GB1041910A - Film-forming polymers of maleic esters, crotonic acid and vinyl acetate - Google Patents

Film-forming polymers of maleic esters, crotonic acid and vinyl acetate

Info

Publication number
GB1041910A
GB1041910A GB40325/64A GB4032564A GB1041910A GB 1041910 A GB1041910 A GB 1041910A GB 40325/64 A GB40325/64 A GB 40325/64A GB 4032564 A GB4032564 A GB 4032564A GB 1041910 A GB1041910 A GB 1041910A
Authority
GB
United Kingdom
Prior art keywords
vinyl acetate
crotonic acid
terpolymer
methyl
neutralized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40325/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alberto Culver Co
Original Assignee
Alberto Culver Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alberto Culver Co filed Critical Alberto Culver Co
Publication of GB1041910A publication Critical patent/GB1041910A/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/16—Esters having free carboxylic acid groups, e.g. monoalkyl maleates or fumarates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Medicinal Preparation (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A neutralized terpolymer is formed by polymerizing vinyl acetate, crotonic acid and a half-ester of maleic acid which is selected from the methyl to the lauryl esters. The terpolymer may contain 3-8% of crotonic acid, 35-85% vinyl acetate and 8-65% of monoalkyl maleate and may be formed by refluxing the monomers for 5-20 hours in ethyl alcohol in the presence of benzoyl peroxide. The terpolymer may be neutralized with 2-amino-2-methyl-1,3-propane diol.ALSO:A hair spray comprises a neutralized terpolymer which is formed by polymerizing vinyl acetate, crotonic acid and a half ester of maleic acid which is selected from the methyl to the lauryl esters. The terpolymer may be neutralized with 2-amino-2 methyl-1, 3-propanediol, dissolved in ethyl alcohol and sprayed using a fluoro-carbon propellant.
GB40325/64A 1964-07-22 1964-10-02 Film-forming polymers of maleic esters, crotonic acid and vinyl acetate Expired GB1041910A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US38453564A 1964-07-22 1964-07-22

Publications (1)

Publication Number Publication Date
GB1041910A true GB1041910A (en) 1966-09-07

Family

ID=23517705

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40325/64A Expired GB1041910A (en) 1964-07-22 1964-10-02 Film-forming polymers of maleic esters, crotonic acid and vinyl acetate

Country Status (1)

Country Link
GB (1) GB1041910A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2453655A1 (en) * 1974-11-12 1976-05-13 Wacker Chemie Gmbh COPOLYMERS OF VINYL ACETATE, MALEIC ACID DIAL FOLESTER, UNSATURATED ESTERS WITH HYDROPHILIC GROUP AND CROTONIC ACID
EP0634428A2 (en) * 1993-07-12 1995-01-18 National Starch and Chemical Investment Holding Corporation A method for manufacture of polymers

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2453655A1 (en) * 1974-11-12 1976-05-13 Wacker Chemie Gmbh COPOLYMERS OF VINYL ACETATE, MALEIC ACID DIAL FOLESTER, UNSATURATED ESTERS WITH HYDROPHILIC GROUP AND CROTONIC ACID
EP0634428A2 (en) * 1993-07-12 1995-01-18 National Starch and Chemical Investment Holding Corporation A method for manufacture of polymers
EP0634428A3 (en) * 1993-07-12 1995-03-22 Nat Starch Chem Invest A method for manufacture of polymers.

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