GB1031194A - Improvements in the fractionation of aqueous solutions - Google Patents
Improvements in the fractionation of aqueous solutionsInfo
- Publication number
- GB1031194A GB1031194A GB1063663A GB1063663A GB1031194A GB 1031194 A GB1031194 A GB 1031194A GB 1063663 A GB1063663 A GB 1063663A GB 1063663 A GB1063663 A GB 1063663A GB 1031194 A GB1031194 A GB 1031194A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aqueous
- batches
- batch
- organic
- series
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/382—Phosphine chalcogenides, e.g. compounds of the formula R3P=X with X = O, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
- G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
- G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A mixture of Pu/U/fission products, or a mixture of Fe, Co, and Ni are separated in solution by a graded concentration multi-stage extraction system. There is set up an array of vessels containing batches of an organic extractant for the species to be separated, or a solution of such extractant in an inert diluent, e.g. tributyl phosphate in CCl4 for U/Pu and trioctyl phosphine oxide in CCl4 for Fe, Co, Mi. The materials to be separated are in aqueous mineral acid solution, and a second series of vessels are prepared containing batches of aqueous mineral acid, each batch containing acid of different concentration, the concentration varying stepwise along the aqueous series, the final vessel of this series preferably containing water. The first aqueous batch, i.e. that containing the materials to be separated is mixed with the first batch of organic extractant, allowed to settle and separated, the aqueous layer is then shaken with the second organic batch, and separated and is then shaken in turn with all the remainder of the organic batches. The first aqueous batch is followed through the organic series by the second aqueous batch, i.e. an aqueous acid solution, and the third and subsequent aqueous batches until each aqueous batch has been treated with each organic batch. The net result of this procedure is that upon completion, the organic batches are uncontaminated and may be used again, whilst the mixture of solutes is so distributed through the aqueous series that each solute occupies almost exclusively a particular range of batches in the aqueous series and may thus be easily separated, e.g. 23 batches of aqueous nitric acid used in the separation of U/Pu/fission products batches 1-5 contained almost all the fission products, Pu 239 was contained in batches 6-10 and U was contained in batches 10-20, and similar results were obtained for Fe, Co and Mi using HCl solutions. If desired the concentration of extractant may be varied stepwise from batch to batch in the organic series.ALSO:In a graded concentration multistage extraction system, e.g for a mixture of Pu/U/fission products, or a mixture of Fe, Co, and Ni, there is set up an array of vessels containing batches of an organic extractant for the species to be separated or a solution of such extractant in an inert diluent e.g. tributyl phosphate in CCl4 for U/Pu and trioctyl phosphine oxide in CCl4 for Fe, Co, Mi. The materials to be separated are in aqueous mineral acid solution, and a second series of vessels are prepared containing batches of aqueous mineral acid, each batch containing acid of different concentration, the concentration varying stepwise along the aqueous series the final vessel of this series preferably containing water. The first aqueous batch i.e. that containing the materials to be separated is mixed with the first batch of organic extractant, allowed to settle and separated, the aqueous layer is then shaken with the second organic batch and separated, and is then shaken in turn with all the remainder of the organic batches. The first aqueous batch is followed through the organic series by the second aqueous batch, i.e. an aqueous acid solution, and the third and subsequent aqueous batches until each aqueous bath has been trated with each organic batch. The net result of this procedure is that upon completion, the organic batches are uncontaminated and may be used again, whilst the mixture of solutes is so distributed through the aqueous series that each solute occupies almost exclusively a particular range of batches in the aqueous series and may thus be easily separated e.g. of 23 batches of aqueous nitric acid used in the separation of U/Pu/fission products batches 1-5 contained almost all the fission products, Pu 239 was contained in batches 6-10 and U was contained in batches 10-20, and similar results were obtained for Fe, Co and Ni using HCl solutions. ]If desired the concentration of extractant may be varied stepwise from batch to batch in the organic series.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1258462 | 1962-04-02 | ||
JP4481462 | 1962-10-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1031194A true GB1031194A (en) | 1966-06-02 |
Family
ID=26348209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1063663A Expired GB1031194A (en) | 1962-04-02 | 1963-03-18 | Improvements in the fractionation of aqueous solutions |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1277812B (en) |
FR (1) | FR1382924A (en) |
GB (1) | GB1031194A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3454366A (en) * | 1965-06-29 | 1969-07-08 | Commissariat Energie Atomique | Electronic controls of a plutonium extraction battery employing neutron detectors |
CN110465113A (en) * | 2019-08-21 | 2019-11-19 | 广东联捷生物科技有限公司 | Integrated sample extraction box |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4188361A (en) * | 1978-04-12 | 1980-02-12 | Davy International (Oil And Chemicals) Limited | Recovery of uranium values |
-
1963
- 1963-03-18 GB GB1063663A patent/GB1031194A/en not_active Expired
- 1963-03-28 FR FR929602A patent/FR1382924A/en not_active Expired
- 1963-04-02 DE DEN22979A patent/DE1277812B/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3454366A (en) * | 1965-06-29 | 1969-07-08 | Commissariat Energie Atomique | Electronic controls of a plutonium extraction battery employing neutron detectors |
CN110465113A (en) * | 2019-08-21 | 2019-11-19 | 广东联捷生物科技有限公司 | Integrated sample extraction box |
Also Published As
Publication number | Publication date |
---|---|
DE1277812B (en) | 1968-09-19 |
FR1382924A (en) | 1964-12-24 |
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