FR3117857B1 - Biosourced alkyd polymers – polyurethane in cosmetics - Google Patents

Biosourced alkyd polymers – polyurethane in cosmetics Download PDF

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Publication number
FR3117857B1
FR3117857B1 FR2013779A FR2013779A FR3117857B1 FR 3117857 B1 FR3117857 B1 FR 3117857B1 FR 2013779 A FR2013779 A FR 2013779A FR 2013779 A FR2013779 A FR 2013779A FR 3117857 B1 FR3117857 B1 FR 3117857B1
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France
Prior art keywords
alkyd
polyurethane
biosourced
cosmetics
cosmetic composition
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FR2013779A
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French (fr)
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FR3117857A1 (en
Inventor
Aude Benard
Pascal Giustiniani
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LOreal SA
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LOreal SA
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/281Monocarboxylic acid compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C08G18/4233Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups derived from polymerised higher fatty acids or alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6625Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/34
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L’invention concerne l’utilisation, dans une composition notamment cosmétique, d’au moins un polymère polyuréthane à base d’alkyde, en particulier à l’état de dispersion aqueuse, obtenu à partir :(a) d’au moins un alkyde formé à partir (a1) d’au moins un polyol ; (a2) d’au moins un acide polycarboxylique ; et (a3) d’au moins un acide monocarboxylique, de préférence l’acide abiétique ou la colophane ; et(b) d’au moins un polyisocyanate, de préférence diisocyanate, en particulier aliphatique ou cycloaliphatique ; et (c) éventuellement, d’au moins un monomère hydrophile, en particulier dans le cas de la mise en œuvre dudit alkyde-polyuréthane à l’état de dispersion ;pour le traitement des matières kératiniques, notamment humaines telles que la peau, ou des fibres kératiniques humaines, notamment les cils. Elle concerne encore un tel alkyde-polyuréthane dans lequel le taux en acide(s) monocarboxylique(s) (a3) est inférieur ou égal à 35 % massique, du poids total de l’alkyde-polyuréthane ; son procédé de préparation, ainsi qu’une composition cosmétique comprenant un tel alkyde-polyuréthane.The invention relates to the use, in particular a cosmetic composition, of at least one alkyd-based polyurethane polymer, in particular in the state of aqueous dispersion, obtained from: (a) at least one alkyd formed from (a1) at least one polyol; (a2) at least one polycarboxylic acid; and (a3) at least one monocarboxylic acid, preferably abietic acid or rosin; and(b) at least one polyisocyanate, preferably diisocyanate, in particular aliphatic or cycloaliphatic; and (c) optionally, at least one hydrophilic monomer, in particular in the case of the use of said alkyd-polyurethane in the dispersion state; for the treatment of keratin materials, in particular human materials such as skin, or human keratin fibers, notably eyelashes. It also concerns such an alkyd-polyurethane in which the level of monocarboxylic acid(s) (a3) is less than or equal to 35% by weight of the total weight of the alkyd-polyurethane; its preparation process, as well as a cosmetic composition comprising such an alkyd-polyurethane.

FR2013779A 2020-12-21 2020-12-21 Biosourced alkyd polymers – polyurethane in cosmetics Active FR3117857B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR2013779A FR3117857B1 (en) 2020-12-21 2020-12-21 Biosourced alkyd polymers – polyurethane in cosmetics

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2013779 2020-12-21
FR2013779A FR3117857B1 (en) 2020-12-21 2020-12-21 Biosourced alkyd polymers – polyurethane in cosmetics

Publications (2)

Publication Number Publication Date
FR3117857A1 FR3117857A1 (en) 2022-06-24
FR3117857B1 true FR3117857B1 (en) 2023-12-01

Family

ID=74871580

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2013779A Active FR3117857B1 (en) 2020-12-21 2020-12-21 Biosourced alkyd polymers – polyurethane in cosmetics

Country Status (1)

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FR (1) FR3117857B1 (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1222426A (en) * 1968-03-08 1971-02-10 Bibby Chemicals Ltd Improvements in or relating to the production of polyurethane foam materials
DE19534361A1 (en) * 1995-09-15 1997-03-20 Basf Lacke & Farben Aqueous binder dispersion for the production of low-yellowing high-gloss coatings
FR2902653B1 (en) * 2006-06-22 2008-09-12 Oreal COSMETIC OR PHARMACEUTICAL COMPOSITION COMPRISING A POLYCONDENSATE, COSMETIC PROCESSING METHOD EMPLOYING SAID COMPOSITION, POLYCONDENSATE AND PREPARATION METHOD
FR2988723B1 (en) * 2012-03-30 2014-04-25 Arkema France AQUEOUS DISPERSIONS OF POLYURETHANE RESINS BASED ON COLOPHANE

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Publication number Publication date
FR3117857A1 (en) 2022-06-24

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