GB1035876A - Paper sizing - Google Patents
Paper sizingInfo
- Publication number
- GB1035876A GB1035876A GB3334964A GB3334964A GB1035876A GB 1035876 A GB1035876 A GB 1035876A GB 3334964 A GB3334964 A GB 3334964A GB 3334964 A GB3334964 A GB 3334964A GB 1035876 A GB1035876 A GB 1035876A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- water
- mixture
- emulsified
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Silicon Polymers (AREA)
Abstract
Emulsions of organopolysiloxanes, for use in sizing paper (see Division D2), are made as follows: (A) a 94/6 mixture of methylhydrogendichlorosilan and trimethylmonochlorosilane is hydrolysed to give an oil of 20 cS viscosity, octamethyl-cyclotetrasiloxane is treated with bleaching earth and heated at 120 DEG C. to a viscosity of 1000 cS, then two oils are mixed in equal amounts and emulsified in water with cetylbenzyldimethyl-ammonium chloride, glycocoll and hydrochloric acid; (B) a 90/10 mixture of methylhydrogendichlorosilane and trimethylchlorosilane is hydrolysed to a thinly liquid oil, which is emulsified in water with dodecylamine, tetrabromoethane, aminocaproic acid and hydrochloric acid; (C) 9 parts of methyltrichlorosilane, 1 part of dimethyldichlorosilane, 8 parts of toluene and 2 parts of n-butanol are added to a mixture of 40 parts of water and 20 parts of toluene, a silicone-resin solution is obtained by hydrolysis and subsequent neutralization with sodium bicarbonate, solvent is distilled off to 50% solids, 36 parts of the silicone oil B are mixed with 8 parts of this solution and emulsified in water with cetylbenzyldimethylammonium chloride, glutamic acid and hydrochloric acid; (D) a mixture of 60.4 parts of methylhydrogendichlorosilane, 34.6 parts of dimethyldichlorosilane and 5 parts of trimethylmonochlorosilane is hydrolysed to a thin oil, which is emulsified in water with cetylbenzyldimethylammonium chloride, hydrochloric acid and aminopropionic acid; and (E) an equimolar mixture of methyltrichlorosilane, dimethyldichlorosilane, phenyltrichlorosilane and diphenyldichlorosilane is hydrolysed in a mixture of water, butanol and cyclohexanol, the product washed with water and concentrated to 50% by distilling off solvent, 38 parts of silicone oil B are mixed with 4 parts of this resin solution and emulsified in water with dodecylamine, tetrabromoethane, glycocoll and hydrochloric acid.ALSO:Paper is sized by adding to the pulp an aqueous emulsion of linear organopolysiloxane in which the end units are R2 (OH)SiO 1/2 , (CH3)2 (H)SiO 1/2 or (CH3)3SiO 1/2 , 50 to 100% of the siloxane units are R(H)SiO, and all remaining units are R2SiO, in which formulae each R is alkyl or aryl, in amount equivalent of 0.01 to 5 parts of organosiloxane by weight per hundred parts of air-dried cellulose pulp. The linear organopolysiloxane may be mixed with up to 10% by weight of a cross-linked or branched organopolysiloxane of units RSiO 3/2 and R2SiO. The emulsifier in the emulsion may be of the cation-active type. The emulsion may also contain a metal salt, e.g. dibutyltin dilaurate, dioctyltin dimaleate or compounds of lead, cobalt, zinc, titanium or cerium, to accelerate cure or a watersoluble prepolymer of a synthetic resin, e.g. polyethyleneimine, urea-formaldehyde, melamineformaldehyde, ethyleneurea-formaldehyde, N-alkylurea-formaldehyde, guaridine-formaldehyde, dicyandiamide-formaldehyde, epoxide resin or a product of reaction of a polyamine with epichlorohydrin, dichlorohydrin or an epoxide resin. Fillers may be incorporated in the pulp, e.g. kaolin, calcium silicate, calcium sulphate, barium sulphate, talc, chalk, titanium dioxide, zinc sulphide or amorphous silica.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF0040504 | 1963-08-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1035876A true GB1035876A (en) | 1966-07-13 |
Family
ID=7098258
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3334964A Expired GB1035876A (en) | 1963-08-16 | 1964-08-14 | Paper sizing |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE651846A (en) |
DE (1) | DE1546248A1 (en) |
GB (1) | GB1035876A (en) |
LU (1) | LU46625A1 (en) |
NL (1) | NL6409346A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1088939A1 (en) * | 1999-09-29 | 2001-04-04 | Dow Corning Toray Silicone Co., Ltd. | Printing paper sizing agent composition |
CN103204993A (en) * | 2013-04-16 | 2013-07-17 | 江苏大学 | Preparation method of methyl silicone resin |
CN103204994A (en) * | 2013-04-16 | 2013-07-17 | 江苏大学 | Preparation method of phenyl silicon resin |
-
1963
- 1963-08-16 DE DE19631546248 patent/DE1546248A1/en active Pending
-
1964
- 1964-07-27 LU LU46625D patent/LU46625A1/xx unknown
- 1964-08-13 NL NL6409346A patent/NL6409346A/xx unknown
- 1964-08-14 BE BE651846D patent/BE651846A/xx unknown
- 1964-08-14 GB GB3334964A patent/GB1035876A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1088939A1 (en) * | 1999-09-29 | 2001-04-04 | Dow Corning Toray Silicone Co., Ltd. | Printing paper sizing agent composition |
CN103204993A (en) * | 2013-04-16 | 2013-07-17 | 江苏大学 | Preparation method of methyl silicone resin |
CN103204994A (en) * | 2013-04-16 | 2013-07-17 | 江苏大学 | Preparation method of phenyl silicon resin |
CN103204993B (en) * | 2013-04-16 | 2015-06-10 | 江苏大学 | Preparation method of methyl silicone resin |
Also Published As
Publication number | Publication date |
---|---|
NL6409346A (en) | 1965-02-17 |
BE651846A (en) | 1964-12-01 |
DE1546248A1 (en) | 1969-07-17 |
LU46625A1 (en) | 1964-09-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3355424A (en) | Method for the preparation of aminoalkylsiloxane copolymers | |
BR8305030A (en) | SILICONE COMPOSITION WITHOUT SOLVENT, CONTROLLED RELEASE AND ITS PREPARATION PROCESS | |
ATE64743T1 (en) | AQUEOUS EMULSIONS OF ORGANOPOLYSILOXANE AND USE OF SUCH EMULSIONS. | |
DE3886998D1 (en) | Process for the production of silicone resin powders. | |
KR830003546A (en) | Process for preparing curable composition | |
EP0291213A3 (en) | Organopolysiloxane microemulsion, process for its production and application thereof | |
KR910000938A (en) | Odorless UV curable organopolysiloxane release coating composition and coating method thereof | |
KR900018282A (en) | Silicone bubble control composition | |
KR830006370A (en) | Silicone coating compositions and coated products used in unprimed plastic substrates | |
KR970042845A (en) | Aqueous silicone emulsion to form silicone elastomer with enhanced adhesion to the support | |
US5025073A (en) | One part heat curable organopolysiloxane compositions | |
ATE143044T1 (en) | PLATINUM CATALYST AND CURED ORGANOPOLYSILOXANE MATERIAL CONTAINING THIS PLATINUM CATALYST | |
US6326061B1 (en) | Aminosiloxane polyether polymers | |
US5484871A (en) | Organopolysiloxanes containing hydrophilic groups | |
GB1035876A (en) | Paper sizing | |
US2863897A (en) | Method of preparing hydroxyl endblocked organopolysiloxane fluids | |
GB1105401A (en) | Organopolysiloxane release materials | |
US3132167A (en) | Process for preparing linear silanol chain-stopped diorganopolysiloxanes | |
US3436251A (en) | Process for rendering paper abrasion resistant,adhesive and water-repellent employing siloxane composition | |
GB1066550A (en) | Process for the manufacture of polyorganosiloxane elastomers | |
US3923736A (en) | Room temperature vulcanizable organopolysiloxanes | |
US2542334A (en) | Condensation of siloxanes | |
US2963501A (en) | Organosilyl peroxides | |
GB945181A (en) | Improvements in or relating to organosilicon compounds | |
US3296198A (en) | Curable organopolysiloxane compositions |