GB1048992A - Process for the production of cellular polyurethanes - Google Patents
Process for the production of cellular polyurethanesInfo
- Publication number
- GB1048992A GB1048992A GB28992/63A GB2899263A GB1048992A GB 1048992 A GB1048992 A GB 1048992A GB 28992/63 A GB28992/63 A GB 28992/63A GB 2899263 A GB2899263 A GB 2899263A GB 1048992 A GB1048992 A GB 1048992A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radicals
- diisocyanate
- radical
- polyhydroxy
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Cellular polyurethanes are prepared by reacting a polyhydroxy polyoxyalkylene glycol ether of M.W. at least 500 with an organic polyisocyanate in the presence of (a) water and/or a non-aqueous blowing agent, (b) a catalyst system for the reaction which comprises at least one organic tin compound and/or at least one organic tertiary amine and (c) a foam-stabilizer consisting of a siloxane-oxyalkylene block copolymer of the general formula <FORM:1048992/C3/1> in which a is from 4 to 10, b is from 2 to 9, R and R1 are hydrocarbon radicals which may be the same or different throughout the polymer molecule, the radicals R attached to any one silicon atom being the same or different, Z is a polyoxyalkylene radical represented by:- -(C2H4O)m(C3H6O)pR11 wherein m+p lies between 15 and 60 and p is between 0.4m and 3m and R11 is a hydrocarbon radical which may be the same or different in various Z residues. The radicals R and R1 in the siloxane-oxyalkylene block copolymer are preferably methyl radicals, but may also be ethyl vinyl or phenyl radicals. R11 is suitably a C1- 6 alkyl radical and may also be a phenyl, cresyl or benzyl radical. The preferred polyhydroxy polyoxyalkylene glycols are those prepared by reacting 1,2-propylene oxide with such compounds as ethylene glycol, 1,2-propylene glycol, butane diol, diethylene glycol, glycerol, trimethylolpropane, hexane triol, pentaerythritol, alpha methyl glucoside and sorbitol. Mixtures of polyhydroxy ethers may be used. Suitable polyisocyanates are hexamethylene diisocyanate, xylene diisocyanate, 4,41-diisocyanato-diphenylmethane, a mixture of 80% toluene, 2,4-diisocyanate and 20% toluene - 2,6 - diisocyanate and polyalkylpolyphenyl isocyanates. The blowing agents may be water, trichlorofluoromethane, dichlorofluoromethane or methylene dichloride. Suitable tin catalysts are stannous octoate, stannous oleate, the stannous salts of gamma(2-methyl, 4-chlorophenoxy) butyric acid and gamma(t.-butylphenoxy) butyric acid and dibutyl tin dilaurate. Triethylamine, triethanolamine, N-methyl morpholine, triethylene diamine and N,N,N1,N1-tetramethyl-1,3-butane diamine are suitable tertiary amine catalysts. Mixtures of catalysts may be used, a preferred mixture being one of a tin salt and triethylene diamine.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL136878D NL136878C (en) | 1963-07-22 | ||
GB28992/63A GB1048992A (en) | 1963-07-22 | 1963-07-22 | Process for the production of cellular polyurethanes |
FI1561/64A FI43498B (en) | 1963-07-22 | 1964-07-21 | |
SE8874/64A SE310786B (en) | 1963-07-22 | 1964-07-21 | |
ES0302288A ES302288A1 (en) | 1963-07-22 | 1964-07-21 | Process for the production of cellular polyurethanes |
NL6408400A NL6408400A (en) | 1963-07-22 | 1964-07-22 | |
BE650844D BE650844A (en) | 1963-07-22 | 1964-07-22 | |
DEL48350A DE1233133B (en) | 1963-07-22 | 1964-07-22 | Process for the production of polyurethane foams |
FR982565A FR1455031A (en) | 1963-07-22 | 1964-07-22 | Polyurethanes production process |
DK364764AA DK116903B (en) | 1963-07-22 | 1964-07-22 | Process for the production of cellular polyurethanes. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB28992/63A GB1048992A (en) | 1963-07-22 | 1963-07-22 | Process for the production of cellular polyurethanes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1048992A true GB1048992A (en) | 1966-11-23 |
Family
ID=10284530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28992/63A Expired GB1048992A (en) | 1963-07-22 | 1963-07-22 | Process for the production of cellular polyurethanes |
Country Status (9)
Country | Link |
---|---|
BE (1) | BE650844A (en) |
DE (1) | DE1233133B (en) |
DK (1) | DK116903B (en) |
ES (1) | ES302288A1 (en) |
FI (1) | FI43498B (en) |
FR (1) | FR1455031A (en) |
GB (1) | GB1048992A (en) |
NL (2) | NL6408400A (en) |
SE (1) | SE310786B (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE584911A (en) * | 1958-11-24 |
-
0
- NL NL136878D patent/NL136878C/xx active
-
1963
- 1963-07-22 GB GB28992/63A patent/GB1048992A/en not_active Expired
-
1964
- 1964-07-21 SE SE8874/64A patent/SE310786B/xx unknown
- 1964-07-21 ES ES0302288A patent/ES302288A1/en not_active Expired
- 1964-07-21 FI FI1561/64A patent/FI43498B/fi active
- 1964-07-22 NL NL6408400A patent/NL6408400A/xx unknown
- 1964-07-22 BE BE650844D patent/BE650844A/xx unknown
- 1964-07-22 DK DK364764AA patent/DK116903B/en unknown
- 1964-07-22 DE DEL48350A patent/DE1233133B/en active Pending
- 1964-07-22 FR FR982565A patent/FR1455031A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE650844A (en) | 1964-11-16 |
FI43498B (en) | 1970-12-31 |
ES302288A1 (en) | 1965-02-16 |
NL136878C (en) | |
NL6408400A (en) | 1965-01-25 |
DK116903B (en) | 1970-02-23 |
SE310786B (en) | 1969-05-12 |
DE1233133B (en) | 1967-01-26 |
FR1455031A (en) | 1966-04-01 |
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