GB1033007A - Process for preparing polymers containing oxymethylene groups - Google Patents

Process for preparing polymers containing oxymethylene groups

Info

Publication number
GB1033007A
GB1033007A GB3197363A GB3197363A GB1033007A GB 1033007 A GB1033007 A GB 1033007A GB 3197363 A GB3197363 A GB 3197363A GB 3197363 A GB3197363 A GB 3197363A GB 1033007 A GB1033007 A GB 1033007A
Authority
GB
United Kingdom
Prior art keywords
chloride
affording
components
cations
halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3197363A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toyo Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Rayon Co Ltd filed Critical Toyo Rayon Co Ltd
Publication of GB1033007A publication Critical patent/GB1033007A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/06—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18—Copolymerisation of aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18—Copolymerisation of aldehydes or ketones
    • C08G2/22—Copolymerisation of aldehydes or ketones with epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18—Copolymerisation of aldehydes or ketones
    • C08G2/26—Copolymerisation of aldehydes or ketones with compounds containing carbon-to-carbon unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Catalysts (AREA)

Abstract

Trioxane is polymerized or copolymerized with not more than 20 mol. per cent of at least one monomer selected from alkylene oxides, cyclic formals, cyclic carbonates, cyclic esters, polybasic acid anhydrides and vinyl compounds, using a catalyst comprising (1) at least one halide of boron, aluminium, iron, tin or antimony and either (2a) at least one non-metal halide capable of affording sulphonium cations or capable of affording phosphonium cations or (2b) at least one oxygen-containing heterocyclic compound or both (2a) and (2b). With components (1) and (2b) at least one of acetyl chloride, trionyl chloride and phosphoric oxychloride is used as activator. Polymerization is carried out in an inert solvent, in the molten state, or in solid phase, at temperatures in the range 0-100 DEG C. and at presence ranging from high vacuum to superatmospheric.ALSO:A trioxane polymerization catalyst comprises (1) at least one halide of boron, aluminium, iron, tin or antimony and either (2a) at least one non-metal halide capsule of affording sulphonium cations or capable of affording phosphonium cations or (2b) at least one oxygen-containing heterocyclic compound, on both (2a) and (2b). Compound (1) may be BF3AlCl3, FeCl3, SnCl4, ShCl5. (2a) may be thionyl chloride, sulfuryl chloride, where sulphonic acid halides, benzene sulfuryl chloride, phosphorous oxychloride, phosphorus trichloride, phosphorus pentachloride, (CH3)4PCl or C6H5 POCl2 (2b) may be an alkylene oxide, styrene oxide, epichlorohydrin, ethylene carbonate or lactone. (Examples are given). With components (1) and (2b) these may be used as activator (3) at least one of acetyl chloride, through chloride, phosphorous oxychloride. The catalyst components may be used in proportions equivalent of component (1) to 0.5-20 equivalents of (2a), (2b) or (2a)+(2b) and up to 50 equivalents of components (3) when used.
GB3197363A 1962-08-13 1963-08-13 Process for preparing polymers containing oxymethylene groups Expired GB1033007A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP3336862 1962-08-13
JP3336762 1962-08-13
JP4523262 1962-09-12
JP3928562 1962-09-12

Publications (1)

Publication Number Publication Date
GB1033007A true GB1033007A (en) 1966-06-15

Family

ID=41020977

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3197363A Expired GB1033007A (en) 1962-08-13 1963-08-13 Process for preparing polymers containing oxymethylene groups

Country Status (3)

Country Link
DE (1) DE1301543B (en)
FR (1) FR1377361A (en)
GB (1) GB1033007A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3418289A (en) * 1965-10-12 1968-12-24 Du Pont Polymerization of 2,2-dialkyl-3-propiolactones using teritary sulfonium salts as initiators

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1271297A (en) * 1916-03-08 1918-07-02 Jewelers Supply Company Safety-catch for pins or brooches.
AT220366B (en) * 1959-01-27 1962-03-26 Hoechst Ag Process for the production of high molecular weight, thermoplastic polyacetals
FR1271297A (en) * 1959-08-29 1961-09-08 Degussa Process for preparing thermally and chemically stable polyoxymethylenes

Also Published As

Publication number Publication date
FR1377361A (en) 1964-11-06
DE1301543B (en) 1969-08-21

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