GB1010741A - Esters of thiocarbamic acid - Google Patents

Esters of thiocarbamic acid

Info

Publication number
GB1010741A
GB1010741A GB3763660A GB3763660A GB1010741A GB 1010741 A GB1010741 A GB 1010741A GB 3763660 A GB3763660 A GB 3763660A GB 3763660 A GB3763660 A GB 3763660A GB 1010741 A GB1010741 A GB 1010741A
Authority
GB
United Kingdom
Prior art keywords
alkyl
furfuryl
aralkyl
cycloalkyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3763660A
Inventor
Marion Wesley Harman
Amico John Joseph D
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Priority to GB3763660A priority Critical patent/GB1010741A/en
Publication of GB1010741A publication Critical patent/GB1010741A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
    • C07D295/21—Radicals derived from sulfur analogues of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/14—Radicals substituted by nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises thiocarbamic acid esters of the general formula <FORM:1010741/C2/1> in which R2 and R3 are alkyl, cycloalkyl, alkoxy-alkyl, aryl, aryloxyalkyl, aralkyl, aralkoxyalkyl, cyanoalkyl, alkenyl, haloalkenyl, cycloalkenyl, furfuryl, or tetrahydrofurfuryl groups, or together represent a polymethylene group which may be interrupted by an oxygen or nitrogen atom, not more than one of R2 and R3 being a cycloalkyl, aryl, alkoxyalkyl, aralkyl, aralkoxy-alkyl, furfuryl or tetrahydrofurfuryl group, and R4 is a trihaloalkenyl group. R2 and R3 preferably have not more than 6 carbon atoms and R4 preferably has 3 or 4 carbon atoms. The esters are prepared by heating an aqueous solution of an alkali metal salt of a thiocarbamic acid of formula <FORM:1010741/C2/2> with a halide R4X. Alternatively, an alkyl thionocarbamate of formula <FORM:1010741/C2/3> is heated with a halide R4X.ALSO:A weed-killing composition comprises a thiocarbamic ester of the general formula:- <FORM:1010741/A5-A6/1> in which R2 and R3 are alkyl, cycloalkyl, alkoxyalkyl, aryl, aryloxyalkyl, aralkyl, aralkoxyalkyl, cyanoalkyl, alkenyl, haloalkenyl, cycloalkenyl, furfuryl or tetrahydrofurfuryl groups or together represent a polymethylene groups which may be interrupted by an oxygen or nitrogen atom, not more than one of R2 and R3 being a cycloalkyl, aryl, alkoxyalkyl, aralkyl, aralkoxyalkyl, furfuryl or tetrahydrofurfuryl group, and R4 is a trihaloalkenyl group, together with a finely divided inert solid or a liquid inert diluent. The compounds may be used as sprays in organic solvents, or the solutions may be dispersed in water, preferably using an organic surface active agent. Finely divided inert solids may be impregnated with either the organic solutions or aqueous dispersions.
GB3763660A 1960-11-02 1960-11-02 Esters of thiocarbamic acid Expired GB1010741A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3763660A GB1010741A (en) 1960-11-02 1960-11-02 Esters of thiocarbamic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3763660A GB1010741A (en) 1960-11-02 1960-11-02 Esters of thiocarbamic acid

Publications (1)

Publication Number Publication Date
GB1010741A true GB1010741A (en) 1965-11-24

Family

ID=10397879

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3763660A Expired GB1010741A (en) 1960-11-02 1960-11-02 Esters of thiocarbamic acid

Country Status (1)

Country Link
GB (1) GB1010741A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011161425A1 (en) 2010-06-25 2011-12-29 Cambridge Display Technonogy Limited Organic light-emitting device and method
DE112011102125T5 (en) 2010-06-25 2013-04-25 Cambridge Display Technology Ltd. Organic light-emitting material, device and method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011161425A1 (en) 2010-06-25 2011-12-29 Cambridge Display Technonogy Limited Organic light-emitting device and method
WO2011161417A1 (en) 2010-06-25 2011-12-29 Cambridge Display Technology Limited Organic light-emitting material device and method
WO2011161416A2 (en) 2010-06-25 2011-12-29 Cambridge Display Technology Limited Organic light-emitting composition, device and method
WO2011161424A1 (en) 2010-06-25 2011-12-29 Cambridge Display Technology Limited Organic light-emitting device and method
DE112011102125T5 (en) 2010-06-25 2013-04-25 Cambridge Display Technology Ltd. Organic light-emitting material, device and method
DE112011102126T5 (en) 2010-06-25 2013-05-08 Cambridge Display Technology Limited Organic light-emitting composition, device and method
DE112011102127T5 (en) 2010-06-25 2013-05-29 Cambridge Display Technology Ltd. Organic light-emitting device and method

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