GB1011978A - Photographic silver halide emulsions of increased sensitivity - Google Patents

Photographic silver halide emulsions of increased sensitivity

Info

Publication number
GB1011978A
GB1011978A GB20377/62A GB2037762A GB1011978A GB 1011978 A GB1011978 A GB 1011978A GB 20377/62 A GB20377/62 A GB 20377/62A GB 2037762 A GB2037762 A GB 2037762A GB 1011978 A GB1011978 A GB 1011978A
Authority
GB
United Kingdom
Prior art keywords
methyl
hydrogen
prepared
formula
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20377/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1011978A publication Critical patent/GB1011978A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/60Two oxygen atoms, e.g. succinic anhydride
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43DMACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
    • A43D113/00Machines for making shoes with out-turned flanges of the uppers or for making moccasins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/12Ketones containing more than one keto group
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/10Organic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pyridine Compounds (AREA)

Abstract

Poly - (1,3 - dicarbomethoxy - 2 - butanone) having the formula shown in Fig. 15 is prepared by adding a few drops of piperidine to a cooled solution of dimethyl - b - oxoglutarate and aqueous formalin in methanol. <FORM:1011978/C3/1> <FORM:1011978/C3/2> Poly - (ethylene - a ,a 1 - diacetyl - glutarate having the formula shown in Fig. 16 is prepared Poly - (ethylene - a a 1 - diacetyl - glutarate) having the formula shown in Fig. 16 is prepared by allowing a solution of ethylene bisacetoacetate and aqueous formalin in ethanol to stand for four days at room temperature.ALSO:Compounds of the general formula R1-CO-CH(R)-CH(R2)-CH(R)-CO-R1 wherein R is hydrogen or an aliphatic carboxylic acyl radical or a group of the formula -CONR6R7 (where R6 and R7 are hydrogen or alkyl, cycloalkyl, aralkyl, aryl, substituted aryl heterocyclic groups or together complete a heterocyclic ring, or R6 is H and R7 is NH2), R1 is alkyl, alkoxyl or hydrazino and R2 is hydrogen or alkyl, are prepared by reacting an aldehyde R2CHO with a reactive methylene compound of the formula R1-CO-CH2-R. Examples are given of the reaction of formalin with reactive methylene compounds in which R1 is methyl, ethyl, pivalyl, methoxy, ethoxy or hydrazino, and R is hydrogen, acetyl, propionyl, carbomethoxyacetyl, CONR6R7 where R6 and R7 complete a piperidyl ring, or -CONH2 which may be unsubstituted, di-substituted with methyl or ethyl groups or by a methyl and a phenyl group, or mono-substituted by phenyl, tolyl, methoxyphenyl, trimethoxyphenyl, carboxyphenyl, sulphophenyl, fluorophenyl, ethyl butyl, benzyl, phenethyl, cyclohexyl, a -pyridyl (or its methyl p-toluene sulphonate), or NH2. Examples also are given of the reaction of acetaldehyde with reactive methylene compounds in which R1 is methoxy or ethoxy and R is acetyl or carbomethoxyacetyl.
GB20377/62A 1961-05-29 1962-05-28 Photographic silver halide emulsions of increased sensitivity Expired GB1011978A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US113066A US3201253A (en) 1961-05-29 1961-05-29 Photographic emulsions containing delta-polycarbonyl sensitizers

Publications (1)

Publication Number Publication Date
GB1011978A true GB1011978A (en) 1965-12-01

Family

ID=22347439

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20377/62A Expired GB1011978A (en) 1961-05-29 1962-05-28 Photographic silver halide emulsions of increased sensitivity

Country Status (4)

Country Link
US (1) US3201253A (en)
BE (1) BE618140A (en)
FR (1) FR1330940A (en)
GB (1) GB1011978A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59188641A (en) 1983-04-11 1984-10-26 Fuji Photo Film Co Ltd Silver halide photographic emulsion
US5247122A (en) * 1991-06-03 1993-09-21 Eastman Kodak Company Thermosetting coating compositions

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR956701A (en) * 1941-11-13 1950-02-06
FR956682A (en) * 1942-03-21 1950-02-02
US2937088A (en) * 1958-01-13 1960-05-17 Eastman Kodak Co Diethylene glycol mixed esters
BE568153A (en) * 1958-05-30
US3046135A (en) * 1958-12-12 1962-07-24 Eastman Kodak Co Sensitization of photographic silver halide emulsions with sulfur-containing polymers
US3046129A (en) * 1958-12-12 1962-07-24 Eastman Kodak Co Sensitization of photographic silver halide emulsions containing colorforming compounds with polymeric thioethers
US3041171A (en) * 1959-04-30 1962-06-26 Eastman Kodak Co Solubilized derivatives of rosins

Also Published As

Publication number Publication date
BE618140A (en) 1962-09-17
US3201253A (en) 1965-08-17
FR1330940A (en) 1963-06-28

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