GB1055306A - A process for the preparation of substantially linear polyaddition products containing repeating urea groups - Google Patents
A process for the preparation of substantially linear polyaddition products containing repeating urea groupsInfo
- Publication number
- GB1055306A GB1055306A GB592864A GB592864A GB1055306A GB 1055306 A GB1055306 A GB 1055306A GB 592864 A GB592864 A GB 592864A GB 592864 A GB592864 A GB 592864A GB 1055306 A GB1055306 A GB 1055306A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diamine
- acids
- hexane
- polyester
- diisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Artificial Filaments (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Diamine-N-carboxylic acids and diamine-N-sulphinic acids are prepared by reacting diamines or their solutions in polar organic solvents with CO2 or SO2 respectively. It is believed that these acids are N-mono-substituted acids or N,N1-di-substituted acids or a mixture of both. Diamines specified are: ethylene diamine, 1, 2 and 1,3-propylene diamine, 1,4-butylene diamine, 1,6-hexane diamine, decane 1,10-diamine, 2 - methyl - hexane 1: 6-diamine, 3-methhexane 1: 6-diamine, cyclohexane 1,3- or NN1 dimethyl-ethylene diamine, 1,4-N,N1-dimethylhexane diamine, piperazine, 2,5-dimethylpiperazine, xylylene diamines, g ,g 1-diaminopropylether, 1,4-phenylene bis-(p-amino-propylether), g ,g 1 - diaminopropyl methylamine. Examples describe the reaction of (1) CO2 with ethylene diamine and of SO2 with ethylene diamine, (2) CO2 with cyclohexane 1,4-diamine, (3) CO2 with piperazine hexahydrate, (4) CO2 with g : g 1-diaminopropylmethylamine, (7) CO2 with hydrazine hydrate and 1,6-hexane diamine, (8) CO2 with carbodihydrazide and bis-(3-amino-propyl)-methyl amine.ALSO:A process for the production of linear polyureas containing groups of the formula <FORM:1055306/C3/1> (in which R is alkylene, cycloalkylene or aralkylene which may be interrupted by hetero atoms; and R1 is a hydrogen atom or is a hydrocarbon radical which together with R forms a closed ring) which comprises reacting an isocyanate-modified dihydroxyl compound containing terminal -NCO groups (and having a M.W. of at least 500 before modification with the diisocyanate), at -20 DEG C. to +60 DEG C. with a diamine -N- carboxylic acid and/or diamine -N- sulphinic acid suspended or dissolved in a polar solvent. The dihydroxyl compound may be a polyester, polyester amide, polyester ether, polyether, polycarbonate, polythioether or polyacetal. Conventional diisocyanates are listed. The reaction between the dihydroxyl compound and the diisocyanate may be performed in the melt or in solution in an organic solvent. The N-sulphinic acid or N-carboxylic acid may be obtained by reaction of SO2 or CO2 with an organic diamine. In a typical Example (5) a polyester derived from adipic acid, hexane-1,6-diol and 2,2-dimethylpropane-1,3-diol was reacted with diphenylmethane 4,41-diisocyanate in chlorobenzene and added to a suspension of the adduct of g ,g 1-di-(amino-propyl) methylamine in dimethylformamide and the product cast on to a glass plate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF39038A DE1223154B (en) | 1963-02-16 | 1963-02-16 | Process for the preparation of substantially linear polyureas |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1055306A true GB1055306A (en) | 1967-01-18 |
Family
ID=7097597
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB592864A Expired GB1055306A (en) | 1963-02-16 | 1964-02-12 | A process for the preparation of substantially linear polyaddition products containing repeating urea groups |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS494838B1 (en) |
BE (1) | BE643811A (en) |
CA (1) | CA764543A (en) |
DE (1) | DE1223154B (en) |
FR (1) | FR1535415A (en) |
GB (1) | GB1055306A (en) |
IT (1) | IT714702A (en) |
NL (1) | NL6401350A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4469856A (en) * | 1981-10-31 | 1984-09-04 | Bayer Aktiengesellschaft | Non-crystalline polyamine/carbonic acid salt compositions, a process for their preparation and their use for the production of polyurethane ureas, especially foamed coatings |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1495840C3 (en) * | 1964-10-19 | 1978-09-21 | Bayer Ag, 5090 Leverkusen | Process for the production of polyurethane elastomers |
ZA761878B (en) * | 1975-05-05 | 1977-03-30 | Grace W R & Co | Method of coating fabric with polyurethane |
DE2843790A1 (en) * | 1978-10-06 | 1980-04-17 | Bayer Ag | METHOD FOR THE PRODUCTION OF AQUEOUS DISPERSIONS OR SOLUTIONS OF POLYURETHANE-POLYHURANE, THE DISPERSIONS OR SOLUTIONS AVAILABLE BY THIS METHOD, AND THEIR USE |
DE3040088A1 (en) * | 1980-10-24 | 1982-06-16 | Bayer Ag, 5090 Leverkusen | ELASTIC ROUGH FABRIC WITH SUEDE-LIKE LOOK AND METHOD FOR THE PRODUCTION THEREOF |
-
0
- IT IT714702D patent/IT714702A/it unknown
- CA CA764543A patent/CA764543A/en not_active Expired
-
1963
- 1963-02-16 DE DEF39038A patent/DE1223154B/en active Pending
-
1964
- 1964-02-12 GB GB592864A patent/GB1055306A/en not_active Expired
- 1964-02-14 FR FR963746A patent/FR1535415A/en not_active Expired
- 1964-02-14 NL NL6401350A patent/NL6401350A/xx unknown
- 1964-02-14 JP JP39007632A patent/JPS494838B1/ja active Pending
- 1964-02-14 BE BE643811D patent/BE643811A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4469856A (en) * | 1981-10-31 | 1984-09-04 | Bayer Aktiengesellschaft | Non-crystalline polyamine/carbonic acid salt compositions, a process for their preparation and their use for the production of polyurethane ureas, especially foamed coatings |
Also Published As
Publication number | Publication date |
---|---|
BE643811A (en) | 1964-05-29 |
DE1223154B (en) | 1966-08-18 |
JPS494838B1 (en) | 1974-02-04 |
IT714702A (en) | |
CA764543A (en) | 1967-08-01 |
FR1535415A (en) | 1968-08-09 |
NL6401350A (en) | 1964-08-17 |
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