GB1056177A - Method for the sequestration of metal ions, and washing compositions - Google Patents

Method for the sequestration of metal ions, and washing compositions

Info

Publication number
GB1056177A
GB1056177A GB39419/63A GB3941963A GB1056177A GB 1056177 A GB1056177 A GB 1056177A GB 39419/63 A GB39419/63 A GB 39419/63A GB 3941963 A GB3941963 A GB 3941963A GB 1056177 A GB1056177 A GB 1056177A
Authority
GB
United Kingdom
Prior art keywords
acid
amino tri
compositions
salt
aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39419/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US229495A external-priority patent/US3278446A/en
Priority claimed from US231596A external-priority patent/US3234124A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1056177A publication Critical patent/GB1056177A/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3817—Acids containing the structure (RX)2P(=X)-alk-N...P (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/386—Polyphosphoric oxyacids, or derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/51—Chelating agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Abstract

Alkaline washing compositions comprise an alkali cleanser (i.e an inorganic material which is alkaline in reaction and possesses cleansing properties) and an amino tri-(alkylidenephosphonic acid) of formula <FORM:1056177/C4-C5/1> wherein X and Y are the same or different and are H or C1-4 alkyl, or a water-soluble salt thereof. Specified alkaline agents are alkali metal and ammonium hydroxides and carbonates, preferably NaOH in a concentration of 1-20% of an aqueous composition. The preferred amino tri-(alkylidene phosphonic acid) is amino tri-(methylphosphonic acid) in the form of its penta-sodium salt (see Division C2). The phosphonic acid component of the compositions acts as a sequestering agent for metal cations (see Division C1). The compositions are used to wash bottles and glassware and may contain an anti-corrosive agent.ALSO:Amino tri(methylphosphonic acid) is prepared by condensing diethyl phosphite with ammonia and formaldehyde in aqueous medium to give hexaethyl amino tri(methylphosphonate) which is hydrolysed with conc. HCl; the pentasodium salt of the acid is prepared by reaction of the acid with aqueous NaOH.ALSO:Compositions containing an amino tri-(alkyldene-phosphonic acid) of formula <FORM:1056177/C1/1> wherein X and Y are H or C1- 4 alkyl or a water-solubl salt thereof are used to sequester heavy metal ions (e.g. Fe+ + +, Fe+ +, Co+ +, Mn+ +) in aqueous solutions.
GB39419/63A 1962-09-04 1963-10-07 Method for the sequestration of metal ions, and washing compositions Expired GB1056177A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22130862A 1962-09-04 1962-09-04
US229495A US3278446A (en) 1962-10-09 1962-10-09 Washing compositions
US231596A US3234124A (en) 1962-10-18 1962-10-18 Sequestration of metal ions

Publications (1)

Publication Number Publication Date
GB1056177A true GB1056177A (en) 1967-01-25

Family

ID=27396929

Family Applications (1)

Application Number Title Priority Date Filing Date
GB39419/63A Expired GB1056177A (en) 1962-09-04 1963-10-07 Method for the sequestration of metal ions, and washing compositions

Country Status (1)

Country Link
GB (1) GB1056177A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353973A2 (en) * 1988-07-30 1990-02-07 Icn Biomedicals Limited Phosphate-free detergents

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353973A2 (en) * 1988-07-30 1990-02-07 Icn Biomedicals Limited Phosphate-free detergents
EP0353973A3 (en) * 1988-07-30 1990-10-17 Icn Biomedicals Limited Phosphate-free detergents

Similar Documents

Publication Publication Date Title
EP0119641B1 (en) Aqueous alkaline cleaning composition
US3720621A (en) Aquenous detergent compositions
US4144185A (en) Method and composition for removing calcium sulfate scale deposits from surfaces
US3234124A (en) Sequestration of metal ions
AU2006346055B2 (en) Alkaline floor cleaning composition and method of cleaning a floor
GB1386746A (en) Use of phosphorus compounds in controlling corrosion of metal parts
US20080015133A1 (en) Alkaline floor cleaning composition and method of cleaning a floor
US3717701A (en) Process for sequestering metal ions by use of an amino carboxylic phosphine
JPS5948866B2 (en) Corrosion inhibitor and inhibition method using the same
US3721629A (en) Method and composition for removing iron stains from porcelain
US3586633A (en) Alkaline cleansing agent
US2618604A (en) Polyphosphate-containing detergent compositions having decreased corrosivity toward aluminum
JPH05239438A (en) Multipurpose scale preventer/remover
GB1483780A (en) Hot-gelling alkali cleaning compositions and process for cleaning surfaces
RU94041205A (en) Method of metal ions isolation from self-precipitating compositions, method of ion-exchange resin regeneration
GB1370111A (en) Quaternary ammonium benzimidazole derivatives as their use as textile treatment agents
US3354092A (en) Ammoniated granular cleaner
JPS61291699A (en) Alkaline cleaner composition
US3910854A (en) Combustion chamber cleaning and corrosion preventing agent
EP0056180A1 (en) Method and composition for inhibiting the amount of oxidation of sulfite in a sulfite containing aqueous gas scrubber medium
GB1056177A (en) Method for the sequestration of metal ions, and washing compositions
JPS59161497A (en) Method of cleaning hard body surface with builder-containingalkali solution
US3350305A (en) Corrosion-inhibited phosphate firefighting solutions and compositions useful for manufacturing them
GB917432A (en) An improved cleaning, and disinfecting or sterilizing process
GB1288369A (en)