GB1022870A - Organic compounds - Google Patents

Organic compounds

Info

Publication number
GB1022870A
GB1022870A GB46930/63A GB4693063A GB1022870A GB 1022870 A GB1022870 A GB 1022870A GB 46930/63 A GB46930/63 A GB 46930/63A GB 4693063 A GB4693063 A GB 4693063A GB 1022870 A GB1022870 A GB 1022870A
Authority
GB
United Kingdom
Prior art keywords
acid
derivatives
bis
dimethyl
derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB46930/63A
Inventor
Fred Melvin Parham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB46930/63A priority Critical patent/GB1022870A/en
Priority to FR956197A priority patent/FR1385610A/en
Priority to DEP33148A priority patent/DE1282845B/en
Publication of GB1022870A publication Critical patent/GB1022870A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Linear polyesters comprise recurring units of formula <FORM:1022870/C3/1> wherein -CH2-C10H16-CH2- is a decahydrobis(methylene)-naphthalene radical and A is a C6-24 divalent radical inert in esterification reaction. Suitable reactants providing the residue A are 4,41-bibenzoic acid, its dodecahydro derivative, its 2,21 and 3,31 dimethyl derivatives and its 2,21-dibromo derivative; bis(4-carboxyphenyl)-methane, -ethane, -propane, -ketone, -ether, -sulphide, -sulphonide and -sulphone; 1,2 - bis(4 - carboxyphenoxy)-ethane; 2,8 - dibenzofurandicarboxylic acid; terephthalic acid and its hexahydro methyl, dimethyl, fluoro, chloro or dichloro derivatives; isophthalic acid and its 5-sulpho, -chloro and -t-butyl derivatives; naphthalenedicarboxylic acids and their decahydro derivatives; phenylenediacetic acid; 4-carboxyphenoxyacetic acid; m- and p-terphenyl-4,411-dicarboxylic acids and the m-perhydro derivative; bicyclo(2,2,2)octane 1,4-dicarboxylic acid; 4,41-stilbenedicarboxylic acid; 1,4 - bis(4 - carboxyphenoxymethyl)-cyclohexane. With the dimethyloldecahydronaphthalene component there may be copolymerized other hydroxy components such as glycols or bisphenols of which a number of examples are given.ALSO:The invention comprises the title compounds, excepting the 1,2-isomer, these being prepared by ring hydrogenating dimethyl naphthalenedicarboxylates with Ru/C and reducing the decahydronaphthalene dicarboxylic acid esters thus obtained to the corresponding diols with LiAlH4.
GB46930/63A 1963-11-27 1963-11-27 Organic compounds Expired GB1022870A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB46930/63A GB1022870A (en) 1963-11-27 1963-11-27 Organic compounds
FR956197A FR1385610A (en) 1963-11-27 1963-12-05 New glycols derived from naphthalene and polyesters made from these glycols
DEP33148A DE1282845B (en) 1963-11-27 1963-12-06 Use of Carbonyloxy Polyesters for making threads or foils

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB46930/63A GB1022870A (en) 1963-11-27 1963-11-27 Organic compounds
FR956197A FR1385610A (en) 1963-11-27 1963-12-05 New glycols derived from naphthalene and polyesters made from these glycols
DEP33148A DE1282845B (en) 1963-11-27 1963-12-06 Use of Carbonyloxy Polyesters for making threads or foils

Publications (1)

Publication Number Publication Date
GB1022870A true GB1022870A (en) 1966-03-16

Family

ID=26204728

Family Applications (1)

Application Number Title Priority Date Filing Date
GB46930/63A Expired GB1022870A (en) 1963-11-27 1963-11-27 Organic compounds

Country Status (3)

Country Link
DE (1) DE1282845B (en)
FR (1) FR1385610A (en)
GB (1) GB1022870A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010148080A3 (en) * 2009-06-16 2011-09-29 Draths Corporation Cyclohexane 1,4 carboxylates
US8367858B2 (en) 2009-06-16 2013-02-05 Amyris, Inc. Terephthalic and trimellitic based acids and carboxylate derivatives thereof
US8415496B2 (en) 2009-06-16 2013-04-09 Amyris, Inc. Biobased polyesters
US8426639B2 (en) 2009-06-16 2013-04-23 Amyris, Inc. Preparation of trans, trans muconic acid and trans, trans muconates
US8809583B2 (en) 2010-01-08 2014-08-19 Amyris, Inc. Methods for producing isomers of muconic acid and muconate salts

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010148080A3 (en) * 2009-06-16 2011-09-29 Draths Corporation Cyclohexane 1,4 carboxylates
US8367859B2 (en) 2009-06-16 2013-02-05 Amyris, Inc. Cyclohexane 1,4 carboxylates
US8367858B2 (en) 2009-06-16 2013-02-05 Amyris, Inc. Terephthalic and trimellitic based acids and carboxylate derivatives thereof
US8415496B2 (en) 2009-06-16 2013-04-09 Amyris, Inc. Biobased polyesters
US8426639B2 (en) 2009-06-16 2013-04-23 Amyris, Inc. Preparation of trans, trans muconic acid and trans, trans muconates
US8809583B2 (en) 2010-01-08 2014-08-19 Amyris, Inc. Methods for producing isomers of muconic acid and muconate salts

Also Published As

Publication number Publication date
DE1282845B (en) 1969-02-20
FR1385610A (en) 1965-01-15

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