GB1031222A - Catalytic hydrocarbon conversion - Google Patents

Catalytic hydrocarbon conversion

Info

Publication number
GB1031222A
GB1031222A GB2860/63A GB286063A GB1031222A GB 1031222 A GB1031222 A GB 1031222A GB 2860/63 A GB2860/63 A GB 2860/63A GB 286063 A GB286063 A GB 286063A GB 1031222 A GB1031222 A GB 1031222A
Authority
GB
United Kingdom
Prior art keywords
carrier
group metal
final catalyst
naphthenes
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2860/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Socony Mobil Oil Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Socony Mobil Oil Co Inc filed Critical Socony Mobil Oil Co Inc
Publication of GB1031222A publication Critical patent/GB1031222A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/387—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation of cyclic compounds containing non six-membered ring to compounds containing a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Hydrocarbon molecules are dehydrogenated in the presence of hydrogen and a catalyst comprising a mechanical mixture of particles of less than 100a in diameter of (a) an alumina carrier having a Pt group metal deposited thereon in such an amount that the final catalyst will contain 0.05 to 5% and (b) a porous inert carrier having a R.E. metal oxide thereon in such an amount that the final catalyst contains 0.1 to 40%, the relative weight fractions of components (a) and (b) being between 0.1 and 0.9. Reference is made to reforming naphthenes, gasoline and kerosene, dehydrogenation of naphthenes, paraffins and butenes and dehydroisomerization of naphthenes, e.g. methyl cyclopentane, paraffins, indanes and tetralins. Reaction conditions and product distribution data are given.ALSO:A hydrocarbon conversion catalyst comprises a mechanical mixture of particles of less than 100 microns in diameter of (a) a carrier comprising predominantly alumina supporting a platinium group metal such that the final catalyst contains between 0.05 and 5% of a platinum group metal and (b) a porous inert carrier containing a valve earth metal oxide in such an amount that the final catalyst contains between 0.1 and 40%, the relative weight fractions of (a) and (b) being between 0.1 and 0.9. Platinum group metal is defined as Pt, Pd, Ru, Rh, Os and Ir. Rare earth metal is defined as elements 57 to 71 inclusive and Sc and Y. Specified rare earth metals are cerium, lanthanum, praseodymium neodyrum, samarium, ytterbium, gadolinium an yttrium or mixtures thereof. Component (a) may include any allotropic form of Al2O3 having e.g. a surface area of at least 10 sq.m/gm. and component (b) may have as a support silica gel, alumina, clays, bauxite, pumice stone, kaolin, charcoal, kieselguhr, porous glass, magnesia, asbestos, coke and magnesium sulphate. The carrier may contain Cl or F. Mechanical separation of components and regeneration details are given.
GB2860/63A 1962-01-30 1963-01-23 Catalytic hydrocarbon conversion Expired GB1031222A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US169934A US3223617A (en) 1962-01-30 1962-01-30 Catalytic hydrocarbon conversion

Publications (1)

Publication Number Publication Date
GB1031222A true GB1031222A (en) 1966-06-02

Family

ID=22617817

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2860/63A Expired GB1031222A (en) 1962-01-30 1963-01-23 Catalytic hydrocarbon conversion

Country Status (3)

Country Link
US (1) US3223617A (en)
DE (1) DE1442850A1 (en)
GB (1) GB1031222A (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3410909A (en) * 1966-06-27 1968-11-12 Eastman Kodak Co Catalytic synthesis of ketones from aldehydes
US3915845A (en) * 1973-12-06 1975-10-28 Universal Oil Prod Co Hydrocarbon conversion with a multimetallic catalytic composite
US4417089A (en) * 1982-09-01 1983-11-22 Phillips Petroleum Company Hydroisomerization
US5248409A (en) * 1992-02-27 1993-09-28 Exxon Research & Engineering Company Metal on rare earth modified silica alumina as hydrocarbon conversion catalyst
US5208200A (en) * 1992-02-27 1993-05-04 Exxon Research And Engineering Co. Noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst
US5254518A (en) * 1992-07-22 1993-10-19 Exxon Research & Engineering Company Group IVB oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst
US5565086A (en) * 1994-11-01 1996-10-15 Exxon Research And Engineering Company Catalyst combination for improved wax isomerization
US20040171900A1 (en) * 2003-02-28 2004-09-02 Conocophillips Company Method and device for reactions start-up
US20040211126A1 (en) * 2003-04-25 2004-10-28 Allen Mark A. Utility meter cover
US20080223425A1 (en) * 2007-03-16 2008-09-18 Shumate Morris W Flexible Base Structure for Portable Shelters
EP2598434B1 (en) 2010-07-26 2018-03-21 Council Of Scientific & Industrial Research An improved process for the storage delivery of hydrogen using catalyst
DE102011009204A1 (en) 2011-01-19 2012-07-19 Thyssenkrupp Uhde Gmbh bulk particles
EP2832716A1 (en) 2013-07-29 2015-02-04 LANXESS Deutschland GmbH 1,3-butadiene synthesis
CN106964398B (en) * 2017-03-09 2019-07-02 武汉凯迪工程技术研究总院有限公司 Hydroisomerizing dewaxing catalyst and preparation method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2814599A (en) * 1953-04-17 1957-11-26 Kellogg M W Co Group iii metal compound promoted platinum or palladium catalyst
US2854403A (en) * 1954-07-26 1958-09-30 Socony Mobil Oil Co Inc Catalytic reforming
DE1066550B (en) * 1954-12-01 1959-10-08 Esso Research And Engineering Company, Elizabeth, N. J. (V. St. A.) Process for the production of abrasion-resistant catalyst supports consisting of »/ -Alumina
US2854404A (en) * 1955-09-26 1958-09-30 Socony Mobil Oil Co Inc Catalytic reforming with a mixed base catalyst
US3002921A (en) * 1958-12-10 1961-10-03 Exxon Research Engineering Co Hydroforming catalyst and process
US2976232A (en) * 1959-01-19 1961-03-21 Exxon Research Engineering Co Platinum-alumina-ceria hydroforming catalyst and process

Also Published As

Publication number Publication date
US3223617A (en) 1965-12-14
DE1442850A1 (en) 1968-12-12

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