GB1023415A - Improvements in or relating to the production of phosphonitrilic trimers - Google Patents
Improvements in or relating to the production of phosphonitrilic trimersInfo
- Publication number
- GB1023415A GB1023415A GB4237564A GB4237564A GB1023415A GB 1023415 A GB1023415 A GB 1023415A GB 4237564 A GB4237564 A GB 4237564A GB 4237564 A GB4237564 A GB 4237564A GB 1023415 A GB1023415 A GB 1023415A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ammonium chloride
- suspension
- trimers
- passing
- chlorine gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000013638 trimer Substances 0.000 title abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 10
- 235000019270 ammonium chloride Nutrition 0.000 abstract 5
- 239000007788 liquid Substances 0.000 abstract 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 3
- IMDXZWRLUZPMDH-UHFFFAOYSA-N dichlorophenylphosphine Chemical compound ClP(Cl)C1=CC=CC=C1 IMDXZWRLUZPMDH-UHFFFAOYSA-N 0.000 abstract 3
- 239000000725 suspension Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000001555 benzenes Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
- C07F9/65815—Cyclic phosphazenes [P=N-]n, n>=3 n = 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
Cis- and trans-2,4,6-trichloro-2,4,6-triphenyltriphosphonitriles are prepared by effecting reaction between chlorine gas and phenylphosphorus dichloride in a suspension of finely-divided ammonium chloride in an inert liquid reaction medium at 60-150 DEG C. The reaction may be effected (a) by passing chlorine gas slowly into a suspension of the ammonium chloride in a solution of phenylphosphorus dichloride in the inert liquid or (b) by passing phenylphosphorus dichloride and chlorine gas simultaneously into the suspension of the ammonium chloride. Preferably, the ammonium chloride has an average particle size below 10 microns and may be prepared by passing gas streams of ammonia and hydrogen chloride into an inert liquid which is the same as that used in the preparation of the phosphonitrilic trimers. Suitable inert liquids are saturated aliphatic hydrocarbons containing 6 to 10 carbon atoms aliphatic helogenated hydrocarbons which are not readily dehydrohalogenated and halogenated benzenes containing 1 to 3 halogen atoms. The cis- and trans-trimers may be recovered from the reaction mixture by filtering it to remove ammonium chloride, evaporating the filtrate to dryness and purifying the resulting product with a paraffin hydrocarbon containing 4 to 7 carbon atoms.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31996063A | 1963-10-30 | 1963-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1023415A true GB1023415A (en) | 1966-03-23 |
Family
ID=23244287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4237564A Expired GB1023415A (en) | 1963-10-30 | 1964-10-16 | Improvements in or relating to the production of phosphonitrilic trimers |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1230422B (en) |
| GB (1) | GB1023415A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0026882A1 (en) * | 1979-10-05 | 1981-04-15 | Hoechst Aktiengesellschaft | Process for preparing alkyl-chloro-phosphazenes |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB905314A (en) * | 1958-04-25 | 1962-09-05 | Albright & Wilson Mfg Ltd | The production of cyclic phosphonitrilic chloride polymers |
-
1964
- 1964-10-16 GB GB4237564A patent/GB1023415A/en not_active Expired
- 1964-10-28 DE DEG41876A patent/DE1230422B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0026882A1 (en) * | 1979-10-05 | 1981-04-15 | Hoechst Aktiengesellschaft | Process for preparing alkyl-chloro-phosphazenes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1230422B (en) | 1966-12-15 |
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