GB1023299A - Polymeric viscosity index improvers for lubricating oils - Google Patents

Polymeric viscosity index improvers for lubricating oils

Info

Publication number
GB1023299A
GB1023299A GB21274/64A GB2127464A GB1023299A GB 1023299 A GB1023299 A GB 1023299A GB 21274/64 A GB21274/64 A GB 21274/64A GB 2127464 A GB2127464 A GB 2127464A GB 1023299 A GB1023299 A GB 1023299A
Authority
GB
United Kingdom
Prior art keywords
blocks
stereo
regular
oil
solvatable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21274/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Princeton Chemical Research Inc
Original Assignee
Princeton Chemical Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Princeton Chemical Research Inc filed Critical Princeton Chemical Research Inc
Publication of GB1023299A publication Critical patent/GB1023299A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2290/00—Mixtures of base materials or thickeners or additives
    • C10M2290/04—Synthetic base oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Lubricating oils comprise as viscosity index improver 0.1 to 30% by weight of a block copolymer comprising stereo-regular hydrocarbon polymer blocks insoluble in oil at below 0 DEG C., and amorphous hydrocarbon polymer blocks soluble in oil at above - 20 DEG C., the copolymer being progressively solvatable in lubricating oil with increasing temperature and completely solvatable below 150 DEG C. The copolymer blocks are preferably derived from C2-C20 olefins and styrene. The lubricating oil may be of the petroleum type, e.g. those consisting of conventional base stocks or base stock blends, or synthetic, e.g. Fischer-Tropsch produced oils. The usual additives may also be present, e.g. detergents, dispersing acids, pour point depressants, anti-oxidants and known viscosity improvers.ALSO:A viscosity index improver for lubricating oil comprises a block copolymer having stereo-regular hydrocarbon polymer blocks insoluble in oil at below 0 DEG C., and amorphous hydrocarbon polymer blocks soluble in oil at above -20 DEG C., the copolymer being progressively solvatable in lubricating oil with increasing temperature and completely solvatable below 150 DEG C. Preferably, the combined molecular weight of the amorphous blocks is at least 50% of that of the stereo-regular blocks. The stereo-regular blocks may be derived from polymers and copolymers of propylene, butene, pentene, hexene and styrene; the amorphous blocks from polymers and copolymers of C2-C20 alpha-olefins. The block copolymers are generally obtained by first forming the stereo-regular blocks and then continuing the polymerization under conditions which will not form stereo-regular chains. Both polymerization stages may be effected in the same reaction zone using the batch method, or the process may be effected continuously using a two-reaction zone system. The stereo-regular polymerization is generally effected with the usual Zeigler catalysts, e.g. aluminium trialkyls or alkyl aluminium halides in combination with halides or alcoholates of transition metals such as vanadium and titanium, in an inert hydrocarbon solvent at elevated temperatures.
GB21274/64A 1963-05-28 1964-05-22 Polymeric viscosity index improvers for lubricating oils Expired GB1023299A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28367263A 1963-05-28 1963-05-28
US35729464A 1964-04-03 1964-04-03

Publications (1)

Publication Number Publication Date
GB1023299A true GB1023299A (en) 1966-03-23

Family

ID=26962174

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21274/64A Expired GB1023299A (en) 1963-05-28 1964-05-22 Polymeric viscosity index improvers for lubricating oils

Country Status (10)

Country Link
US (1) US3509056A (en)
AT (1) AT264691B (en)
BE (1) BE647517A (en)
CH (1) CH482012A (en)
DE (1) DE1282826B (en)
ES (1) ES300305A1 (en)
FR (1) FR1405878A (en)
GB (1) GB1023299A (en)
NL (1) NL6405443A (en)
SE (1) SE311712B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116989A (en) * 1982-03-23 1983-10-05 Mitsubishi Petrochemical Co Block copolymers of propylene butene-1 and optionally ethylene

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE759715A (en) * 1969-12-12 1971-06-02 Shell Int Research BLOCK COPOLYMERS AS VISCOSITY INDEX IMPROVING AGENTS
US3897353A (en) * 1972-12-29 1975-07-29 Texaco Inc Method of preventing haze in oil concentrates containing an amorphous ethylene-propylene copolymer viscosity index improver
US4132663A (en) * 1975-03-17 1979-01-02 Gulf Research & Development Company Mineral oil compositions having improved pour point containing alpha-olefin copolymers
DE2905954C2 (en) * 1979-02-16 1982-10-28 Röhm GmbH, 6100 Darmstadt Concentrated polymer emulsions as viscosity index improvers for mineral oils
US4334040A (en) * 1979-09-18 1982-06-08 Mitsubishi Petrochemical Company Limited Propylene block copolymers
IT1152433B (en) * 1982-07-14 1986-12-31 Montedison Spa BLOCK COPOLYMERS OF OLEFINS WITH VINYLAROMATIC MONOMERS
US4663220A (en) * 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
EP0482949B1 (en) * 1990-10-25 1995-12-13 Tokuyama Corporation Propylene-ethylene/butene block copolymer
US7776804B2 (en) * 2005-03-16 2010-08-17 The Lubrizol Corporation Viscosity improver compositions providing improved low temperature characteristics to lubricating oil
US20120015854A1 (en) * 2008-08-08 2012-01-19 Ravishankar Periagaram S Olefinic Copolymer Compositions for Viscosity Modification of Motor Oil
CH705978A1 (en) 2012-01-11 2013-07-15 Qvanteq Ag Method and device for determining a surface characteristic of stents and stent with defined surface characteristics.
CH706684A1 (en) 2012-06-28 2013-12-31 Qvanteq Ag Packaging and transfer system for implant application.
WO2016122422A1 (en) 2015-01-30 2016-08-04 Celik Omar Production processes applied for obtaining a rheological grade sepiolite and resulting products
WO2016200347A1 (en) 2015-06-10 2016-12-15 Celik Omar Production processes applied for obtaining a rheological grade sepiolite and resulting products
CN114292355A (en) * 2022-01-20 2022-04-08 方昱炜 Synthesis of polyolefin lubricating oil viscosity index improver

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL99091C (en) * 1955-12-30
BE560366A (en) * 1956-08-28
US2917458A (en) * 1957-04-09 1959-12-15 Exxon Research Engineering Co Polypropylene grease
BE637093A (en) * 1962-09-10

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116989A (en) * 1982-03-23 1983-10-05 Mitsubishi Petrochemical Co Block copolymers of propylene butene-1 and optionally ethylene

Also Published As

Publication number Publication date
ES300305A1 (en) 1966-04-01
CH482012A (en) 1969-11-30
FR1405878A (en) 1965-07-16
BE647517A (en) 1964-08-31
SE311712B (en) 1969-06-23
DE1282826B (en) 1968-11-14
AT264691B (en) 1968-09-10
US3509056A (en) 1970-04-28
NL6405443A (en) 1964-11-30

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