GB1007786A - Dyeable acrylonitrile polymer fibres - Google Patents

Dyeable acrylonitrile polymer fibres

Info

Publication number
GB1007786A
GB1007786A GB5310/64A GB531064A GB1007786A GB 1007786 A GB1007786 A GB 1007786A GB 5310/64 A GB5310/64 A GB 5310/64A GB 531064 A GB531064 A GB 531064A GB 1007786 A GB1007786 A GB 1007786A
Authority
GB
United Kingdom
Prior art keywords
sulphonate
sodium
atoms
radical
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5310/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1007786A publication Critical patent/GB1007786A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70—Material containing nitrile groups
    • D06P3/76—Material containing nitrile groups using basic dyes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
    • D01F11/06—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/927—Polyacrylonitrile fiber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Artificial Filaments (AREA)

Abstract

Acrylonitrile polymer fibres are treated in the gel state with a solution, preferably aqueous, containing 0.1-5%, on the height of solution, of an alkyl aryl sulphonate of the formula R-Ar-SO2O-X wherein X is a monovalent salt-forming radical, R is an alkyl radical of 4-12 C atoms and Ar is an aromatic hydrocarbon radical of 6-12 C atoms, and thereafter dried to form fibres of improved dyeability. The preferred sulphonates are the isopropylamine or sodium salt of p-dodecryl-benzenesulphonate, sodium 2-butylnaphthalene-6-sulphonate and sodium 2-isopropylnaphthalene-6-sulphonate. The acrylonitrile polymers may contain 2-20% of other copolymerisable mono-olefinic monomers (many specified). Other known agents may also be incorporated in the polymer or applied in the course of the process, e.g. heat and light stabilisers, delusterants, plasticisers, lubricants and anti-static agents. Examples of treating and dyeing with basic dyes are given.
GB5310/64A 1963-02-14 1964-02-07 Dyeable acrylonitrile polymer fibres Expired GB1007786A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US258631A US3300272A (en) 1963-02-14 1963-02-14 Process for the preparation of dyeable acrylonitrile polymer fibers and compositions thereof

Publications (1)

Publication Number Publication Date
GB1007786A true GB1007786A (en) 1965-10-22

Family

ID=22981433

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5310/64A Expired GB1007786A (en) 1963-02-14 1964-02-07 Dyeable acrylonitrile polymer fibres

Country Status (10)

Country Link
US (1) US3300272A (en)
BE (1) BE643829A (en)
CH (1) CH438573A (en)
DE (1) DE1494668A1 (en)
DK (1) DK109964C (en)
FR (1) FR1397262A (en)
GB (1) GB1007786A (en)
LU (1) LU45412A1 (en)
NL (1) NL6401277A (en)
SE (1) SE302655B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3402014A (en) * 1962-11-19 1968-09-17 Monsanto Co Preparation of dyeable acrylic fibers and filaments
US3506991A (en) * 1964-07-01 1970-04-21 Celanese Corp Dye receptive fibers and method of preparing same
US3473881A (en) * 1965-01-14 1969-10-21 Du Pont Process for the dyeing of anionic polymeric synthetic textiles and blends with cellulose with basic dye bases
US3418290A (en) * 1965-10-18 1968-12-24 Du Pont Sulfonated caprolactones and polymerization with 2,2-dialkyl-3-propiolactones
US3619105A (en) * 1967-09-22 1971-11-09 Eastman Kodak Co Cellulose ester fiber with d,hexyl sodium sulfosuccinate therein and dyeing thereof
US5326391A (en) * 1992-11-18 1994-07-05 Ppg Industries, Inc. Microporous material exhibiting increased whiteness retention

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2484430A (en) * 1946-12-31 1949-10-11 Eastman Kodak Co Quaternary salts of polyvinyl pyridine and polyvinyl quinoline
US2759975A (en) * 1952-05-28 1956-08-21 Gen Aniline & Film Corp Mixed alkyl-benzyl-alkylol quaternary ammonium salts
NL258181A (en) * 1959-11-24 Boehme Chemie Gmbh
US3097054A (en) * 1960-08-26 1963-07-09 Dow Chemical Co Method of making high-shrink textile fibers

Also Published As

Publication number Publication date
SE302655B (en) 1968-07-29
DK109964C (en) 1968-08-12
BE643829A (en) 1964-08-14
LU45412A1 (en) 1964-08-13
FR1397262A (en) 1965-04-30
DE1494668A1 (en) 1969-12-11
CH438573A (en) 1967-06-30
US3300272A (en) 1967-01-24
NL6401277A (en) 1964-08-17

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