GB1016952A - Plasticised halogen-containing resins - Google Patents
Plasticised halogen-containing resinsInfo
- Publication number
- GB1016952A GB1016952A GB2823862A GB2823862A GB1016952A GB 1016952 A GB1016952 A GB 1016952A GB 2823862 A GB2823862 A GB 2823862A GB 2823862 A GB2823862 A GB 2823862A GB 1016952 A GB1016952 A GB 1016952A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diallyl
- reacting
- radical
- compound
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A plastic composition comprises in uniform admixture a polymer of which at least 50% by weight is formed from a halogen-containing monomer having a terminal ethylenically unsaturated group and, as plasticizer therefor, a polymerizable fumaric acid ester composition, the said plastic composition further containing a polyallyl ester of a polybasic acid. The fumaric acid ester compositions may have the general formula <FORM:1016952/C3/1> where A is the fumaryl radical <FORM:1016952/C3/2> R is a divalent aliphatic or alicylic hydrocarbon or oxyhydrocarbon radical; R1 and R2 are each alkyl, cycloalkyl, alkenyl or aralkyl n is 0, 1 or 2; m and y are unlike and each is 0 or 1 and the sum of m+n is at least 1. They may be prepared as in Specification 997,172. The polyalkyl esters are esters of any allyl alcohol, substituted or unsubstituted, with a polybasic acid which is saturated or unsaturated. A substantially non-volatile alkyl substituted monoaryl compound may be added to improve the viscosity (hereinafter called an aryl alkane). Preferred aryl alkanes are obtained by (1) condensing an aromatic hydrocarbon of the benzene series with an acylic propylene polymer containing 12 to 18 carbon atoms and (2) mono-alkylating benzene with the product obtained by substantial mono-chlorination of paraffin base kerosene fractions. Peroxy compounds, fillers, stabilizers and colouring materials may be added. In the examples the halogen containing polymer is polyvinyl chloride and the polyallyl esters employed are diallyl adipate, diallyl phthalate, diallyl succinate, diallyl sebacate, diallyl oxalate, diallyl malonate, diallyl dimerate, diallyl diglycollate and triallyl citrate.ALSO:Fumaric acid esters of the general formula <FORM:1016952/C2/1> where A is the fumaryl radical <FORM:1016952/C2/2> R is a divalent aliphatic or alicyclic hydrocarbon or oxyhydrocarbon radical; R1 and R2 are each alkyl, cycloalkyl, alkenyl or aralkyl; n is 0, 1 or 2; m and y are unlike and are each 0 or 1 and the sum of m and n is at least 1 may be prepared by one of the following methods:- (1) Reacting a partial ester of maleic acid <FORM:1016952/C2/3> where X is an aliphatic or alicyclic hydrocarbon radical of valency X and X is a whole number from 2 to 6, with at least one hydroxy compound R1OH where R1 is alkyl, cycloalkyl, alkenyl or aralkyl, in the presence of a halogen-containing compound; (2) Reacting a fumaryl chloride of formula <FORM:1016952/C2/4> where R1 is above, with a polyhydroxy compound having 2 to 6 hydroxyl groups, the molar ratio of chloride to polyhydroxy compound being X:1 where X equals the number of hydroxyl groups; and (3) Reacting a fumarate ester of formula <FORM:1016952/C2/5> where R1 is as above, with a polyhydroxy compound having 2 to 6 hydroxyl groups, the molar ratio of the fumarate ester to polyhydroxy compound being 1 to 1.5 X: 1 where X is the number of hydroxyl groups. In the examples fumaric acid esters are formed by (1) reacting isobutyl fumaryl chloride with 1,3-butanediol and (2) reacting the following dialkyl fumarates with the following polyhydroxy compounds :- diisohexyl, dibutyl, dimethylamyl, diiso-octyl, diisohexyl, di-2-ethylhexyl or diisobutyl fumarates and 1,2-, 1,3- or 1,4-butanediol; neopentyl glycol; dipropylene glycol and di- or triethylene glycol.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10002661A | 1961-04-03 | 1961-04-03 | |
US12595161A | 1961-07-24 | 1961-07-24 | |
US178542A US3280067A (en) | 1961-04-03 | 1962-03-09 | Plasticized halogen-containing resins |
US19536862A | 1962-05-21 | 1962-05-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1016952A true GB1016952A (en) | 1966-01-12 |
Family
ID=26824123
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2823862A Expired GB1016952A (en) | 1961-04-03 | 1962-07-23 | Plasticised halogen-containing resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1016952A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2455486A1 (en) * | 1979-05-04 | 1980-11-28 | Matec Holding | COATING METHOD FOR FLAT ELEMENTS AND COATING LAYER |
-
1962
- 1962-07-23 GB GB2823862A patent/GB1016952A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2455486A1 (en) * | 1979-05-04 | 1980-11-28 | Matec Holding | COATING METHOD FOR FLAT ELEMENTS AND COATING LAYER |
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