FR3082517B1 - STABILIZATION OF 1,1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE - Google Patents
STABILIZATION OF 1,1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE Download PDFInfo
- Publication number
- FR3082517B1 FR3082517B1 FR1855324A FR1855324A FR3082517B1 FR 3082517 B1 FR3082517 B1 FR 3082517B1 FR 1855324 A FR1855324 A FR 1855324A FR 1855324 A FR1855324 A FR 1855324A FR 3082517 B1 FR3082517 B1 FR 3082517B1
- Authority
- FR
- France
- Prior art keywords
- hexafluorobut
- ene
- stabilization
- cis
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NLOLSXYRJFEOTA-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)C=CC(F)(F)F NLOLSXYRJFEOTA-UHFFFAOYSA-N 0.000 title abstract 2
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- -1 alkene compound Chemical class 0.000 abstract 2
- NLOLSXYRJFEOTA-OWOJBTEDSA-N (e)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C\C(F)(F)F NLOLSXYRJFEOTA-OWOJBTEDSA-N 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne l'utilisation d'un composé alcène en C3 à C6 et comportant une seule double liaison, pour limiter ou empêcher l'isomérisation du cis-1,1,1,4,4,4-hexafluorobut-2-ène en trans-1,1,1,4,4,4-hexafluorobut-2-ène , ou pour limiter ou empêcher la dégradation du cis-1,1,1,4,4,4-hexafluorobut -2-ène. L'invention concerne également une composition comprenant au moins 50 % en poids de 1,1,1,4,4,4-hexafluorobut-2-ène et un composé alcène en C3 à C6 et comportant une seule double liaison ; ainsi que diverses utilisations de cette composition.The invention relates to the use of a C3-C6 alkene compound having a single double bond, for limiting or preventing the isomerization of cis-1,1,1,4,4,4-hexafluorobut-2-ene into trans-1,1,1,4,4,4-hexafluorobut-2-ene, or to limit or prevent the degradation of cis-1,1,1,4,4,4-hexafluorobut -2-ene. The invention also relates to a composition comprising at least 50% by weight of 1,1,1,4,4,4-hexafluorobut-2-ene and a C3-C6 alkene compound and comprising a single double bond; as well as various uses of this composition.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1855324A FR3082517B1 (en) | 2018-06-18 | 2018-06-18 | STABILIZATION OF 1,1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE |
PCT/FR2019/051379 WO2019243704A1 (en) | 2018-06-18 | 2019-06-07 | Stabilisation of 1,1,1,4,4,4-hexafluorobut-2-ene |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1855324 | 2018-06-18 | ||
FR1855324A FR3082517B1 (en) | 2018-06-18 | 2018-06-18 | STABILIZATION OF 1,1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3082517A1 FR3082517A1 (en) | 2019-12-20 |
FR3082517B1 true FR3082517B1 (en) | 2021-01-15 |
Family
ID=63834132
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1855324A Active FR3082517B1 (en) | 2018-06-18 | 2018-06-18 | STABILIZATION OF 1,1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR3082517B1 (en) |
WO (1) | WO2019243704A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3131584A1 (en) * | 2021-12-31 | 2023-07-07 | Arkema France | Stabilized composition of (hydro)halogenated olefin |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009003165A1 (en) | 2007-06-27 | 2008-12-31 | Arkema Inc. | Stabilized hydrochlorofluoroolefins and hydrofluoroolefins |
MX345543B (en) * | 2009-06-02 | 2017-02-03 | Du Pont | Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene. |
FR3033791B1 (en) * | 2015-03-18 | 2017-04-14 | Arkema France | STABILIZATION OF 1-CHLORO-3,3,3-TRIFLUOROPROPENE |
-
2018
- 2018-06-18 FR FR1855324A patent/FR3082517B1/en active Active
-
2019
- 2019-06-07 WO PCT/FR2019/051379 patent/WO2019243704A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
FR3082517A1 (en) | 2019-12-20 |
WO2019243704A1 (en) | 2019-12-26 |
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