FR3090213B1 - Lithium iron hydroxysulphide negative electrode active material - Google Patents

Lithium iron hydroxysulphide negative electrode active material Download PDF

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Publication number
FR3090213B1
FR3090213B1 FR1873243A FR1873243A FR3090213B1 FR 3090213 B1 FR3090213 B1 FR 3090213B1 FR 1873243 A FR1873243 A FR 1873243A FR 1873243 A FR1873243 A FR 1873243A FR 3090213 B1 FR3090213 B1 FR 3090213B1
Authority
FR
France
Prior art keywords
negative electrode
active material
hydroxysulphide
electrode active
lithium iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1873243A
Other languages
French (fr)
Other versions
FR3090213A1 (en
Inventor
Philippe Barboux
Mohamed Chakir
Domitille Giaume
Caroline Mir
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Renault SAS
Ecole Nationale Superieure de Chimie de Paris ENSCP
Original Assignee
Centre National de la Recherche Scientifique CNRS
Renault SAS
Ecole Nationale Superieure de Chimie de Paris ENSCP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1873243A priority Critical patent/FR3090213B1/en
Application filed by Centre National de la Recherche Scientifique CNRS, Renault SAS, Ecole Nationale Superieure de Chimie de Paris ENSCP filed Critical Centre National de la Recherche Scientifique CNRS
Priority to KR1020217018998A priority patent/KR20210133208A/en
Priority to EP19842781.7A priority patent/EP3898522B1/en
Priority to US17/415,363 priority patent/US12095086B2/en
Priority to CN201980083700.2A priority patent/CN113423665A/en
Priority to JP2021535114A priority patent/JP7527293B2/en
Priority to PCT/EP2019/085857 priority patent/WO2020127427A1/en
Publication of FR3090213A1 publication Critical patent/FR3090213A1/en
Application granted granted Critical
Publication of FR3090213B1 publication Critical patent/FR3090213B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L’invention a pour objet un matériau actif d’électrode négative pour batterie lithium-ion de formule (I) suivante :Li1-xOHFe1+xS (I),dans laquelle x varie de 0,00 à 0,25, de préférence de 0,05 à 0,20.The subject of the invention is an active material for a negative electrode for a lithium-ion battery of the following formula (I): Li1-xOHFe1 + xS (I), in which x varies from 0.00 to 0.25, preferably from 0.05 to 0.20.

FR1873243A 2018-12-18 2018-12-18 Lithium iron hydroxysulphide negative electrode active material Expired - Fee Related FR3090213B1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1873243A FR3090213B1 (en) 2018-12-18 2018-12-18 Lithium iron hydroxysulphide negative electrode active material
EP19842781.7A EP3898522B1 (en) 2018-12-18 2019-12-18 Negative electrode active material based on iron and lithium hydroxysulfide
US17/415,363 US12095086B2 (en) 2018-12-18 2019-12-18 Negative electrode active material based on iron and lithium hydroxysulfide
CN201980083700.2A CN113423665A (en) 2018-12-18 2019-12-18 Negative electrode active material based on lithium iron hydroxysulfide
KR1020217018998A KR20210133208A (en) 2018-12-18 2019-12-18 Anode active material based on iron and lithium hydroxysulfide
JP2021535114A JP7527293B2 (en) 2018-12-18 2019-12-18 Anode active materials based on iron and lithium hydroxysulfide
PCT/EP2019/085857 WO2020127427A1 (en) 2018-12-18 2019-12-18 Negative electrode active material based on iron and lithium hydroxysulfide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1873243A FR3090213B1 (en) 2018-12-18 2018-12-18 Lithium iron hydroxysulphide negative electrode active material

Publications (2)

Publication Number Publication Date
FR3090213A1 FR3090213A1 (en) 2020-06-19
FR3090213B1 true FR3090213B1 (en) 2020-11-20

Family

ID=66676693

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1873243A Expired - Fee Related FR3090213B1 (en) 2018-12-18 2018-12-18 Lithium iron hydroxysulphide negative electrode active material

Country Status (7)

Country Link
US (1) US12095086B2 (en)
EP (1) EP3898522B1 (en)
JP (1) JP7527293B2 (en)
KR (1) KR20210133208A (en)
CN (1) CN113423665A (en)
FR (1) FR3090213B1 (en)
WO (1) WO2020127427A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3127636B1 (en) * 2021-09-30 2024-03-08 Renault Sas Sodium iron hydroxysulfide compound, process for preparing such a compound, active material comprising such a compound and electrochemical electrode made from such an active material.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100449073B1 (en) 2002-10-15 2004-09-18 한국전자통신연구원 Cathode material for lithium secondary batteries and method for manufacturing the Same
EP2772971B1 (en) 2011-10-25 2018-05-02 Toyota Jidosha Kabushiki Kaisha Metal ion battery
JP2014017157A (en) * 2012-07-10 2014-01-30 Toyota Motor Corp Positive electrode active material for lithium secondary battery, method for producing positive electrode active material for lithium secondary battery, and lithium secondary battery

Also Published As

Publication number Publication date
US20220069306A1 (en) 2022-03-03
US12095086B2 (en) 2024-09-17
KR20210133208A (en) 2021-11-05
CN113423665A (en) 2021-09-21
EP3898522A1 (en) 2021-10-27
JP2022514028A (en) 2022-02-09
EP3898522B1 (en) 2023-01-04
FR3090213A1 (en) 2020-06-19
WO2020127427A1 (en) 2020-06-25
JP7527293B2 (en) 2024-08-02

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