FR3128475A1 - Insulating panel made of composite materials and its method of manufacture - Google Patents

Insulating panel made of composite materials and its method of manufacture Download PDF

Info

Publication number
FR3128475A1
FR3128475A1 FR2111277A FR2111277A FR3128475A1 FR 3128475 A1 FR3128475 A1 FR 3128475A1 FR 2111277 A FR2111277 A FR 2111277A FR 2111277 A FR2111277 A FR 2111277A FR 3128475 A1 FR3128475 A1 FR 3128475A1
Authority
FR
France
Prior art keywords
panel
binder
cork
mass
polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR2111277A
Other languages
French (fr)
Inventor
Patrick Vidal
Rémi Auvergne
Sylvain Caillol
Benjamin CHOLLET
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vidals Acier
Vidal's Acier
Centre National de la Recherche Scientifique CNRS
Universite de Montpellier I
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Universite de Montpellier
Original Assignee
Vidals Acier
Vidal's Acier
Centre National de la Recherche Scientifique CNRS
Universite de Montpellier I
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Universite de Montpellier
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vidals Acier, Vidal's Acier, Centre National de la Recherche Scientifique CNRS, Universite de Montpellier I, Ecole Nationale Superieure de Chimie de Montpellier ENSCM, Universite de Montpellier filed Critical Vidals Acier
Priority to FR2111277A priority Critical patent/FR3128475A1/en
Priority to PCT/EP2022/079176 priority patent/WO2023067045A1/en
Publication of FR3128475A1 publication Critical patent/FR3128475A1/en
Pending legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/16Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of fibres or chips, e.g. bonded with synthetic resins, or with an outer layer of fibres or chips
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0866Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/18Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of organic plastics with or without reinforcements or filling materials or with an outer layer of organic plastics with or without reinforcements or filling materials; plastic tiles

Abstract

Panneau isolant en matériaux composites et son procédé de fabrication La présente invention a pour objet panneau (1) isolant à base de matériaux composites, caractérisé en ce qu’il comporte au moins: - une couche (2) comportant un mélange d’au moins un liant et de liège , - une tôle (3) métallique plane ou profilée. [Fig 1]Insulating panel made of composite materials and its method of manufacture The present invention relates to an insulating panel (1) based on composite materials, characterized in that it comprises at least: - a layer (2) comprising a mixture of at least a binder and cork, - a flat or profiled metal sheet (3). [Fig 1]

Description

Panneau isolant en matériaux compositeset son procédé de fabricationInsulating panel made of composite materials and its method of manufacture

Domaine technique de l'inventionTechnical field of the invention

La présente invention concerne le domaine des panneaux pour l’isolation thermique et phonique et, plus particulièrement, des panneaux isolants à base de matériaux bio-sourcés respectueux de l’environnement.The present invention relates to the field of panels for thermal and sound insulation and, more particularly, insulating panels based on bio-sourced materials that respect the environment.

Etat de la techniqueState of the art

Dans le domaine des panneaux isolants (isolant pour l’enveloppe d’un bâtiment), il est connu d'utiliser des plaques d’isolation en polyuréthane et polyisocyanurate. Les inconvénients de ce type de plaques sont qu’elles sont constituées de matériaux qui ne respectent pas l’environnement et qu’elles ont des performances faibles en Eté. En effet, elles permettent de maintenir la chaleur à l’intérieur des bâtiments en Hiver mais en Eté, à la tombée de la nuit, lorsque la température extérieure devient inférieure à la température intérieure, ces plaques ne permettent pas aux bâtiments de se rafraîchir et leur utilisation impose donc souvent l’usage d’un système de climatisation intérieur, c’est ce que l’on appelle le déphasage. L’impact environnemental négatif de ce type d’isolation est donc double : l’utilisation d’un isolant pétro-sourcé de manière importante et la nécessité d’utiliser un dispositif de climatisation en Eté augmentent l’empreinte carbone.In the field of insulating panels (insulation for the envelope of a building), it is known to use polyurethane and polyisocyanurate insulation plates. The disadvantages of this type of plates are that they are made of materials that do not respect the environment and that they have poor performance in summer. Indeed, they make it possible to maintain the heat inside the buildings in Winter but in Summer, at nightfall, when the outside temperature becomes lower than the inside temperature, these plates do not allow the buildings to cool down and their use therefore often requires the use of an indoor air conditioning system, this is called phase shift. The negative environmental impact of this type of insulation is therefore twofold: the use of a significant petro-sourced insulation and the need to use an air conditioning system in summer increase the carbon footprint.

Le but de la présente invention est donc de pallier les inconvénients précédemment cités et de proposer un panneau et un procédé de fabrication d’un panneau isolant contenant plus de 50% de matériaux bio-sourcés plus respectueux de l’environnement et ayant un bon déphasage.The object of the present invention is therefore to overcome the drawbacks mentioned above and to propose a panel and a method of manufacturing an insulating panel containing more than 50% of bio-sourced materials that are more respectful of the environment and have a good phase shift. .

On désigne par « déphasage » la capacité d’un matériau composant l'enveloppe d’une habitation à ralentir la pénétration de la chaleur. Le déphasage permet donc de lisser les écarts de températures intérieures dus aux variations de températures extérieures.“Phase shift” refers to the ability of a material making up the envelope of a dwelling to slow down the penetration of heat. The phase shift therefore makes it possible to smooth out the differences in interior temperatures due to variations in exterior temperatures.

Conformément à l’invention, il est donc proposé un panneau isolant à base de matériaux composites, remarquable en ce qu’il comporte au moins:
- une couche comportant un mélange d’au moins un liant et de liège,
- une tôle métallique plane ou profilée.
In accordance with the invention, there is therefore proposed an insulating panel based on composite materials, remarkable in that it comprises at least:
- a layer comprising a mixture of at least one binder and cork,
- a flat or profiled sheet metal.

On appelle « panneau » un assemblage composite formé d’un substrat (ici la tôle) recouvert d’une ou plusieurs couches d’un autre matériau ou mélange de matériaux.A “panel” is a composite assembly made up of a substrate (here sheet metal) covered with one or more layers of another material or mixture of materials.

On appelle « matériau composite » un assemblage d'au moins deux composants (matériaux) non miscibles (mais ayant une forte capacité de pénétration) dont les propriétés se complètent. Le nouveau matériau ainsi constitué, hétérogène, possède des propriétés que les composants seuls ne possèdent pas.A “composite material” is an assembly of at least two components (materials) that are not miscible (but have a high penetration capacity) whose properties complement each other. The new material thus formed, heterogeneous, has properties that the components alone do not have.

On appelle « liège », un matériau présent dans l'écorce de quelques arbres, et notamment dans celle du chêne-liège. Le terme « liège » désigne indifféremment le matériau sous sa forme brute ou prétraitée (les prétraitements sont les traitements effectués au liège brute pour permettre son utilisation dans le domaine de l’isolation par exemple).We call "cork", a material present in the bark of some trees, and in particular in that of the cork oak. The term "cork" refers to the material in its raw or pretreated form (pretreatments are the treatments carried out on raw cork to allow its use in the field of insulation, for example).

On appelle « tôle métallique plane » une feuille métallique laminée. A “flat metal sheet” is a rolled metal sheet .

On appelle « tôle métallique profilée » une feuille métallique fabriquée avec un profil déterminé (par exemple : une tôle métallique nervurée ou ondulée).The term "profiled sheet metal" refers to a sheet metal manufactured with a determined profile (for example: a ribbed or corrugated sheet metal).

On appelle « liant » un produit qui sert à agglomérer en masse solide des particules solides sous forme de poudre ou de granulats (par exemple, une colle).A “binder” is a product that serves to agglomerate solid particles in the form of powder or aggregates (for example, an adhesive) into a solid mass.

Avantageusement, la tôle métallique est une tôle en acier.Advantageously, the metal sheet is a steel sheet.

De manière préférée, le liant est un liant organique.Preferably, the binder is an organic binder.

On appelle liants « organiques », les liants hydrocarbonés à base de carbures d’hydrogène dont le durcissement est réversible et fonction de la température (ex : goudron, bitume) et les liants de type résine ou polymère.The term "organic" binders refers to hydrocarbon binders based on hydrogen carbides whose hardening is reversible and a function of temperature (e.g. tar, bitumen) and binders of the resin or polymer type.

De manière encore plus préférée, le liant est un polymère ou un mélange de polymères.Even more preferably, the binder is a polymer or a mixture of polymers.

Préférentiellement, le liant est un polyuréthane, un polyépoxyde, ou un non-isocyanate polyuréthane (NIPU).Preferably, the binder is a polyurethane, a polyepoxide, or a non-isocyanate polyurethane (NIPU).

Plus préférentiellement, le liant est un polyuréthane.More preferably, the binder is a polyurethane.

Encore plus préférentiellement, le liant est issu d’une réaction de polyaddition d’un polyisocyanate avec un polyol.Even more preferentially, the binder results from a polyaddition reaction of a polyisocyanate with a polyol.

De manière préférée, la couche comporte entre 20 et 80% en masse de liège et respectivement entre 80 et 20 % en masse de polyuréthane.Preferably, the layer comprises between 20 and 80% by mass of cork and respectively between 80 and 20% by mass of polyurethane.

De manière plus préférée, la couche comporte entre 35 et 65% en masse de liège et respectivement entre 65 et 35 % en masse de polyuréthane.More preferably, the layer comprises between 35 and 65% by mass of cork and respectively between 65 and 35% by mass of polyurethane.

De manière encore plus préférée, la couche comporte entre 45 et 55% en masse de liège et respectivement entre 55 et 45 % en masse de polyuréthane.Even more preferably, the layer comprises between 45 and 55% by mass of cork and respectively between 55 and 45% by mass of polyurethane.

Avantageusement, le liant est issu d’une réaction de polyaddition entre un diisocyanate et un polyol.Advantageously, the binder results from a polyaddition reaction between a diisocyanate and a polyol.

On désigne par « diisocyanate », une molécule ayant la structure suivante :The term "diisocyanate" denotes a molecule having the following structure:

avec R contenant des structures aliphatiques linéaires et cycliques et/ou des structures aromatiques (par exemple : MDI, HDI, TDI, HMDI, IPDI, LDI…)with R containing linear and cyclic aliphatic structures and/or aromatic structures (for example: MDI, HDI, TDI, HMDI, IPDI, LDI…)

ou issu de son auto-condensation avec R contenant par exemple des fonctions isocyanurates, biurée allophanates…, une fonctionnalité n=2 ou n >2, et une masse inférieure à 10000g.mol-1 or resulting from its self-condensation with R containing for example isocyanurate functions, allophanate biurea, etc., an n=2 or n >2 functionality, and a mass of less than 10000g.mol -1

ou issu de prépolymérisation d’un polyol en défaut avec un diisocyanate, une fonctionnalité n=2 ou n>2 et une masse inférieure à 10000g.mol-1 or resulting from prepolymerization of a polyol in default with a diisocyanate, an n=2 or n>2 functionality and a mass of less than 10000g.mol -1

Plus avantageusement, le liant est issu de la réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et un polyol.More advantageously, the binder is derived from the polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and a polyol.

De manière plus avantageuse, le liant est issu d’une réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et un diol choisi parmi les diols suivants : éthylène glycol ou 1,4-butanediol ou 1,3-propanediol.More advantageously, the binder results from a polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and a diol chosen from the following diols: ethylene glycol or 1,4-butanediol or 1, 3-propanediol.

De manière encore plus avantageuse, le liant est issu d’une réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et le 1,3-propanediol.Even more advantageously, the binder results from a polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and 1,3-propanediol.

Préférentiellement, le liège est en poudre.Preferably, the cork is in powder form.

On appelle « poudre » de liège, un état dans lequel le liège est sous forme de morceaux de taille inférieure à 100 micromètres.We call "powder" of cork, a state in which the cork is in the form of pieces of size less than 100 micrometers.

L’invention concerne également un procédé de fabrication en continu d’un panneau isolant tel que décrit précédemment, remarquable en ce qu’il comporte au moins les étapes successives suivantes :
-Recouvrement en continu d’une tôle métallique par une couche de mélange liège/liant,
-Passage dans une étuve en continu à une température comprise entre 40 et 150°C.
The invention also relates to a method for the continuous manufacture of an insulating panel as described above, noteworthy in that it comprises at least the following successive steps:
- Continuous covering of a metal sheet with a layer of cork/binder mixture,
- Passing through a continuous oven at a temperature between 40 and 150°C.

On appelle « étuve en continu » une étuve dans laquelle il y a un mécanisme ou une machine qui permet le transport d’une charge de façon continue sur un trajet prédéterminé.A "continuous oven" is an oven in which there is a mechanism or a machine that allows the transport of a load continuously over a predetermined path.

Brève description des figuresBrief description of figures

D’autres avantages et caractéristiques ressortiront mieux de la description qui va suivre d’un mode d’exécution d'un panneau selon l’invention, en référence à la figure annexée sur laquelle :Other advantages and characteristics will emerge better from the following description of an embodiment of a panel according to the invention, with reference to the appended figure in which:

est une vue en coupe transversale d'un panneau conforme à l'invention, is a cross-sectional view of a panel according to the invention,

est une vue en perspective d’un panneau avec un exemple de tôle métallique profilée conforme à l’invention, is a perspective view of a panel with an example of profiled metal sheet according to the invention,

est une vue en coupe transversale d'un panneau un autre exemple de tôle métallique profilée conforme à l’invention, is a cross-sectional view of a panel another example of profiled metal sheet according to the invention,

Claims (16)

Panneau (1) isolant à base de matériaux composites,caractériséen ce qu’il comporte au moins:
- une couche (2) comportant un mélange d’au moins un liant et de liège ,
- une tôle (3) métallique plane ou profilée.
Insulating panel (1) based on composite materials, characterized in that it comprises at least:
- a layer (2) comprising a mixture of at least one binder and cork,
- A flat or profiled metal sheet (3).
Panneau (1) selon la revendication 1,caractériséen ce que la tôle (3) métallique est une tôle en acier.Panel (1) according to Claim 1, characterized in that the metal sheet (3) is a steel sheet. Panneau (1) selon l’une quelconque des revendications précédentes,caractériséen ce que le liant est un liant organique.Panel (1) according to any one of the preceding claims, characterized in that the binder is an organic binder. Panneau (1) selon l’une quelconque des revendications précédentes,caractériséen ce que le liant est un polymère ou un mélange de polymères.Panel (1) according to any one of the preceding claims, characterized in that the binder is a polymer or a mixture of polymers. Panneau (1) selon l’une quelconque des revendications précédentes,caractériséen ce que le liant est un polyuréthane, un polyépoxyde ou un non-isocyanate polyuréthane (NIPU).Panel (1) according to any one of the preceding claims, characterized in that the binder is a polyurethane, a polyepoxide or a non-isocyanate polyurethane (NIPU). Panneau (1) selon l’une quelconque des revendications précédentes,caractériséen ce que le liant est un polyuréthane.Panel (1) according to any one of the preceding claims, characterized in that the binder is a polyurethane. Panneau (1) selon la revendication 6,caractériséen ce que le liant est issu d’une réaction de polyaddition d’un polyisocyanate avec un polyol.Panel (1) according to Claim 6, characterized in that the binder results from a polyaddition reaction of a polyisocyanate with a polyol. Panneau (1) selon la revendication 6,caractériséen ce que la couche (2) comporte entre 20 et 80 % en masse de liège et respectivement entre 80 et 20% en masse de polyuréthane.Panel (1) according to Claim 6, characterized in that the layer (2) comprises between 20 and 80% by mass of cork and respectively between 80 and 20% by mass of polyurethane. Panneau (1) selon la revendication 6,caractériséen ce que la couche (2) comporte entre 35 et 65% en masse de liège et respectivement entre 65 et 35% en masse de polyuréthane.Panel (1) according to Claim 6, characterized in that the layer (2) comprises between 35 and 65% by mass of cork and respectively between 65 and 35% by mass of polyurethane. Panneau (1) selon la revendication 6,caractériséen ce que la couche (2) comporte entre 45 et 55% en masse de liège et respectivement entre 55 et 45% en masse de polyuréthane.Panel (1) according to Claim 6, characterized in that the layer (2) comprises between 45 and 55% by mass of cork and respectively between 55 and 45% by mass of polyurethane. Panneau (1) selon la revendication 6,caractériséen ce que le liant est issu d’une réaction de polyaddition entre un diisocyanate et un polyol.Panel (1) according to Claim 6, characterized in that the binder results from a polyaddition reaction between a diisocyanate and a polyol. Panneau (1) selon la revendication 6,caractériséen ce que le liant est issu de la réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et un polyol.Panel (1) according to Claim 6, characterized in that the binder results from the polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and a polyol. Panneau (1) selon la revendication 11,caractériséen ce que le liant est issu de la réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et un diol choisi parmi les diols suivants : éthylène glycol ou 1,4-butanediol ou 1,3-propanediol.Panel (1) according to Claim 11, characterized in that the binder results from the polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and a diol chosen from the following diols: ethylene glycol or 1 ,4-butanediol or 1,3-propanediol. Panneau (1) selon la revendication 12,caractériséen ce que le liant est issu de la réaction de polyaddition entre un diisocyanate à base de 1,6-diisocyanatohexane contenant des fonctions allophanates et le 1,3-propanediol.Panel (1) according to Claim 12, characterized in that the binder results from the polyaddition reaction between a diisocyanate based on 1,6-diisocyanatohexane containing allophanate functions and 1,3-propanediol. Panneau (1) selon l’une quelconque des revendications précédentes,caractériséen ce que le liège est pris en poudre.Panel (1) according to any one of the preceding claims, characterized in that the cork is powdered. Procédé de fabrication en continu d’un panneau (1) isolant selon les revendications 1 à 9,caractériséen ce qu’il comporte au moins les étapes successives suivantes :
-Recouvrement en continu d’une tôle (3) métallique par une couche (2) de mélange liège/liant,
-Passage dans une étuve en continu à une température comprise entre 40 et 150°C.
Process for the continuous manufacture of an insulating panel (1) according to claims 1 to 9, characterized in that it comprises at least the following successive steps:
- Continuous covering of a metal sheet (3) with a layer (2) of cork/binder mixture,
- Passing through a continuous oven at a temperature between 40 and 150°C.
FR2111277A 2021-10-22 2021-10-22 Insulating panel made of composite materials and its method of manufacture Pending FR3128475A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2111277A FR3128475A1 (en) 2021-10-22 2021-10-22 Insulating panel made of composite materials and its method of manufacture
PCT/EP2022/079176 WO2023067045A1 (en) 2021-10-22 2022-10-20 Insulating panel made of composite materials and method for producing same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2111277 2021-10-22
FR2111277A FR3128475A1 (en) 2021-10-22 2021-10-22 Insulating panel made of composite materials and its method of manufacture

Publications (1)

Publication Number Publication Date
FR3128475A1 true FR3128475A1 (en) 2023-04-28

Family

ID=80122942

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2111277A Pending FR3128475A1 (en) 2021-10-22 2021-10-22 Insulating panel made of composite materials and its method of manufacture

Country Status (2)

Country Link
FR (1) FR3128475A1 (en)
WO (1) WO2023067045A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130011623A1 (en) * 2011-07-08 2013-01-10 Nicolon Corporation d/b/a TenCate Geosynthetics North America Monolithic three-dimensional composite and method of making same
US20170226749A1 (en) * 2016-02-09 2017-08-10 Knoll, Inc. Cork-based tile for privacy apparatuses and method of making and using the same
WO2018117268A1 (en) * 2016-12-22 2018-06-28 凸版印刷株式会社 Multilayer stretched film, substrate for decorative sheets, decorative sheet and decorative panel

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5841908B2 (en) * 1972-01-13 1983-09-16 ボンタイル カブシキガイシヤ Keishiyousou no Keiseihouhou
US4347272A (en) * 1980-07-11 1982-08-31 Schmidt Donald H Flexible composition of cork and sheet structures made therefrom

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130011623A1 (en) * 2011-07-08 2013-01-10 Nicolon Corporation d/b/a TenCate Geosynthetics North America Monolithic three-dimensional composite and method of making same
US20170226749A1 (en) * 2016-02-09 2017-08-10 Knoll, Inc. Cork-based tile for privacy apparatuses and method of making and using the same
WO2018117268A1 (en) * 2016-12-22 2018-06-28 凸版印刷株式会社 Multilayer stretched film, substrate for decorative sheets, decorative sheet and decorative panel

Also Published As

Publication number Publication date
WO2023067045A1 (en) 2023-04-27

Similar Documents

Publication Publication Date Title
KR102578732B1 (en) Infrared-cured latent two-component polyurethane adhesive
Yarahmadi et al. Accelerated ageing and degradation characteristics of rigid polyurethane foam
US8604093B2 (en) Fire-resistant polyurethane foam and fabrication method thereof
US20150367603A1 (en) Panel with fire barrier
CN111925495A (en) Preparation method of self-repairing polyurethane and polyurea hybridized and crosslinked by metal coordination bond and hydrogen bond
KR101298027B1 (en) Polturethane primer composition for waterproof and floor construction
EP0026123B1 (en) Use of a plastic adhesive layer as an insert layer in laminated glass and the laminated glasses
KR102550908B1 (en) Anode for Electrochemical Cell
EP1648975A2 (en) Material having sound-damping and adhesive properties
FR3128475A1 (en) Insulating panel made of composite materials and its method of manufacture
US10333014B2 (en) Method and substrates for making photovoltaic cells
CN1961175A (en) Vacuum heat insulation material and cold reserving apparatus with the same
KR20200047476A (en) Resin Composition
CN114940885A (en) Heat-conducting bi-component polyurethane adhesive and preparation method and application thereof
JP5294137B2 (en) Method for producing rigid polyurethane foam
EP0189720A1 (en) Thermally insulating material of the syntactical type, particularly elastomeric material, partly or completely fireproof
KR20200012437A (en) Resin Composition
KR101864940B1 (en) Thermal insulation foams for high explosive
Lee et al. Inhibition of Si fracture via rigid solid electrolyte interphase in lithium‐ion batteries
EP1283310A1 (en) Isothermal and fire-proof panel
KR101915850B1 (en) Compositions for rocket motor of hydroxyl-terminated polybutadiene chamber insulation and manufacturing method theof, rocket motor including hydroxyl-terminated polybutadiene chamber insulation
CN105601965A (en) Preparation method of polyurethane-polyisocyanurate thin-film graded material
CN104854208B (en) Solid can self-adhesion organic polymer and its application method
JP3232111U (en) Cover structure
EP0094299A1 (en) Composite material of self supporting sandwich panel type

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

EXTE Extension to a french territory

Extension state: PF

PLSC Publication of the preliminary search report

Effective date: 20230428

PLFP Fee payment

Year of fee payment: 3