FR3074968B1 - Electrode a air reversible a base d'un oxyde de graphene - Google Patents

Electrode a air reversible a base d'un oxyde de graphene Download PDF

Info

Publication number
FR3074968B1
FR3074968B1 FR1761794A FR1761794A FR3074968B1 FR 3074968 B1 FR3074968 B1 FR 3074968B1 FR 1761794 A FR1761794 A FR 1761794A FR 1761794 A FR1761794 A FR 1761794A FR 3074968 B1 FR3074968 B1 FR 3074968B1
Authority
FR
France
Prior art keywords
graphene oxide
nitrogen
air electrode
sulfur
organic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1761794A
Other languages
English (en)
Other versions
FR3074968A1 (fr
Inventor
Philippe Stevens
Gwenaelle Toussaint
Aurelien Louis Habrioux
Clement Aime Comminges
Boniface Kokoh
Ismail Abidat
Teko Wilhelmin Napporn
David Portehault
Emmanuelle Cazayus-Claverie
Olivier Durupthy
Corinne Chaneac
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Electricite de France SA
Centre National de la Recherche Scientifique CNRS
Original Assignee
Electricite de France SA
Centre National de la Recherche Scientifique CNRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Electricite de France SA, Centre National de la Recherche Scientifique CNRS filed Critical Electricite de France SA
Priority to FR1761794A priority Critical patent/FR3074968B1/fr
Priority to EP18826431.1A priority patent/EP3721497A1/fr
Priority to US16/769,344 priority patent/US11489159B2/en
Priority to CN201880086568.6A priority patent/CN111602276A/zh
Priority to PCT/FR2018/053125 priority patent/WO2019110933A1/fr
Publication of FR3074968A1 publication Critical patent/FR3074968A1/fr
Application granted granted Critical
Publication of FR3074968B1 publication Critical patent/FR3074968B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inert Electrodes (AREA)
  • Hybrid Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Il est proposé un procédé de fabrication d'un composé (30) à base d'oxyde de graphène pour électrode à air d'une batterie métal-air. Un composé organique (2) à base d'azote et de soufre est ajouté à une suspension aqueuse (1) d'un oxyde de graphène. L'eau de la suspension est évaporée pour obtenir une poudre (5). Cette poudre est chauffée sous atmosphère inerte pour sublimer le composé organique et stimuler l'incorporation d'azote (21) issu du composé organique dans des sites graphitiques de l'oxyde de graphène. L'oxyde de graphène dopé azote et soufre (20) est ajoutée dans une deuxième suspension aqueuse (3) comprenant un composé à base de nitrate de cobalt (4). Cette deuxième suspension est chauffée pour former des nanoparticules (41) d'oxyde de cobalt à la surface d'au moins un feuillet d'oxyde de graphène dopé azote et soufre.
FR1761794A 2017-12-07 2017-12-07 Electrode a air reversible a base d'un oxyde de graphene Active FR3074968B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1761794A FR3074968B1 (fr) 2017-12-07 2017-12-07 Electrode a air reversible a base d'un oxyde de graphene
EP18826431.1A EP3721497A1 (fr) 2017-12-07 2018-12-05 Procédé de fabrication d'un composé à base d'oxyde de graphène pour électrode à air d'une batterie métal-air et composé associé
US16/769,344 US11489159B2 (en) 2017-12-07 2018-12-05 Method for producing a graphene oxide-based compound for an air electrode of a metal-air battery and associated compound
CN201880086568.6A CN111602276A (zh) 2017-12-07 2018-12-05 制造用于金属-空气电池的空气电极的基于氧化石墨烯的化合物的方法和相关化合物
PCT/FR2018/053125 WO2019110933A1 (fr) 2017-12-07 2018-12-05 Procédé de fabrication d'un composé à base d'oxyde de graphène pour électrode à air d'une batterie métal-air et composé associé

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1761794 2017-12-07
FR1761794A FR3074968B1 (fr) 2017-12-07 2017-12-07 Electrode a air reversible a base d'un oxyde de graphene

Publications (2)

Publication Number Publication Date
FR3074968A1 FR3074968A1 (fr) 2019-06-14
FR3074968B1 true FR3074968B1 (fr) 2021-09-17

Family

ID=61873422

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1761794A Active FR3074968B1 (fr) 2017-12-07 2017-12-07 Electrode a air reversible a base d'un oxyde de graphene

Country Status (5)

Country Link
US (1) US11489159B2 (fr)
EP (1) EP3721497A1 (fr)
CN (1) CN111602276A (fr)
FR (1) FR3074968B1 (fr)
WO (1) WO2019110933A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110492108B (zh) * 2019-07-30 2022-09-02 武汉理工大学 氮硫共掺杂石墨烯基负载核壳纳米粒子复合材料及其制备方法和应用
FR3104828B1 (fr) 2019-12-13 2022-11-11 Electricite De France Procédé de fabrication d’une électrode à gaz présentant un gradient de composition
CN111359064B (zh) * 2020-04-01 2024-11-22 玻尔量子(厦门)科技有限公司 一种医用氢氧气雾化机
CN114583127B (zh) * 2022-02-28 2023-05-09 南京工业大学 一种制备CoNi-S@3D-C纳米复合材料和改性电池隔膜的方法
CN114515552B (zh) * 2022-03-11 2023-03-07 山东大学 一种NiCo合金@氮掺杂石墨烯多级孔气凝胶及其制备方法与在锌-空气电池中的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2687483A1 (fr) * 2012-07-16 2014-01-22 Basf Se Graphène contenant de l'azote et éventuellement du fer et/ou du cobalt
US20180093893A1 (en) * 2015-04-02 2018-04-05 Case Western Reserve University Metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
WO2017123289A2 (fr) * 2015-10-06 2017-07-20 Board Of Regents, The University Of Texas System Piles à combustible liquide direct sans membrane
CN105268440A (zh) * 2015-11-06 2016-01-27 河南理工大学 一种石墨烯负载氧化钴催化剂及其制备方法
CN105417532A (zh) * 2015-12-22 2016-03-23 北京理工大学 一步法制备高氮掺杂石墨烯
KR101854514B1 (ko) * 2016-02-12 2018-05-04 영남대학교 산학협력단 3차원 니켈폼 상의 다층 메조기공 구조의 그래핀/니켈-코발트-황화물 배열 복합체 및 이의 제조방법
CN106684389A (zh) * 2016-12-30 2017-05-17 温州大学 硫氮双掺杂石墨烯纳米材料及其制备方法与应用

Also Published As

Publication number Publication date
WO2019110933A1 (fr) 2019-06-13
US20200313185A1 (en) 2020-10-01
EP3721497A1 (fr) 2020-10-14
FR3074968A1 (fr) 2019-06-14
CN111602276A (zh) 2020-08-28
US11489159B2 (en) 2022-11-01

Similar Documents

Publication Publication Date Title
FR3074968B1 (fr) Electrode a air reversible a base d'un oxyde de graphene
He et al. A general synthesis strategy for monodisperse metallic and metalloid nanoparticles (In, Ga, Bi, Sb, Zn, Cu, Sn, and their alloys) via in situ formed metal long-chain amides
Zhang et al. Electrochemical route to the preparation of highly dispersed composites of ZnO/carbon nanotubes with significantly enhanced electrochemiluminescence from ZnO
Anderson et al. Nanoparticle conversion chemistry: Kirkendall effect, galvanic exchange, and anion exchange
Cui et al. Synthesis and functions of Ag2S nanostructures
Kumar et al. Au–ZnO bullet-like heterodimer nanoparticles: synthesis and use for enhanced nonenzymatic electrochemical determination of glucose
Mariotti et al. Tailoring microplasma nanofabrication: from nanostructures to nanoarchitectures
Xing et al. Ultrathin single-crystal ZnO nanobelts: Ag-catalyzed growth and field emission property
Qu et al. Programmed synthesis of Sn3N4 nanoparticles via a soft chemistry approach with urea: application for ethanol vapor sensing
Zhao et al. Preparation and characterization of netted sphere-like CdS nanostructures
Wu et al. In situ synthesis of large-area single sub-10 nm nanoparticle arrays by polymer pen lithography
CN104743529B (zh) 一种高催化性能氮化钨的合成方法
Zhang et al. Preparation and characterization of copper azide nanowire array
Yoon et al. One pot synthesis of octahedral {111} CuIr gradient alloy nanocrystals with a Cu-rich core and an Ir-rich surface and their usage as efficient water splitting catalyst
Abd-Elrahim et al. Room-temperature fabrication of a heterostructure Cu2O@ CuO nanosheet electrocatalyst for non-enzymatic detection of glucose and H2O2
Sannegowda et al. Stable nano-sized copper and its oxide particles using cobalt tetraamino phthalocyanine as a stabilizer; application to electrochemical activity
Gopalan et al. Gold nanoparticles dispersed into poly (aminothiophenol) as a novel electrocatalyst—Fabrication of modified electrode and evaluation of electrocatalytic activities for dioxygen reduction
Jia et al. Robust anion exchange realized in crystalline metal cyanamide nanoparticles
Lu et al. The assembly of semiconductor sulfide nanocrystallites with organic reagents as templates
Yang et al. Fabrication of nano-network gold films via anodization of gold electrode and their application in SERS
Raj et al. Fabrication of Au@ SiO2 core–shell nanoparticles on conducting glass substrate by pulse electrophoresis deposition
Maraldi et al. Prussian Blue nanoparticles supported on a hybrid platform of graphene oxide and cubic silsesquioxane applied to Diuron detection
Li et al. Selectively self-assembling graphene nanoribbons with shaped iron oxide nanoparticles
Liu et al. Synthesis of one-dimensional ZnO nanoneedles using thermal oxidation process in the air and its application as filed emitters
CN100500949C (zh) 一种纳米氧化锌晶面可控生长的方法

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20190614

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5

PLFP Fee payment

Year of fee payment: 6

PLFP Fee payment

Year of fee payment: 7

PLFP Fee payment

Year of fee payment: 8

PLFP Fee payment

Year of fee payment: 9