GB1000679A - Organic polymers for use as electrical semi-conductors - Google Patents

Organic polymers for use as electrical semi-conductors

Info

Publication number
GB1000679A
GB1000679A GB14641/64A GB1464164A GB1000679A GB 1000679 A GB1000679 A GB 1000679A GB 14641/64 A GB14641/64 A GB 14641/64A GB 1464164 A GB1464164 A GB 1464164A GB 1000679 A GB1000679 A GB 1000679A
Authority
GB
United Kingdom
Prior art keywords
mixed
friedel
polymers
aromatic nucleus
aluminium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14641/64A
Inventor
Herbert Naarmann
Fritz Beck
Ernst-Guenther Kastning
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1000679A publication Critical patent/GB1000679A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Polymers suitable for use as electrical semi-conductors are obtained by heating a compound having an aromatic nucleus which is either a hydrocarbon or a hydrocarbon having a hetero atom in the aromatic nucleus, with a substance, or mixture of substances, which acts both as a Friedel-Crafts catalyst and as a dehydrogenating agent, at 100 DEG to 800 DEG C. in the presence of an inert gas and in the absence of oxygen. The polymer may have a conductivity of 10-10 to 10-0.5 mho. The compound having an aromatic nucleus may be benzene, toluene, xylene, diphenyl, pyrene, perylene, naphthalene, anthracene, phenanthrene, thiophene, pyrrole, indole or carbazole. Either a substance acting as a Friedel-Crafts catalyst mixed with a substance acting as a dehydrogenating agent, or a substance acting both as a Friedel-Crafts catalyst and as a dehydrogenating agent, may be used. In examples, polymers are prepared in the presence of aluminium trichloride mixed with copper dichloride, aluminium tribromide mixed with copper dichloride, aluminium trichloride mixed with iron trichloride, titanium tetrachloride mixed with iron trichloride, and aluminium trichloride mixed with tetrachloroquinone. The conductivity of the polymers may be increased by heating them at 100 DEG to 1000 DEG C. in an inert atmosphere.
GB14641/64A 1963-04-11 1964-04-09 Organic polymers for use as electrical semi-conductors Expired GB1000679A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB71493A DE1178529B (en) 1963-04-11 1963-04-11 Use of organic polycondensation products as electrical, especially light-electrical, semiconductor bodies

Publications (1)

Publication Number Publication Date
GB1000679A true GB1000679A (en) 1965-08-11

Family

ID=6977058

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14641/64A Expired GB1000679A (en) 1963-04-11 1964-04-09 Organic polymers for use as electrical semi-conductors

Country Status (5)

Country Link
BE (1) BE646441A (en)
CH (1) CH444314A (en)
DE (1) DE1178529B (en)
GB (1) GB1000679A (en)
NL (1) NL6403752A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3494877A (en) * 1968-02-28 1970-02-10 Dow Chemical Co Polymerizing aromatic hydrocarbons by regenerative oxidation coupling
EP0016305A1 (en) * 1979-03-20 1980-10-01 Allied Corporation Electrically conducting compositions derived from poly(phenylene), and shaped article comprising such a composition
EP0023595A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic
EP0023596A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic
EP0031967A2 (en) * 1980-01-07 1981-07-15 BASF Aktiengesellschaft Process for preparing electrically conductive poly-aromatic polymers, their use in electrical engineering and as antistatic additives for plastics
EP0095412A1 (en) * 1982-05-25 1983-11-30 Thomson-Csf Polymers containing heterocycles and aromatic nuclei, and organic conductor materials made from these polymers
US4462929A (en) * 1982-09-30 1984-07-31 Allied Corporation Solution of a chalcogen-containing polymer in acids and process of forming polymer articles therefrom
US5204423A (en) * 1988-06-13 1993-04-20 Solvay & Cie Process for the preparation of polythiophenes by use of ferric salts and alkyl halides
US5221786A (en) * 1989-06-12 1993-06-22 Solvay & Cie (Societe Anonyme) Process for the preparation of polythiophenes and electrically conducting devices containing them
US5254648A (en) * 1989-06-12 1993-10-19 Solvay & Cie (Societe Anonyme) Process for the preparation of polythiophenes and electrically conducting devices containing them
US5290891A (en) * 1991-04-16 1994-03-01 Solvay (Societe Anonyme) Process for the preparation of polyindoles, electroconductive compositions and devices containing them and applications of the polyindoles
WO2004087782A1 (en) * 2003-03-31 2004-10-14 Council Of Scientific And Industrial Research Copolymer of benzine and substituted benzene
US7186793B2 (en) 2003-03-31 2007-03-06 Council Of Scientific And Industrial Research Recording/playback apparatus, recording/playback method, program, and storage medium

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3480568A (en) * 1965-02-24 1969-11-25 Union Oil Co Polymerization of benzene in the presence of oxygen and cupric and aluminum chloride
DE3005300A1 (en) * 1980-02-13 1981-08-20 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3005299A1 (en) * 1980-02-13 1981-08-20 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3009351A1 (en) * 1980-03-12 1981-09-24 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE HETEROPOLYPHENYLENES AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3009350A1 (en) * 1980-03-12 1981-09-24 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE HETEROPOLYAROMATS AND THE USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3018459A1 (en) * 1980-05-14 1981-11-19 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE SOLUBLE HETEROPOLYPHENYLENE AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3025771A1 (en) * 1980-07-08 1982-02-04 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE SOLUBLE HETEROPOLYPHENYLENE AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS
DE3026328A1 (en) * 1980-07-11 1982-02-18 Basf Ag, 6700 Ludwigshafen METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYMERIC SYSTEMS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3494877A (en) * 1968-02-28 1970-02-10 Dow Chemical Co Polymerizing aromatic hydrocarbons by regenerative oxidation coupling
EP0016305A1 (en) * 1979-03-20 1980-10-01 Allied Corporation Electrically conducting compositions derived from poly(phenylene), and shaped article comprising such a composition
EP0023595A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic
EP0023596A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic
EP0031967A2 (en) * 1980-01-07 1981-07-15 BASF Aktiengesellschaft Process for preparing electrically conductive poly-aromatic polymers, their use in electrical engineering and as antistatic additives for plastics
EP0031967A3 (en) * 1980-01-07 1981-08-05 Basf Aktiengesellschaft Process for preparing electrically conductive poly-aromatic polymers, their use in electrical engineering and as antistatic additives for plastics
US4508639A (en) * 1982-05-25 1985-04-02 Thomson-Csf Polymers containing heterocycles and aromatic nuclei, and conductive organic materials made from such polymers
EP0095412A1 (en) * 1982-05-25 1983-11-30 Thomson-Csf Polymers containing heterocycles and aromatic nuclei, and organic conductor materials made from these polymers
FR2527618A1 (en) * 1982-05-25 1983-12-02 Thomson Csf POLYMERS CONTAINING HETEROCYCLES AND AROMATIC CORES AND CONDUCTIVE ORGANIC MATERIALS FORMED THEREFROM
US4462929A (en) * 1982-09-30 1984-07-31 Allied Corporation Solution of a chalcogen-containing polymer in acids and process of forming polymer articles therefrom
US5204423A (en) * 1988-06-13 1993-04-20 Solvay & Cie Process for the preparation of polythiophenes by use of ferric salts and alkyl halides
US5221786A (en) * 1989-06-12 1993-06-22 Solvay & Cie (Societe Anonyme) Process for the preparation of polythiophenes and electrically conducting devices containing them
US5254648A (en) * 1989-06-12 1993-10-19 Solvay & Cie (Societe Anonyme) Process for the preparation of polythiophenes and electrically conducting devices containing them
US5290891A (en) * 1991-04-16 1994-03-01 Solvay (Societe Anonyme) Process for the preparation of polyindoles, electroconductive compositions and devices containing them and applications of the polyindoles
WO2004087782A1 (en) * 2003-03-31 2004-10-14 Council Of Scientific And Industrial Research Copolymer of benzine and substituted benzene
US7186793B2 (en) 2003-03-31 2007-03-06 Council Of Scientific And Industrial Research Recording/playback apparatus, recording/playback method, program, and storage medium

Also Published As

Publication number Publication date
NL6403752A (en) 1964-10-12
DE1178529B (en) 1964-09-24
CH444314A (en) 1967-09-30
BE646441A (en) 1964-10-12

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