FR3083715B1 - ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE - Google Patents

ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE Download PDF

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Publication number
FR3083715B1
FR3083715B1 FR1856528A FR1856528A FR3083715B1 FR 3083715 B1 FR3083715 B1 FR 3083715B1 FR 1856528 A FR1856528 A FR 1856528A FR 1856528 A FR1856528 A FR 1856528A FR 3083715 B1 FR3083715 B1 FR 3083715B1
Authority
FR
France
Prior art keywords
iodine
gaseous state
adsorbent material
iodide salt
material loaded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1856528A
Other languages
French (fr)
Other versions
FR3083715A1 (en
Inventor
Gregoire Auge
Jean Daou
Joffrey Huve
Habiba Nouali
Andrey Ryzhikov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Haute Alsace
Onet Technologies CN SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Haute Alsace
Onet Technologies CN SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Haute Alsace, Onet Technologies CN SAS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1856528A priority Critical patent/FR3083715B1/en
Priority to EP19753142.9A priority patent/EP3820606A1/en
Priority to PCT/FR2019/051701 priority patent/WO2020012109A1/en
Publication of FR3083715A1 publication Critical patent/FR3083715A1/en
Application granted granted Critical
Publication of FR3083715B1 publication Critical patent/FR3083715B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/02—Treating gases
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G21F9/301—Processing by fixation in stable solid media
    • G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/34—Specific shapes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/202—Single element halogens
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/206—Organic halogen compounds
    • B01D2257/2068—Iodine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/45—Gas separation or purification devices adapted for specific applications
    • B01D2259/4583—Gas separation or purification devices adapted for specific applications for removing chemical, biological and nuclear warfare agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D59/00—Separation of different isotopes of the same chemical element
    • B01D59/22—Separation by extracting
    • B01D59/26—Separation by extracting by sorption, i.e. absorption, adsorption, persorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
FR1856528A 2018-07-13 2018-07-13 ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE Active FR3083715B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR1856528A FR3083715B1 (en) 2018-07-13 2018-07-13 ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE
EP19753142.9A EP3820606A1 (en) 2018-07-13 2019-07-09 Adsorbent material loaded with iodide salt useful for trapping radioactive iodine from iodine compounds in gaseous state by isotopic substitution of iodine
PCT/FR2019/051701 WO2020012109A1 (en) 2018-07-13 2019-07-09 Adsorbent material loaded with iodide salt useful for trapping radioactive iodine from iodine compounds in gaseous state by isotopic substitution of iodine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1856528A FR3083715B1 (en) 2018-07-13 2018-07-13 ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE

Publications (2)

Publication Number Publication Date
FR3083715A1 FR3083715A1 (en) 2020-01-17
FR3083715B1 true FR3083715B1 (en) 2022-09-09

Family

ID=63963163

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1856528A Active FR3083715B1 (en) 2018-07-13 2018-07-13 ADSORBENT MATERIAL LOADED WITH IODIDE SALT USEFUL FOR TRAPPING RADIOACTIVE IODINE FROM IODINE COMPOUNDS IN THE GASEOUS STATE BY ISOTOPIC SUBSTITUTION OF IODINE

Country Status (3)

Country Link
EP (1) EP3820606A1 (en)
FR (1) FR3083715B1 (en)
WO (1) WO2020012109A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995019A (en) * 2020-08-24 2020-11-27 国投信开水环境投资有限公司 Slow-release regulating composite phosphorus removing agent and preparation method thereof
CN112023874A (en) * 2020-09-18 2020-12-04 上海复旭分子筛有限公司 Zeolite molecular sieve adsorbent for deeply removing iodide in gas-phase medium and preparation method and application thereof
CN113019473A (en) * 2021-03-06 2021-06-25 凯瑞环保科技股份有限公司 Preparation method of anion exchange resin
CN114713207B (en) * 2022-04-07 2024-03-15 江苏索普聚酯科技有限公司 Functional adsorption material for recycling iodine and rhodium elements in organic acetic acid and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1124116A (en) * 1965-07-28 1968-08-21 Atomic Energy Authority Uk Improvements in or relating to charcoal for use in trapping systems
US5075084A (en) * 1989-01-21 1991-12-24 Bayer Aktiengesellschaft Process for the removal of iodine and iodine compounds from hydrogen-containing gases and vapors
US7737319B2 (en) * 2005-04-29 2010-06-15 Llyon Technologies, Llc Treating radioactive materials
JP5781279B2 (en) * 2010-06-15 2015-09-16 三菱重工業株式会社 Radioactive iodine adsorbent and radioactive iodine removal device
JP6581945B2 (en) * 2016-06-01 2019-09-25 三菱重工業株式会社 Radioactive iodine adsorbent and radioactive iodine removal device

Also Published As

Publication number Publication date
EP3820606A1 (en) 2021-05-19
FR3083715A1 (en) 2020-01-17
WO2020012109A1 (en) 2020-01-16

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