GB1041024A - Anion exchange resin - Google Patents
Anion exchange resinInfo
- Publication number
- GB1041024A GB1041024A GB20677/63A GB2067763A GB1041024A GB 1041024 A GB1041024 A GB 1041024A GB 20677/63 A GB20677/63 A GB 20677/63A GB 2067763 A GB2067763 A GB 2067763A GB 1041024 A GB1041024 A GB 1041024A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitrogen
- polyphenylene ethers
- groups
- sulphur
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003957 anion exchange resin Substances 0.000 title abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229920001955 polyphenylene ether Polymers 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Chemical group 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 229910052739 hydrogen Chemical group 0.000 abstract 2
- 239000001257 hydrogen Chemical group 0.000 abstract 2
- 229910052698 phosphorus Chemical group 0.000 abstract 2
- 239000011574 phosphorus Chemical group 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 abstract 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000005997 bromomethyl group Chemical group 0.000 abstract 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical group 0.000 abstract 1
- 125000004970 halomethyl group Chemical group 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 1
- 150000003003 phosphines Chemical group 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
- C08G65/485—Polyphenylene oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
Abstract
The invention comprises polyphenylene ethers of formula <FORM:1041024/C3/1> wherein the oxygen of one unit is attached directly to the para-position of the phenylene nucleus of the adjacent unit, Y is nitrogen, sulphur or phosphorus, R1 is a hydrocarbon radical which is monovalent when joined to one Y group or polyvalent when joined to more than one Y group or may be hydroxy aliphatic when Y is nitrogen, or hydrogen when Y is nitrogen and p is 2; n is at least 10, preferably at least 100; m is a number which is an average for the molecule of from 0.01 to 2; p is 2 or 3 and q is 2 when Y is nitrogen, p is 3 and q is 2 when Y is phosphorus, and p is 2 and q is 1 when Y is sulphur; and R is hydrogen, halogen or a hydrocarbon, halohydrocarbon, hydrocarbonoxy or halohydrocarbonoxy radical. The polymers are prepared by reacting polyphenylene ethers having halomethyl groups (see Application No. 20675/63) with ammonia, amines, organic sulphides, tertiary phosphines or bisphosphines followed by reaction with a strong base. In examples, polyphenylene ethers containing bromomethyl groups and chloromethyl groups are reacted with trimethyl amine, N,N,N1,N1 - tetramethylethylenediamine, N,N-dimethylaminoethanol, dimethylsulphide, tri-n-butyl phosphine, and N,N,N1,N1-tetramethyl-1,3-butanediamine and then with sodium hydroxide. The polymers may be used as anion exchange resins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB20677/63A GB1041024A (en) | 1963-05-23 | 1963-05-23 | Anion exchange resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB20677/63A GB1041024A (en) | 1963-05-23 | 1963-05-23 | Anion exchange resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1041024A true GB1041024A (en) | 1966-09-01 |
Family
ID=10149844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20677/63A Expired GB1041024A (en) | 1963-05-23 | 1963-05-23 | Anion exchange resin |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1041024A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0130964A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Amino ketone cross-linked polyphenylene oxide |
| EP0130966A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyphenylene oxide |
| EP0130963A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyarylene oxide membranes |
| EP0130965A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyphenylene oxide |
| EP0305860A1 (en) * | 1987-09-03 | 1989-03-08 | General Electric Company | Polyphenylene ether amine salts, flame retardant extrudate of blends thereof and method of making |
-
1963
- 1963-05-23 GB GB20677/63A patent/GB1041024A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0130964A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Amino ketone cross-linked polyphenylene oxide |
| EP0130966A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyphenylene oxide |
| EP0130963A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyarylene oxide membranes |
| EP0130965A1 (en) * | 1983-06-30 | 1985-01-09 | Monsanto Company | Cross-linked polyphenylene oxide |
| EP0305860A1 (en) * | 1987-09-03 | 1989-03-08 | General Electric Company | Polyphenylene ether amine salts, flame retardant extrudate of blends thereof and method of making |
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