvements in high molecular weight polyhydroxy-polyether resins

Country Status (2)

Country Link
DE (1) DE1495503B2 (en)
GB (1) GB1056384A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2092593A (en) * 1980-12-18 1982-08-18 Sumitomo Chemical Co Poly(hydroxy ether)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2092593A (en) * 1980-12-18 1982-08-18 Sumitomo Chemical Co Poly(hydroxy ether)

Also Published As

Publication number Publication date
DE1495503B2 (en) 1970-11-12
DE1495503A1 (en) 1968-12-19

Similar Documents

Publication Publication Date Title
US2768153A (en) Process for curing polyepoxides and resulting products
DE1928409C3 (en) Use of curable hydrophilic copolymers as a water-soluble hydrophilic coating to prevent fogging of transparent or reflective surfaces
US3582487A (en) Polyester moulding and coating compositions hardening by ultra-violet radiation in the presence of a benzoin aryl ether photosensitizer
US3420914A (en) Unsaturated polyester compositions and their preparation
DE2534012B2 (en) Process for the production of binders
US5045572A (en) Radiation curable cross linkable compositions containing an aliphatic polyfunctional alkenyl ether
EP0752454A2 (en) Scratch-resistant conductive coatings
EP0104838A2 (en) Phosphate esters of acrylated epoxides
JPS5536212A (en) Thermosetting resin composition
GB1056384A (en) Improvements in high molecular weight polyhydroxy-polyether resins
US3721722A (en) Thickenable unsaturated polyester resin system
GB1317326A (en) Process of production of a binder for aqueous coatings
GB1108790A (en) Compositions comprising phenolaldehyde condensation products and polyhydroxyethers
US3800004A (en) Phenolic based unsaturated polyester resin
DE2028496A1 (en)
US5055357A (en) Radiation curable cross linkable compositions
US5276174A (en) Alk-1-enyloxy carbonates
US3293212A (en) Thermosetting reaction product of hexakis-(alkoxymethyl) melamines and bisphenols
US4303579A (en) Vinyl ester resins having improved color
US2828278A (en) Resin from polyesters and aromatic vinyl compounds
US2843566A (en) Alkenylphenol-aldehyde
US3164564A (en) Unsaturated linear polycarbonate
EP0284888B1 (en) Unsaturated polyester resins, process for their preparation, compositions containing these polyester resins and their use in the preparation of coatings
US3024285A (en) Preparation of biethers of polymethyl-
US3374204A (en) Process for preparing high molecular weight polyhydroxy-polyether resins