GB1032169A - A method of forming rigid structures, and structures formed thereby - Google Patents

A method of forming rigid structures, and structures formed thereby

Info

Publication number
GB1032169A
GB1032169A GB47013/64A GB4701364A GB1032169A GB 1032169 A GB1032169 A GB 1032169A GB 47013/64 A GB47013/64 A GB 47013/64A GB 4701364 A GB4701364 A GB 4701364A GB 1032169 A GB1032169 A GB 1032169A
Authority
GB
United Kingdom
Prior art keywords
particles
nickel
resin
mould
thermosetting resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB47013/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JAMES ARTHUR FARRELL
Original Assignee
JAMES ARTHUR FARRELL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19641504261 priority Critical patent/DE1504261A1/en
Application filed by JAMES ARTHUR FARRELL filed Critical JAMES ARTHUR FARRELL
Priority to GB47013/64A priority patent/GB1032169A/en
Publication of GB1032169A publication Critical patent/GB1032169A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/007Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/34Moulds, cores, or mandrels of special material, e.g. destructible materials
    • B28B7/344Moulds, cores, or mandrels of special material, e.g. destructible materials from absorbent or liquid- or gas-permeable materials, e.g. plaster moulds in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
    • B28B7/34Moulds, cores, or mandrels of special material, e.g. destructible materials
    • B28B7/346Manufacture of moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/38Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B29C33/3814Porous moulds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • C04B41/5144Metallising, e.g. infiltration of sintered ceramic preforms with molten metal with a composition mainly composed of one or more of the metals of the iron group
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/63Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • C04B41/69Metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00939Uses not provided for elsewhere in C04B2111/00 for the fabrication of moulds or cores

Abstract

Rigid bodies are formed by thinly coating individual particles of finely powdered material with a thermosetting resin, compacting the material to form a porous body, partially curing the resin at room temperature and then completing the curing in stages at progressively elevated temperatures. The pores of the body thus formed may be partially or completely filled with a metal e.g. nickel by chemical nickel plating or by an atmosphere of nickel carbonyl. In one example a porous body of finely divided steel, prepared as above, was sensitized by a three minute dip in a bath containing 400 cc of hydroquinone, 100 cc of Pyrocatechol and 1000 cc of acetone and then activated by a two minute bath of 10 gms of stannous chloride 40 cc hydrochloric acid, and 1000 cc distilled water. The thus treated body was then placed in a chemical nickel plating bath composed of nickel sulphate (0.08 moles/litre), sodium hypophosphite (0.23 moles/litre), lactic acid (0.3 moles/litre) and propionic acid (0.003 moles/litre) for 16 hours after which the pores were completely filled. In a second example a porous body of glass was treated as above and then chemically plated with nickel for 20 minutes at 190 DEG F in a bath of 7 ozs of nickel chloride, 1 1/2 ozs sodium hypophosphite, 1 1/2 ozs sodium litrate and 1 gallon of water. This was insufficient to completely fill the pores and this process resulted in a porous body.ALSO:Rigid structures are formed by applying a very thin film of a thermosetting resin to the surface of finely-divided individual glass particles, compacting the particles to form a porous preform, partially using the resin at room temperature and finally completely curing the resin in stages at progressively elevated temperatures. The pores of the body thus formed may be filled with a second thermosetting resin, or may be completely or partially filled with metal (nickel) by a chemical plating process or by an atmosphere of e.g. nickel carbonyl. In one embodiment a porous mould is made by coating the particles with a thermosetting resin dissolved in a solvent, evaporating the solvent, and manually applying the coated particles to a shaping pattern or mould. The whole is then enclosed in a flexible impervious bag and further consolidated after which the bag is removed and the resin pre-cured and then cured in stages as stated above. The mould is preferably composed of strata of powdered material having different sizes the finest being at the operative surface of the mould whilst the coarser particles comprise the body of the mould (see Fig. 5, not shown).ALSO:Individual particles of finely divided powdered material are coated with a thermosetting resin by placing the particles in a cloth bag or the like, immersing the bag in a vessel of resin, which contains a solvent, and ultrasonically vibrating the vessel. The resin solution is then allowed to drain off the coated particles after which the solvent in the coating is evaporated.
GB47013/64A 1964-11-17 1964-11-18 A method of forming rigid structures, and structures formed thereby Expired GB1032169A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19641504261 DE1504261A1 (en) 1964-11-17 1964-11-17 Porous solid body and method of shaping the same
GB47013/64A GB1032169A (en) 1964-11-17 1964-11-18 A method of forming rigid structures, and structures formed thereby

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEF0044461 1964-11-17
GB47013/64A GB1032169A (en) 1964-11-17 1964-11-18 A method of forming rigid structures, and structures formed thereby

Publications (1)

Publication Number Publication Date
GB1032169A true GB1032169A (en) 1966-06-08

Family

ID=34634942

Family Applications (1)

Application Number Title Priority Date Filing Date
GB47013/64A Expired GB1032169A (en) 1964-11-17 1964-11-18 A method of forming rigid structures, and structures formed thereby

Country Status (2)

Country Link
DE (1) DE1504261A1 (en)
GB (1) GB1032169A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2284378A (en) * 1993-12-01 1995-06-07 Technology Limited Bronzepalm Flooring tiles & flooring system
GB2312184A (en) * 1996-04-17 1997-10-22 David John Darby Making a durable sand mould
WO2010136433A2 (en) 2009-05-25 2010-12-02 Airbus Operations Gmbh Device and method for producing a composite component

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4879143A (en) * 1985-12-06 1989-11-07 Rang Kg Haus Moderner Fussboden Process for the production of floor covering
DK167254B1 (en) * 1988-07-21 1993-09-27 Hartmann As Brdr PROCEDURE FOR THE PREPARATION OF FORMED ARTICLES OF A FLUIDIZED CELLULOSE FIBER MATERIAL
JPH10509665A (en) * 1994-11-02 1998-09-22 ウニポール・アクチェンゲゼルシャフト Apparatus for directing fluid between a chamber and a channel bounded by a hard surface, and a method of manufacturing the apparatus

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2284378A (en) * 1993-12-01 1995-06-07 Technology Limited Bronzepalm Flooring tiles & flooring system
GB2284378B (en) * 1993-12-01 1998-03-11 Technology Limited Bronzepalm Flooring system
GB2312184A (en) * 1996-04-17 1997-10-22 David John Darby Making a durable sand mould
GB2312184B (en) * 1996-04-17 2001-01-17 David John Darby Making a mould
WO2010136433A2 (en) 2009-05-25 2010-12-02 Airbus Operations Gmbh Device and method for producing a composite component
WO2010136433A3 (en) * 2009-05-25 2011-04-07 Airbus Operations Gmbh Device and method for producing a composite component
CN102448709A (en) * 2009-05-25 2012-05-09 空中客车作业有限公司 Device and method for producing a composite component

Also Published As

Publication number Publication date
DE1504261A1 (en) 1969-09-25

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