GB1020372A - Flexible cellulosic filamentary materials having ultra-violet light shielding properties - Google Patents
Flexible cellulosic filamentary materials having ultra-violet light shielding propertiesInfo
- Publication number
- GB1020372A GB1020372A GB4047663A GB4047663A GB1020372A GB 1020372 A GB1020372 A GB 1020372A GB 4047663 A GB4047663 A GB 4047663A GB 4047663 A GB4047663 A GB 4047663A GB 1020372 A GB1020372 A GB 1020372A
- Authority
- GB
- United Kingdom
- Prior art keywords
- film
- hydroxide
- ferric
- salt
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 8
- 150000003839 salts Chemical class 0.000 abstract 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000007864 aqueous solution Substances 0.000 abstract 6
- 238000000576 coating method Methods 0.000 abstract 6
- 239000004627 regenerated cellulose Substances 0.000 abstract 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 4
- -1 alkaline earth metal basic salt Chemical class 0.000 abstract 4
- 238000004873 anchoring Methods 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 239000011248 coating agent Substances 0.000 abstract 4
- 229920000742 Cotton Polymers 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002585 base Substances 0.000 abstract 3
- 229960004887 ferric hydroxide Drugs 0.000 abstract 3
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 abstract 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 239000001099 ammonium carbonate Substances 0.000 abstract 2
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 2
- 230000005540 biological transmission Effects 0.000 abstract 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 2
- 239000000920 calcium hydroxide Substances 0.000 abstract 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 2
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 2
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 2
- 229940105329 carboxymethylcellulose Drugs 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- 238000007654 immersion Methods 0.000 abstract 2
- 238000011065 in-situ storage Methods 0.000 abstract 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 2
- 238000012856 packing Methods 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 2
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 2
- 239000001632 sodium acetate Substances 0.000 abstract 2
- 235000017281 sodium acetate Nutrition 0.000 abstract 2
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 2
- 235000017550 sodium carbonate Nutrition 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011240 wet gel Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Wrappers (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
A fibrous cellulosic base sheet (e.g. of paper or cotton) is impregnated with a cellulosic hydrophilic film-forming material, e.g. regenerated cellulose, carboxy methyl cellulose and other cellulose ethers, and hydrophilic cellulose esters, and treated with an aqueous solution of an inorganic water-soluble ferric salt and then immersed in an aqueous solution maintained at a pH of at least 5, preferably at least 10, to precipitate ferric hydroxide in situ. The ferric salt is preferably ferric chloride, suitably 0.01-0.2% by weight of the anhydrous salt, and the second aqueous solution may contain an alkali or alkaline earth metal basic salt or hydroxide, preferably 2% sodium hydroxide. Sodium acetate, sodium carbonate, ammonium carbonate, potassium hydroxide and calcium hydroxide are also specified. Immersion times may be 1-60 secs. in the ferric salt bath at room temperature, and 5-30 secs. in the alkaline bath at from room temperature to 40 DEG C. After removal from the alkaline bath and washing, the sheet may be plasticized in an aqueous bath containing e.g. glycerol, and also an anchoring agent, e.g. melamine-formaldehyde precondensates, urea-formaldehyde precondensates, polyalkylene-imines and epoxy resins, if it is desired subsequently to apply a polymeric film-forming coating. Water-insoluble anchoring agents may be applied to the sheet after drying. Materials so treated show a substantially reduced transmission of ultra-violet light and are useful in packing foodstuffs (see Division A2). For details of coatings which may be applied see Division B2.ALSO:A coated sheet material comprises a flexible, hydrophilic cellulosic filamentary material, for example a non-fibrous regenerated cellulose film, a carboxymethyl cellulose film, or a fibrous cellulosic base sheet (e.g. paper or cotton) impregnated with a hydrophilic cellulosic film-forming material, uniformly impregnated with ferric hydroxide or hydrated ferric oxide at least adjacent one surface thereof, and having a film-forming polymer coating on the surface thereof, for instance a copolymer of at least 50% of vinylidene chloride and at least one other monomer copolymerizable therewith. Filamentary materials in general include fibrous and non-fibrous sheets, films, pellicles, and ribbons of regenerated cellulose, cellulose ethers, hydrophilic cellulose esters, cotton and paper. Specified coating materials include also vinyl chloride-vinyl acetate copolymers, nitrocellulose and polyalkylenes such as polyethylene and polypropylene. Coatings may be applied by melt-extrusion or from solutions, including lacquers and latices, to the coloured cellulosic base sheet. In a preferred method, regenerated cellulose film, in the wet-gel state, is treated with an aqueous solution of an inorganic water-soluble ferric salt and then immersed in an aqueous solution maintained at a pH of at least 5, preferably at least 10, to precipitate ferric hydroxide in situ. The ferric salt is preferably ferric chloride, suitably 0,01-0,2% by weight of the anhydrous salt and the second aqueous solution may contain an alkali or alkaline earth metal basic salt or hydroxide, preferably 2% sodium hydroxide. Sodium acetate, sodium carbonate, ammonium carbonate, potassium hydroxide and calcium hydroxide are also specified. Immersion times may be 1-60 seconds in the ferric salt bath at room temperature, and 5-30 seconds in the alkaline bath at from room temperature to 40 DEG C. After removal from the alkaline bath and washing, the film may be plasticized in an aqueous bath containing e.g. glycerol, and also an anchoring agent, e.g. melamine-formaldehyde precondensates, urea-formaldehyde precondensates, polyalkylene-imines and epoxy resins, if it is desired subsequently to apply a polymeric film-forming coating. Water-insoluble anchoring agents may be applied to the film after drying. The film is then coated. In an example, an impregnated, anchor-coated regenerated cellulose film is coated with "Saran" (Registered Trade Mark) dissolved in a mixture of tetrahydrofuran and toluene, and containing also small proportions of clay, wax and alkyd resin to improve surface characteristics. Coated films so made show a substantially reduced transmission of ultra-violet light and are useful in packing foodstuffs (see Division A2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4047663A GB1020372A (en) | 1963-10-14 | 1963-10-14 | Flexible cellulosic filamentary materials having ultra-violet light shielding properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4047663A GB1020372A (en) | 1963-10-14 | 1963-10-14 | Flexible cellulosic filamentary materials having ultra-violet light shielding properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1020372A true GB1020372A (en) | 1966-02-16 |
Family
ID=10415089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4047663A Expired GB1020372A (en) | 1963-10-14 | 1963-10-14 | Flexible cellulosic filamentary materials having ultra-violet light shielding properties |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1020372A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108927101A (en) * | 2018-07-06 | 2018-12-04 | 济南大学 | A kind of acicular nanometer FeOOH adsorbent and preparation method thereof |
| CN110592702A (en) * | 2019-09-26 | 2019-12-20 | 东华大学 | Photoresponse and anti-freezing elastic gel fiber and preparation method thereof |
-
1963
- 1963-10-14 GB GB4047663A patent/GB1020372A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108927101A (en) * | 2018-07-06 | 2018-12-04 | 济南大学 | A kind of acicular nanometer FeOOH adsorbent and preparation method thereof |
| CN110592702A (en) * | 2019-09-26 | 2019-12-20 | 东华大学 | Photoresponse and anti-freezing elastic gel fiber and preparation method thereof |
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