GB1018661A - Process for the hydrogenation of hydroperoxides - Google Patents

Process for the hydrogenation of hydroperoxides

Info

Publication number
GB1018661A
GB1018661A GB508762A GB508762A GB1018661A GB 1018661 A GB1018661 A GB 1018661A GB 508762 A GB508762 A GB 508762A GB 508762 A GB508762 A GB 508762A GB 1018661 A GB1018661 A GB 1018661A
Authority
GB
United Kingdom
Prior art keywords
hydroperoxides
hydrogenation
methylpentene
compound
examples
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB508762A
Inventor
Kenneth Allison Maurice Ba Spa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Priority to GB508762A priority Critical patent/GB1018661A/en
Publication of GB1018661A publication Critical patent/GB1018661A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond

Abstract

Organic hydroperoxides are hydrogenated in the presence of a platinum group metal modified by a compound of Ag, Cu, Zn, Cd, Hg, Sn, Pb, As, Sb, Bi or Tl. The hydroperoxides are preferably acyclic or unsaturated acyclic compounds, e.g. cyclohexenyl hydroperoxide. The catalyst is selective for hydrogenation of methylpentene hydroperoxides in the presence of methyl pentenes. Examples 1 and 2 describe selective reduction of tertiary-butyl hydroperoxide. Example 3 the reduction of methylpentene hydroperoxides and Example 4 a combination.ALSO:Hydrogenation catalysts comprise platinum group metal, preferably palladium, modified by a compound of a metal selected from Ag, Cu, Zn, Cd, Hg, Sn, Pb, As, Sb, Bi and T1. Catalyst supports mentioned are C, CaCO3, BaCO3, ZnCO3, MgO, BaSO4, Al2O3 or sepiolite. Acids mentioned are HNO3, CH3COOH and C2H5COOH. Examples are given.
GB508762A 1962-02-09 1962-02-09 Process for the hydrogenation of hydroperoxides Expired GB1018661A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB508762A GB1018661A (en) 1962-02-09 1962-02-09 Process for the hydrogenation of hydroperoxides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB508762A GB1018661A (en) 1962-02-09 1962-02-09 Process for the hydrogenation of hydroperoxides

Publications (1)

Publication Number Publication Date
GB1018661A true GB1018661A (en) 1966-01-26

Family

ID=9789526

Family Applications (1)

Application Number Title Priority Date Filing Date
GB508762A Expired GB1018661A (en) 1962-02-09 1962-02-09 Process for the hydrogenation of hydroperoxides

Country Status (1)

Country Link
GB (1) GB1018661A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5354917A (en) * 1993-11-12 1994-10-11 Texaco Chemical Company Use of supported rhodium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
WO1998037966A1 (en) * 1997-02-27 1998-09-03 Phillips Petroleum Company Hydrogenation catalysts for unsaturated hydrocarbons

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5354917A (en) * 1993-11-12 1994-10-11 Texaco Chemical Company Use of supported rhodium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
WO1998037966A1 (en) * 1997-02-27 1998-09-03 Phillips Petroleum Company Hydrogenation catalysts for unsaturated hydrocarbons
US6127310A (en) * 1997-02-27 2000-10-03 Phillips Petroleum Company Palladium containing hydrogenation catalysts

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