GB1001820A - Process for the polymerization of ª‡-olefinic hydrocarbon material and catalysts for effecting such polymerization - Google Patents
Process for the polymerization of ª‡-olefinic hydrocarbon material and catalysts for effecting such polymerizationInfo
- Publication number
- GB1001820A GB1001820A GB2876264A GB2876264A GB1001820A GB 1001820 A GB1001820 A GB 1001820A GB 2876264 A GB2876264 A GB 2876264A GB 2876264 A GB2876264 A GB 2876264A GB 1001820 A GB1001820 A GB 1001820A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerization
- catalyst
- aluminium
- halide
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A polymerization catalyst is formed from the components (1) a halide or alkoxide containing from 1 to 8 carbon atoms of titanium, zirconium, vanadium, chromium or molybdenum, (2) at least one component selected from the following: (a) the metals of Groups IA, II and IIIA of the Mendeleeff Periodic Table, or alkyl or hydride derivatives thereof or complex metal hydrides of aluminium and alkali metal; (b) organoaluminium halides having the formula RmAlXn and R3Al2X3, wherein R represents an alkyl or cycloalkyl group containing from 1 to 6 carbon atoms or a phenyl or tolyl group, X represents chlorine or bromine and m and n are integers whose sum is equivalent to the valency of aluminium and (c) a polymeric reaction product of aluminium and a methylene halide, and (3) a Friedel-Crafts halide of an element of Groups II to VI and VIII of the Mendeleeff Periodic Table in a complex with a catalyst component capable of increasing the stereospecificity of the catalyst mixture. The catalyst is used for the polymerization of a -mono- and di-olefins in the normal manner, preferably in solution in the usual organic solvents. Monomers exemplified are: ethylene, propylene, butene-1, 3-methyl butene-1, 4-methyl pentene-1, 3-methyl hexene-1, allyl cyclohexane, styrene, butadiene, and isoprene. Long lists of suitable catalyst components are given; those exemplified are: (1) TiCl3, TiCl4; (2) (C2H5)2AlCl, C2H5AlCl2, Al metal; (3) complexes of: AlCl3, BeCl3 or TiCl4 with hexamethylphosphoric triamide; AlCl3, SnCl2 or BF3 with diphenyl ether; AlBr3 or ZrCl4 with titanium tetrabutoxide; ZnCl2 with NaF or PO(OC2H5); AlBr3 with sodium acetate; MgCl2 with dimethylformamide; and the complexes (C2H5)2AlCl.CaO and C2H5AlCl2.P(C6H5)3. Polymerization may be effected in the presence of hydrogen. The polymers produced are highly crystalline and may be formed into plates, sheets, films, fibres or moulded articles.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30834263A | 1963-09-12 | 1963-09-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1001820A true GB1001820A (en) | 1965-08-18 |
Family
ID=23193605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2876264A Expired GB1001820A (en) | 1963-09-12 | 1964-07-13 | Process for the polymerization of ª‡-olefinic hydrocarbon material and catalysts for effecting such polymerization |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1495611A1 (en) |
| GB (1) | GB1001820A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1301898B (en) * | 1965-12-22 | 1969-08-28 | Inst Francais Du Petrol | Process for the polymerization and interpolymerization of conjugated dienes |
| US4028481A (en) | 1970-06-18 | 1977-06-07 | Mitsui Toatsu Chemicals, Incorporated | Production of olefin polymers and novel catalysts therefore |
| US4048415A (en) * | 1970-10-02 | 1977-09-13 | Mitsui Petrochemical Industries Ltd. | Process for polymerization of olefins and catalyst composition therefor |
| US4103078A (en) | 1969-08-01 | 1978-07-25 | Chisso Corporation | Method for producing polymers of alpha-olefin |
| US4135045A (en) | 1970-10-02 | 1979-01-16 | Mitsui Petrochemical Industries, Ltd. | Process for polymerization of olefins and catalyst composition therefor |
| US4210738A (en) | 1971-03-23 | 1980-07-01 | Solvay & Cie. | Catalytic complexes |
| US4304891A (en) * | 1980-03-22 | 1981-12-08 | Chisso Corporation | Process for producing α-olefin polymers |
| US4319010A (en) | 1970-12-02 | 1982-03-09 | Stamicarbon, B.V. | Process for the polymerization of alkenes |
| US5210161A (en) * | 1983-04-26 | 1993-05-11 | Phillips Petroleum Company | Supported vanadium dihalide-ether complex catalyst |
-
1964
- 1964-07-13 GB GB2876264A patent/GB1001820A/en not_active Expired
- 1964-08-22 DE DE19641495611 patent/DE1495611A1/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1301898B (en) * | 1965-12-22 | 1969-08-28 | Inst Francais Du Petrol | Process for the polymerization and interpolymerization of conjugated dienes |
| US4103078A (en) | 1969-08-01 | 1978-07-25 | Chisso Corporation | Method for producing polymers of alpha-olefin |
| US4028481A (en) | 1970-06-18 | 1977-06-07 | Mitsui Toatsu Chemicals, Incorporated | Production of olefin polymers and novel catalysts therefore |
| US4048415A (en) * | 1970-10-02 | 1977-09-13 | Mitsui Petrochemical Industries Ltd. | Process for polymerization of olefins and catalyst composition therefor |
| US4135045A (en) | 1970-10-02 | 1979-01-16 | Mitsui Petrochemical Industries, Ltd. | Process for polymerization of olefins and catalyst composition therefor |
| US4319010A (en) | 1970-12-02 | 1982-03-09 | Stamicarbon, B.V. | Process for the polymerization of alkenes |
| US4210738A (en) | 1971-03-23 | 1980-07-01 | Solvay & Cie. | Catalytic complexes |
| US4304891A (en) * | 1980-03-22 | 1981-12-08 | Chisso Corporation | Process for producing α-olefin polymers |
| US5210161A (en) * | 1983-04-26 | 1993-05-11 | Phillips Petroleum Company | Supported vanadium dihalide-ether complex catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1495611A1 (en) | 1969-11-20 |
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