FR3130136A1 - Water-in-oil emulsions comprising a surfactant, a water-soluble vinyl polymer and an organosiloxane - Google Patents

Water-in-oil emulsions comprising a surfactant, a water-soluble vinyl polymer and an organosiloxane Download PDF

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FR3130136A1
FR3130136A1 FR2113477A FR2113477A FR3130136A1 FR 3130136 A1 FR3130136 A1 FR 3130136A1 FR 2113477 A FR2113477 A FR 2113477A FR 2113477 A FR2113477 A FR 2113477A FR 3130136 A1 FR3130136 A1 FR 3130136A1
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water
composition
composition according
vinyl polymer
soluble vinyl
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French (fr)
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Geoffrey White
Aline Aude GUIMONT
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LOreal SA
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LOreal SA
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585Organosilicon compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

Abstract

É mulsions eau dans l’huile comprenant un tensioactif, un polym è re vinylique soluble dans l’eau et un organosiloxane Une composition en émulsion eau dans l’huile comprenant (a) de l’eau, (b) au moins une huile, (c) au moins un tensioactif, (d) au moins un polymère vinylique soluble dans l’eau, et (e) au moins un filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone est proposée. La composition peut être une composition pour les cils, par exemple une composition de mascara incluant en outre au moins un colorant. Figure pour l’abrégé : NÉANTWater-in-oil emulsions comprising a surfactant, a water-soluble vinyl polymer and an organosiloxane A water-in-oil emulsion composition comprising (a) water, (b) at least one oil, (c) at least one surfactant, (d) at least one water-soluble vinyl polymer, and (e) at least one organosiloxane film former which is selected from silicone resin and acrylic/silicone random graft copolymer is provided. The composition can be a composition for the eyelashes, for example a mascara composition additionally including at least one colorant. Figure for abstract: NIL

Description

Émulsions eau dans l’huile comprenant un tensioactif, un polymère vinylique soluble dans l’eau et un organosiloxaneWater-in-oil emulsions comprising a surfactant, a water-soluble vinyl polymer and an organosiloxane

DOMAINE DE L’INVENTIONFIELD OF THE INVENTION

La présente invention concerne des émulsions (compositions) eau dans l’huile (e/h) comprenant (1) au moins un tensioactif (2) au moins polymère vinylique soluble dans l’eau, et (3) au moins un filmogène organosiloxane. Les compositions ont des propriétés cosmétiques bénéfiques dont des propriétés de tenue, résistance au sébum et/ou résistance à l’eau bonnes ou améliorées. De manière significative, les compositions ont également des propriétés de résistance et d’élimination du sébum bonnes ou améliorées.The present invention relates to water-in-oil (w/o) emulsions (compositions) comprising (1) at least one surfactant (2) at least one water-soluble vinyl polymer, and (3) at least one organosiloxane film former. The compositions have beneficial cosmetic properties including good or improved holding properties, sebum resistance and/or water resistance. Significantly, the compositions also have good or improved strength and sebum removal properties.

discussion du contextediscussion of context

Des compositions de mascara sont couramment utilisées pour renforcer l’aspect des cils. Les compositions de mascara conventionnelles utilisent généralement des cires pour former des structures de réseau cristallin afin de renforcer courbure, volume, longueur, épaisseur et/ou couleurs des cils. Cependant, les compositions de mascara conventionnelles incluant des cires ont tendance à devenir moins résistantes à l’huile et/ou au sébum, provoquant maculage, écaillage et/ou transfert de couleur après un certain temps d’utilisation.Mascara compositions are commonly used to enhance the appearance of eyelashes. Conventional mascara compositions generally use waxes to form crystal lattice structures to enhance curvature, volume, length, thickness and/or color of eyelashes. However, conventional mascara compositions including waxes tend to become less resistant to oil and/or sebum, causing smudging, flaking and/or color transfer after some time of use.

Les mascaras sont notamment préparés à partir de deux types de formulations : les mascaras aqueux dits mascaras crème, sous forme d’une dispersion de cires dans l’eau, et les mascaras anhydres ou à faible teneur en eau, dits mascaras résistants à l’eau (qualifiés de « hydrofuges »), sous forme de dispersions de cires dans des solvants organiques.Mascaras are in particular prepared from two types of formulations: aqueous mascaras known as cream mascaras, in the form of a dispersion of waxes in water, and anhydrous or low water content mascaras, known as heat-resistant mascaras. water (qualified as “water repellents”), in the form of dispersions of waxes in organic solvents.

Les mascaras aqueux contiennent principalement un système de tensioactif, par exemple à base de stéarate de triéthanolamine, qui permet d’obtenir une dispersion stable de particules de cire agglomérées dans une phase aqueuse. Ce système joue un rôle important dans l’obtention d’une telle dispersion, notamment à l’interface dans les interactions entre particules de cire.Aqueous mascaras mainly contain a surfactant system, for example based on triethanolamine stearate, which makes it possible to obtain a stable dispersion of agglomerated wax particles in an aqueous phase. This system plays an important role in obtaining such a dispersion, especially at the interface in the interactions between wax particles.

Les mascaras anhydres ont tendance à présenter les inconvénients, entre autres, d’être secs, d’avoir une mauvaise flexibilité et/ou une mauvaise consistance. De plus, les consommateurs ont des difficultés à retirer de tels mascaras des cils.Anhydrous mascaras tend to have the disadvantages of being dry, having poor flexibility and/or poor consistency, among others. In addition, consumers have difficulty removing such mascaras from eyelashes.

WO 2019/122102 a trait à une émulsion directe à utiliser sur les lèvres contenant au moins 10 % de résine de silicone.WO 2019/122102 relates to a direct emulsion for use on the lips containing at least 10% silicone resin.

WO 2014/046883 a trait à une composition cosmétique pulvérulente en barbotine contenant des particules enrobées d’une composition de liant, d’une composition de gel de silicone, et le résidu d’évaporation d’une composition à base d’alcool et un procédé de fabrication de la composition.WO 2014/046883 relates to a pulverulent cosmetic composition in slip form containing particles coated with a binder composition, a silicone gel composition, and the evaporation residue of an alcohol-based composition and a method of making the composition.

WO 2010/149493 a trait à une composition de maquillage et/ou de soin des matières kératineuses, comprenant au moins une phase grasse, au moins une résine de silicone et au moins un copolymère de styrène/acrylate.WO 2010/149493 relates to a composition for making up and/or caring for keratinous materials, comprising at least one fatty phase, at least one silicone resin and at least one styrene/acrylate copolymer.

WO 2014/143757 a trait à des compositions contenant une émulsion de résine de silicone contenant 0,5 % en poids à 95 % en poids d’une résine de silicone ou d’un adhésif sensible à la pression (ASP), 0,1 à 90 % en poids d’un copolymère séquencé d’oxyde d’éthylène/oxyde de propylène, et une quantité suffisante d’eau pour compléter à 100 % en poids.WO 2014/143757 relates to compositions containing a silicone resin emulsion containing 0.5% by weight to 95% by weight of a silicone resin or a pressure sensitive adhesive (PSA), 0.1 to 90% by weight of an ethylene oxide/propylene oxide block copolymer, and a sufficient amount of water to make up to 100% by weight.

US 10 441 527 a trait à des compositions fluides contenant de multiples composants, dont le premier peut inclure un copolymère qui est un siloxane réticulé (par exemple un aminosiloxane réticulé), un copolymère de silicone polyéther (par exemple un copolymère de silicone polyéther (AB)n), et/ou un copolymère de saccharide siloxane, et dont le second peut inclure une résine organopolysiloxane et/ou un copolymère d’acrylate.US 10,441,527 relates to fluid compositions containing multiple components, the first of which may include a copolymer which is a cross-linked siloxane (e.g. a cross-linked aminosiloxane), a silicone polyether copolymer (e.g. a silicone polyether copolymer (AB )n), and/or a saccharide siloxane copolymer, and the latter of which may include an organopolysiloxane resin and/or an acrylate copolymer.

FR 2968983 a trait à des compositions anhydres fluides contenant au moins une poudre d’élastomère d’organopolysiloxane enrobée de résine de silicone ; au moins un véhicule élastomère d’organopolysiloxane dans une première huile ; au moins une cire ; au moins une laque organique ; et au moins une seconde huile.FR 2968983 relates to fluid anhydrous compositions containing at least one organopolysiloxane elastomer powder coated with silicone resin; at least one organopolysiloxane elastomeric vehicle in a first oil; at least one wax; at least one organic lacquer; and at least a second oil.

Le document US 2006/0078578 a trait à des compositions filmogènes contenant un minéral montmorillonite non quaternaire dispersé et un composant filmogène.US 2006/0078578 relates to film-forming compositions containing a dispersed non-quaternary montmorillonite mineral and a film-forming component.

Il existe un besoin de développer une composition cosmétique, en particulier pour le maquillage des cils, permettant d’obtenir un produit de bonne tenue, résistant à l’eau et au sébum et stable et/ou facile à éliminer.There is a need to develop a cosmetic composition, in particular for making up the eyelashes, making it possible to obtain a product with good staying power, resistant to water and to sebum and stable and/or easy to remove.

La présente invention concerne des émulsions eau dans l’huile (e/h) pour cheveux, cils et/ou sourcils comprenant au moins un tensioactif, au moins un polymère vinylique soluble dans l’eau et au moins un filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone. De préférence, la composition est une composition pour les cils. De manière préférée entre toutes, la composition est une composition de mascara comprenant en outre au moins un colorant. Dans certains modes de réalisation, la composition est sensiblement exempte de polymères acryliques incluant des groupes styrène.The present invention relates to water-in-oil (w/o) emulsions for hair, eyelashes and/or eyebrows comprising at least one surfactant, at least one water-soluble vinyl polymer and at least one organosiloxane film former which is chosen from a silicone resin and an acrylic/silicone random graft copolymer. Preferably, the composition is an eyelash composition. Most preferably, the composition is a mascara composition further comprising at least one colorant. In some embodiments, the composition is substantially free of acrylic polymers including styrene groups.

Dans un autre aspect, la présente invention concerne des compositions en émulsion eau dans l’huile (e/h) pour les cils et/ou les sourcils (par exemple, un mascara) comprenant de l’eau, au moins une huile, au moins une cire en une quantité d’environ 10 % à environ 25 % en poids du poids total de la composition. Elle comprend en outre un tensioactif de faible valeur HLB comprenant un squelette et un (des) groupe(s) pendant(s), dans lequel (1) le squelette est hydrophobe et un ou plusieurs groupes pendants est (sont) hydrophile(s) ou (2) le squelette est hydrophile et un ou plusieurs groupes pendants est (sont) hydrophobe(s). Elle comprend en outre au moins une gomme de silicone et un polymère vinylique soluble dans l’eau ; un filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone ; et facultativement au moins un colorant. Dans certains modes de réalisation, la composition est sensiblement exempte de polymères acryliques qui incluent des groupes styrène.In another aspect, the present invention relates to compositions in water-in-oil (w/o) emulsion for the eyelashes and/or the eyebrows (for example, a mascara) comprising water, at least one oil, least one wax in an amount from about 10% to about 25% by weight of the total weight of the composition. It further comprises a low HLB surfactant comprising a backbone and pendant group(s), wherein (1) the backbone is hydrophobic and one or more pendant groups is (are) hydrophilic or (2) the backbone is hydrophilic and one or more pendant groups is (are) hydrophobic. It further comprises at least one silicone gum and one water-soluble vinyl polymer; an organosiloxane film former which is chosen from a silicone resin and an acrylic/silicone random graft copolymer; and optionally at least one colorant. In some embodiments, the composition is substantially free of acrylic polymers that include styrene groups.

Dans un autre aspect, la présente invention concerne des compositions en émulsion eau dans l’huile (e/h) pour les cils et/ou les sourcils (par exemple, un mascara) comprenant au moins un tensioactif ; un polymère vinylique soluble dans l’eau ; un filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone ; et facultativement au moins un colorant.In another aspect, the present invention relates to compositions in water-in-oil (w/o) emulsion for the eyelashes and/or the eyebrows (for example, a mascara) comprising at least one surfactant; a water-soluble vinyl polymer; an organosiloxane film former which is chosen from a silicone resin and an acrylic/silicone random graft copolymer; and optionally at least one colorant.

La présente invention concerne également des procédés de traitement, de soin et/ou de maquillage des cheveux, des cils et/ou des sourcils par application de compositions de la présente invention sur les cheveux, les cils et/ou les sourcils en une quantité suffisante pour traiter, soigner et/ou maquiller les cheveux, les cils et/ou les sourcils. De préférence, la composition est une composition pour les cils. De manière préférée entre toutes, la composition est une composition de mascara comprenant en outre au moins un colorant.The present invention also relates to methods for treating, caring for and/or making up the hair, the eyelashes and/or the eyebrows by applying compositions of the present invention to the hair, the eyelashes and/or the eyebrows in a sufficient quantity. for treating, caring for and/or making up the hair, the eyelashes and/or the eyebrows. Preferably, the composition is an eyelash composition. Most preferably, the composition is a mascara composition further comprising at least one colorant.

Claims (10)

Composition en émulsion eau dans l’huile comprenant (a) de l'eau, (b) au moins une huile, (c) au moins un tensioactif à faible HLB, (d) au moins un polymère vinylique soluble dans l'eau, et (e) au moins un filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone, dans laquelle la composition est sensiblement exempte de polymères acryliques qui comprennent des groupes styrène.A water-in-oil emulsion composition comprising (a) water, (b) at least one oil, (c) at least one low HLB surfactant, (d) at least one water-soluble vinyl polymer, and (e) at least one organosiloxane film former which is selected from a silicone resin and an acrylic/silicone random graft copolymer, wherein the composition is substantially free of acrylic polymers which include styrene groups. Composition selon la revendication 1, comprenant en outre au moins une gomme de silicone.Composition according to Claim 1, further comprising at least one silicone gum. Composition selon l’une quelconque des revendications précédentes, dans laquelle la composition comprend d'environ 2% à environ 6% en poids par rapport au poids total de la composition de l’au moins un polymère vinylique soluble dans l'eau.Composition according to any one of the preceding claims, in which the composition comprises from about 2% to about 6% by weight relative to the total weight of the composition of the at least one water-soluble vinyl polymer. Composition selon l’une quelconque des revendications précédentes, dans laquelle l’au moins un filmogène organosiloxane est une résine de triméthylsiloxysilicate.A composition according to any preceding claim, wherein the at least one organosiloxane film former is a trimethylsiloxysilicate resin. Composition selon l’une quelconque des revendications précédentes, dans laquelle le polymère vinylique soluble dans l'eau est la polyvinylpyrrolidone.A composition according to any preceding claim, wherein the water-soluble vinyl polymer is polyvinylpyrrolidone. Composition selon l’une quelconque des revendications précédentes, comprenant en outre au moins une cire en une quantité comprise entre environ 10 % et environ 25 % en poids du poids total de la composition, et.Composition according to any one of the preceding claims, further comprising at least one wax in an amount of between about 10% and about 25% by weight of the total weight of the composition, and. Composition selon l’une quelconque des revendications précédentes, dans laquelle la composition comprend au moins 1% en poids d'une ou plusieurs cires ayant un point de fusion supérieur à 65°C.Composition according to any one of the preceding claims, in which the composition comprises at least 1% by weight of one or more waxes having a melting point above 65°C. Composition selon l’une quelconque des revendications précédentes, comprenant en outre au moins un colorant.Composition according to any one of the preceding claims, further comprising at least one colorant. Composition selon l’une quelconque des revendications précédentes, comprenant en outre au moins une argile de silicate hydrophobe.A composition according to any preceding claim, further comprising at least one hydrophobic silicate clay. Composition selon l’une quelconque des revendications précédentes, dans laquelle le filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone est présent en une quantité d'environ 1% à environ 10% en poids du poids total de la composition et/ou le rapport pondéral du filmogène organosiloxane qui est choisi parmi une résine de silicone et un copolymère greffé statistique acrylique/silicone sur le polymère vinylique soluble dans l'eau est présent dans une plage de 1:1 à environ 5:1, de préférence de 2:1 à environ 4:1.A composition according to any preceding claim, wherein the organosiloxane film former which is selected from a silicone resin and an acrylic/silicone random graft copolymer is present in an amount of from about 1% to about 10% by weight of the total weight of the composition and/or the weight ratio of the organosiloxane film former which is selected from a silicone resin and an acrylic/silicone random graft copolymer to the water-soluble vinyl polymer is present in a range from 1:1 to about 5: 1, preferably from 2:1 to about 4:1.
FR2113477A 2021-12-14 2021-12-14 Water-in-oil emulsions comprising a surfactant, a water-soluble vinyl polymer and an organosiloxane Pending FR3130136A1 (en)

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