GB1023281A - Water-soluble salts of acrylic copolymers - Google Patents

Water-soluble salts of acrylic copolymers

Info

Publication number
GB1023281A
GB1023281A GB1976863A GB1976863A GB1023281A GB 1023281 A GB1023281 A GB 1023281A GB 1976863 A GB1976863 A GB 1976863A GB 1976863 A GB1976863 A GB 1976863A GB 1023281 A GB1023281 A GB 1023281A
Authority
GB
United Kingdom
Prior art keywords
acid
water
resins
ethyl
acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1976863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB1023281A publication Critical patent/GB1023281A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

A composition comprising (1) water, (2) a water-soluble salt of (A) a polymer containing (i) from 1 to 5% by weight of carboxylic acid units derived from one or more of the following acids, namely: acrylic acid, methacrylic acid, methacrylic acid dimer, maleic acid, itaconic acid, methacryloxy propionic acid and methacryloxy isobutyric acid, and (ii) ester units of the formula <FORM:1023281/C3/1> where R represents methyl or ethyl, the balance, if any, of the copolymer being constituted by compatible units as hereinbefore defined with (B). At least one of the following amines, viz. 2 - (dimethylamino) - ethanol, trimethylamine, triethylamine and 2-methyl-2-amino-propanol-1, and (3) a cosolvent coprising isopropanol, n-butanol, 2-ethyl hexanol, 2-butoxy ethanol, 2-butoxyethyl acetate, butoxyethoxyethyl acetate, ethoxyethoxyethyl acetate, isophorine or triethanolamine. The compositions may be mixed with ag. dispersions of water-insoluble vinyl or acrylic polymers, or with phenol-formaldehyde resins, aminoplasts such as urea-formaldehyde resins, melamineformaldehyde resins, ethylene urea-formaldehyde resins, alcohol modified aminoplasts and epoxy resins. Examples describe the copolymerization of ethyl acrylate/methyl methacrylate/acrylamide/methacrylic acid and ethyl acrylate / methyl methacrylate / b - hydroxypropyl methacrylate / methacrylic acid. The compositions obtained from these copolymers are mixed with an ag. solution of water-soluble methoxylated melamine-formaldehyde resin and titanium dioxide. Cross-linked polymers.-When the polymers are co-mixed with other resins such as aminoplasts and polyepoxide 3-20% of a comonomer enhancing cross-linking is incorporated. Several examples of such comonomers containing hydroxyl, amino, ureido, amide or epoxy groups are given.ALSO:Paper, leather, wood, metals, glass, ceramics, concrete, asbestos-cement products such as boards and shingles, textiles e.g. rugs, woven, nonwoven, or knitted fabrics are coated with a composition comprising (1) water, (2) a water-soluble salt of (A) a polymer containing (i) from 1-5% by weight of carboxylic acid units derived from one or more of the following acids, namely acrylic acid, methacrylic acid, methacrylic acid dimer, maleic acid, itaconic acid, methacryloxypropionic acid and methacryloxy butyric acid and (ii) ester units of the formula <FORM:1023281/B1-B2/1> where R represents methyl or ethyl, the balance, if any, of the copolymer being constituted by compatible units (defined) with (B) at least one of the following amines viz. 2-(dimethylamino)-ethanol, trimethyl amine, triethyl amine and 2-methyl-2-aminopropanol-1, and (3) a co-solvent comprising isopropanol, n-butanol, 2-ethyl-hexanol, 2-butoxy ethanol, 2-butoxy ethyl acetate, butoxyethoxyethyl acetate, ethoxyethoxyethyl acetate, isophorone or triethanol amine. After application the coatings may be air dried or dried at a temperature of from 140-210 DEG F. To ensure maximum resistance to water the coatings may be subjected to a final curing by heating to elevated temperatures of 220-450 DEG F. The compositions may be mixed with aqueous dispersions of water insoluble vinyl polymers, or with phenol for maldehyde resins, amino-plasts such as ureaformaldehyde resins melamine-formaldehyde resins, ethylene urea-formaldehyde resins, alcohol modified amino-plasts, and epoxy resins. Examples relate to coating steel plate by spraying with a suction-type sray gun, air drying, followed by a final cure. Pigmented coating compositions containing rutile are also described.
GB1976863A 1962-06-01 1963-05-17 Water-soluble salts of acrylic copolymers Expired GB1023281A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19924262A 1962-06-01 1962-06-01

Publications (1)

Publication Number Publication Date
GB1023281A true GB1023281A (en) 1966-03-23

Family

ID=22736767

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1976863A Expired GB1023281A (en) 1962-06-01 1963-05-17 Water-soluble salts of acrylic copolymers

Country Status (4)

Country Link
BE (1) BE633106A (en)
DE (2) DE1228015B (en)
GB (1) GB1023281A (en)
NL (2) NL256395A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4654395A (en) * 1984-04-09 1987-03-31 S. C. Johnson & Son, Inc. Water-soluble polymer sheet for delivering laundry care additive and laundry care product formed from same
EP0360038A2 (en) * 1988-09-03 1990-03-28 BASF Aktiengesellschaft Process for the manufacture of amine-modified copolymers of ethylene and carboxylic acids, these copolymers and their use in coupling agents and cable-insulating materials
EP0447785A2 (en) * 1990-03-19 1991-09-25 Th. Goldschmidt AG Acrylic ester polymers containing ammonium salt groups
EP0523480A1 (en) * 1991-07-16 1993-01-20 Th. Goldschmidt AG Polymers of acrylic esters containing ammonium groups and long chain hydrocarbon oxy-groups
EP1391469A1 (en) * 2002-08-16 2004-02-25 Bayer Aktiengesellschaft Aqueous binder dispersions as coating agents

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2760226A (en) * 1947-07-16 1956-08-28 Bengtson Sven Emanuel Sausage casing end tying machine
US2904526A (en) * 1957-08-27 1959-09-15 Goodrich Co B F Coating compositions
NL231902A (en) * 1957-10-04

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4654395A (en) * 1984-04-09 1987-03-31 S. C. Johnson & Son, Inc. Water-soluble polymer sheet for delivering laundry care additive and laundry care product formed from same
EP0360038A2 (en) * 1988-09-03 1990-03-28 BASF Aktiengesellschaft Process for the manufacture of amine-modified copolymers of ethylene and carboxylic acids, these copolymers and their use in coupling agents and cable-insulating materials
EP0360038A3 (en) * 1988-09-03 1992-02-12 BASF Aktiengesellschaft Process for the manufacture of amine-modified copolymers of ethylene and carboxylic acids, these copolymers and their use in coupling agents and cable-insulating materials
EP0447785A2 (en) * 1990-03-19 1991-09-25 Th. Goldschmidt AG Acrylic ester polymers containing ammonium salt groups
EP0447785A3 (en) * 1990-03-19 1991-12-27 Th. Goldschmidt Ag Acrylic ester polymers containing ammonium salt groups
EP0523480A1 (en) * 1991-07-16 1993-01-20 Th. Goldschmidt AG Polymers of acrylic esters containing ammonium groups and long chain hydrocarbon oxy-groups
EP1391469A1 (en) * 2002-08-16 2004-02-25 Bayer Aktiengesellschaft Aqueous binder dispersions as coating agents
US7232860B2 (en) 2002-08-16 2007-06-19 Bayer Materialscience Ag Aqueous binder dispersions as coating compositions

Also Published As

Publication number Publication date
NL121782C (en)
DE1239795B (en) 1967-05-03
BE633106A (en) 1963-12-02
NL256395A (en)
DE1228015B (en) 1966-11-03

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