FR3063225A1 - AQUEOUS FOAMING GEL COMPRISING AN ALKYL SULFATE DERIVATIVE, AN ALKYL POLYGLUCOSIDE, A POLYOL AND AN ORGANIC ACID - Google Patents

Abstract

The present invention relates to a foaming cleaning composition in the form of an aqueous gel comprising at least one alkyl sulphate derivative, at least one alkyl polyglucoside, optionally at least one alkyl betaine derivative, at least one polyol and at least one an organic acid, the weight ratio derived from alkyl sulfate / alkyl polyglucosides being between 0.5 and 2.5, preferably between 0.8 and 1.3, and even more preferably between 0.9 and 1.2. The composition according to the invention is a foaming and transparent cleaning composition, stable, having excellent cosmetics with in particular an optimized viscosity without adding a thickening polymer for easy use. The composition of the invention also has a good foam quality and good sensory properties on the skin, especially after rinsing.

Description

063 225

51635 ® FRENCH REPUBLIC

NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY © Publication number:

(to be used only for reproduction orders)

©) National registration number

COURBEVOIE © Int Cl ⁸ : A 61 K8 / 58 (2017.01), A 61 K8 / 60, 8/36, 8/34, A 61 Q 1/14, 1/00, 5/00

A1 PATENT APPLICATION

©) Date of filing: 28.02.17. ©) Applicant (s): L'OREAL Société anonyme— FR. (30) Priority: @ Inventor (s): L'ALLORET FLORENCE and DES- VINCENT FIELDS. (43) Date of public availability of the request: 31.08.18 Bulletin 18/35. ©) List of documents cited in the report preliminary research: Refer to end of present booklet (© References to other national documents ©) Holder (s): L'OREAL Société anonyme. related: ©) Extension request (s): ©) Agent (s): L'OREAL Société anonyme.

FR 3 063 225 - A1 (t> 4) AQUEOUS FOAMING GEL COMPRISING AN ALKYL SULFATE DERIVATIVE, AN ALKYL POLYGLUCOSIDE, A POLYOL AND AN ORGANIC ACID.

The present invention relates to a foaming cleaning composition in the form of an aqueous gel comprising at least one alkyl sulfate derivative, at least one alkyl polyglucosides, optionally at least one alkyl betaine derivative, at least one polyol and at least one organic acid, the weight ratio of alkyl sulphate / alkyl polyglucosides being between 0.5 and 2.5, preferably between 0.8 and 1.3, and even more preferably between 0.9 and 1, 2.

The composition according to the invention is a foaming and transparent cleaning composition, stable, having excellent cosmeticity with in particular an optimized viscosity without adding thickening polymer for easy use. The composition of the invention also has a good quality of foam and good sensory properties on the skin, especially after rinsing.

Aqueous foaming gel comprising an alkyl sulfate derivative, an alkyl polyglucoside, a polyol and an organic acid

The subject of the present invention is a foaming cleaning composition in the form of an aqueous gel comprising at least one anionic surfactant chosen from alkyl sulphate derivatives, at least one nonionic surfactant chosen from alkyl polyglucosides, at least one polyol and at least an organic acid, as well as the use of said composition in particular in the cosmetic field as cleaning or make-up removing products for keratin materials such as the skin, keratin fibers (eyelashes and hair), the scalp, as well as for treating oily skin and / or disinfect the skin and / or scalp.

Cleansing the skin is very important for facial care. It must be as effective as possible because fatty residues such as excess sebum, the remains of cosmetic products used daily and makeup products accumulate in the skin folds and can clog the pores of the skin and cause the appearance of pimples.

One way to cleanse the skin well is to use foaming cleansers. The foaming cleaning products currently available on the market come in the form of breads, gels or foaming creams. They generally contain either soaps which have the advantage of giving a creamy foam but can cause tightness due to their excessive detergency, or foaming surfactants such as sulfated surfactants, in particular sodium lauryl sulfate (SLS) or sodium laureth sulfate (SLES), or amphoteric surfactants such as coconut betaine, cocoamidopropyl betaine or sodium cocoamphodiacetate, which are very effective in terms of foam and detergency.

Furthermore, the foaming products can be thickened using a salt, for example sodium chloride, for certain surfactants, or by the addition of a thickener of the alkyl-PEG type such as PEG-150 distearate. or PEG-55 propylene glycol oleate, or by adding a gelling agent of the natural gum type, in particular xanthan gum, scleroglucan or carrageenan.

Thickening with salt is a well-known and widely used approach, since it allows both to be inexpensive and also not to alter the qualities of foam; but in general, it does not allow the composition to be thickened significantly for all surfactant systems. On the other hand, the increase in the viscosity of the medium by a thickening or gelling agent is more versatile but often has a negative impact on the foam qualities of the formula (start, quantity of foam) and can be perceived negatively due to the sensory impact of this type of ingredients (texture too slippery on application, with a gelled appearance or difficult to rinse).

Cosmetic compositions for cleaning the skin, and in particular foaming cleansing products, are therefore widely used on a daily basis and consumers express the need for foaming products of simple composition having the following characteristics:

- a transparent texture often associated with aqueous and skin purification universes, the presentation of this type of texture in transparent packaging making it possible to highlight the specificity of this type of texture;

- a texture whose viscosity is optimized to facilitate the use of the product - indeed, thick foaming formulas are not easy to extract from the packaging (especially for children or seniors) while foaming formulas that are too fluid are difficult to manipulate ;

- while retaining good qualities of foam.

It therefore appears necessary to have available new foaming compositions for cleaning the skin which are transparent in appearance and whose texture is optimized in terms of viscosity in order to improve the qualities of use, while having compositions which do not incorporate thickening polymer. The cosmetic qualities sought are excellent, in terms of foaming properties and skin finish after rinsing.

It has been surprisingly discovered that the combination of at least one anionic surfactant chosen from alkyl sulphate derivatives, at least one nonionic surfactant chosen from alkyl polyglucosides, at least one polyol and at least one organic acid, with a mass ratio derived from alkyl sulphate / alkyl polyglucosides suitably chosen, makes it possible to obtain foaming and transparent skin-cleaning compositions, stable, having excellent cosmetic properties with in particular a viscosity optimized for use easy without adding thickening polymer.

The present invention therefore relates to a foaming cleaning composition in the form of an aqueous gel comprising at least one anionic surfactant chosen from alkyl sulphate derivatives, at least one nonionic surfactant chosen from alkyl polyglucosides, at least one polyol and at least one organic acid, the mass ratio derived from alkyl sulphate / alkyl polyglucosides being between 0.5 and 2.5.

The composition according to the invention is a foaming and transparent cleaning composition, stable, having excellent cosmetic properties with in particular an optimized viscosity without adding thickening polymer for easy use. The composition of the invention also has a good quality of foam and good sensory properties on the skin, especially after rinsing.

By "stable composition" is meant a composition which after 2 months of storage at all temperatures between 4 ° C and 45 ° C shows no macroscopic change in color, odor, viscosity, as well as no variation in microscopic appearance.

By "transparent composition" is meant a macroscopically homogeneous composition whose light transmittance, at a wavelength equal to 500 nm, through a sample 1 cm thick, is at least 10%, this which corresponds to an absorbance Abs = -log (transmittance) less than 1.5. The transparency of a transparent composition also corresponds to a range between 0 and 50 NTU measured with the HACH Company, Model 21 OOP Portable Turbidimeter turbidimeter.

The viscosity of the compositions of the invention is moreover between 0.5 and 5 Pa.s, and preferably between 0.65 and 2 Pa.s, and even more preferably between 0.8 and 1.2 Pa .s at a temperature of 25 ° C, the viscosity being measured using a Rheomat 180 (LAMY company), equipped with a mobile MS-R1, MS-R2, MS-R3, MS-R4 or MS -R5 chosen according to the consistency of the composition, rotating at a rotation speed of 200 rpm ' ¹ .

According to a particular embodiment of the invention, the composition comprises at least one additional surfactant chosen from alkyl betaine derivatives, which makes it possible to maximize the performance of the composition in terms of viscosity and cosmeticity. The subject of the invention is also a method of cosmetic treatment of keratin materials consisting in applying to the keratin materials a composition as defined above.

The subject of the invention is also the use of said composition in the cosmetic or dermatological field, and in particular for the care, protection and / or makeup of keratin materials, in particular of the skin of the body or of the face, or for hair care.

The composition according to the invention is intended for topical application and therefore contains a physiologically acceptable medium. The term “physiologically acceptable medium” is understood here to mean a medium compatible with keratin materials.

In the context of the present invention, the term “keratin material” is understood in particular to mean the skin, the scalp, keratin fibers such as the eyelashes, the eyebrows, the hair, and the hair, the nails, the mucous membranes such as the lips , and more particularly the skin (body, face, eye area, eyelids).

In what follows, the expression "at least one" is equivalent to "one or more" and, unless otherwise indicated, the limits of a range of values are included in this field.

Surfactants

The anionic surfactant (s) chosen from alkyl sulphate derivatives and the nonionic surfactant (s) chosen from the alkyl polyglucosides present in the composition of the invention, as well as the surfactant (s) chosen from alkyl betaines which may be present in the composition, are foaming.

Foaming surfactants are detergents and differ from emulsifying surfactants by the value of their HLB (Hydrophilic Lipophilie balance), HLB being the ratio between the hydrophilic part and the lipophilic part in the molecule. The term HLB is well known to those skilled in the art and is described for example in "The HLB System. A time-saving guide to Emulsifier Sélection ”(published by ICI Americas Inc; 1984).

The term HLB (from the English "Hydrophilic Lipophilie Balance") is well known to those skilled in the art, and designates the hydrophilic-lipophilic balance of a surfactant. The HLB or hydrophilic-lipophilic balance of the surfactant (s) used according to the invention can be determined by the GRIFFIN method or the DAVIES method.

The higher the value, the higher the solubility in water and conversely, the lower the value, the more the surfactant will have an affinity for oil.

The HLB according to GRIFFIN is defined in the publication J. Soc. Cosm. Chem. 1954 (Volume 5), pages 249-256 or the HLB determined experimentally and as described in the work of the authors F. PUISIEUX and M. SEILLER, entitled GALENICA 5: Dispersed systems - Tome I - Surface active agents and emulsions - Chapter IV - Notions of HLB and critical HLB, pages 153-194 - paragraph 1.1.2. HLB determination experimentally, pages 164-180.

Preferably, it is the value of the calculated HLB which must be taken into account.

The calculated HLB is defined as the following coefficient:

HLB calculated = 20 x molar mass hydrophilic part / total molar mass.

The HLB according to DAVIES consists in summing up the hydrophilic and lipophilic contributions made by each of the structural groups of the surfactant:

HLB - £ HLBgroupes hydrophilic ~ Σ H LBg _rO roups hydrophobic 7

Thus, the HLB of the surfactant is equal to the sum of the HLBs of the hydrophilic groups minus the sum of the HLBs of the hydrophobic groups plus 7.

There are HLB tables for the different classic groups that can be found in particular in the following collection: Surfactants in cosmetics, second edition, surfactant science seriés volume 68, edited by Martin M.Rieger & Linda D.Rhein, p. 134, table 4.

Reference may be made to the document “Encyclopedia of Chemical Technology, KIRKOTHMER”, volume 22, p. 333-432, 3 ^rd edition, 1979, WILEY, for the definition of the properties and emulsifying functions of surfactants, in particular p. 347377 of this reference, for anionic and nonionic surfactants.

According to a particular embodiment of the invention, the HLB values of the surfactant (s) are determined according to the DAVIES method which defines a scale varying from 0 to several tens (generally up to 50).

For emulsifying surfactants, the HLB generally ranges from 3 to 8 for the preparation of water-in-oil (W / O) emulsions and from 8 to 18 for the preparation of oil-in-water (O / W) emulsions, while the Foaming surfactants generally have an HLB greater than 18, and better still greater than 20.

Anionic surfactants derived from alkyl sulfate

The anionic surfactant (s) derived from alkyl sulphate which can be used in the context of the invention comprise at least one sulphate function (-OSO ₃ H or -OSO ₃ '). They can be chosen from the following compounds: alkylsulphates, alkylethersulphates, alkylamidoethersulphates, alkylarylpolyethersulphates, and mixtures thereof; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 8 to 24, even better from 8 to 16, or even from 10 to 14 carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds possibly being polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. Preferably, they are not polyoxyethylenated.

Preferably, the anionic surfactant (s) derived from alkyl sulfate are chosen from:

- alkyl sulfates, the linear or branched alkyl group comprising from 8 to 24 carbon atoms, in particular from 10 to 20 carbon atoms,

- alkyl ether sulfates, the linear or branched alkyl group comprising from 8 to 24 carbon atoms, in particular from 10 to 20 carbon atoms, preferably not ethoxylated,

- and their mixtures;

in particular in the form of alkali or alkaline-earth metal, ammonium or amino alcohol salts.

When the anionic surfactant is in the form of a salt, said salt can be chosen from alkali metal salts such as the sodium or potassium salt, ammonium salts, salts of amines and in particular amino alcohols, and alkaline earth metal salts such as the magnesium salt.

As examples of amino alcohol salts, mention may be made of the mono-, di- and triethanolamine salts, the mono-, di- or tri-isopropanolamine salts, the 2-amino 2methyl 1-propanol, 2-amino 2 salts -methyl 1,3-propanediol and tris (hydroxymethyl) amino methane.

The alkali or alkaline earth metal salts are preferably used, and in particular the sodium or magnesium salts.

According to a particular embodiment of the invention, the alkyl sulfate derivative (s) are chosen from (C8-C24) alkyl sulfates, preferably (C10-C20) alkyl sulfates, and mixtures thereof; in particular in the form of alkali or alkaline-earth metal, ammonium or amino alcohol salts.

As alkyl sulfate derivatives, mention may be made of the following surfactants:

- sodium lauryl sulfate sold under the names Texapon L S 30 by the company BASF; TEXAPON LS 30 or TEXAPON LS 30 NA or TEXAPON LS 30 / MB by BASF; SULFETAL LS - RSPO - B by ZSCHIMMER &SCHWARZ; STEPANOL WA-EXTRA HP or STEPANOL WA-EXTRA HP / MB by STEPAN; WILFARES LX28 / RSPO (MB) by WILMAR; ROSULFAN L / PH or ROSULFAN L / PH MB by PCC EXOL; RHODAPON LX28 FLA or RHODAPON LX-28 RLB by RHODIA (SOLVAY); ALKOPON 24 S 29 by OXITENO; TENSOPOL S30LSHPH by TENSACHEM;

- sodium coconut sulfate sold under the name of Mackol CAS 100N by the company Novecare.

In a preferred embodiment of the invention, the surfactant derived from alkyl sulfate is sodium lauryl sulfate.

The alkyl sulphate derivative (s) may be present in the composition in accordance with the invention in an active material (AM) content ranging from 0.5% to 20% by weight, preferably from 1% to 15% by weight , even more preferably from 1.5% to 12% by weight, and even better from 2% to 10% by weight of the total weight of the composition.

Non-ionic alkyl polyglucoside surfactants

For the purposes of the present invention, the term "alkyl polyglycoside" means an alkylmonooside (degree of polymerization 1) or alkylpolyoside (degree of polymerization greater than 1).

The alkylpolyglycosides can be used alone or in the form of mixtures of several alkylpolyglycosides. They generally correspond to the following formula (I):

RiO- (G) _a in which:

the radical R! denotes a linear or branched alkyl radical containing from 8 to 30 carbon atoms, preferably from 8 to 24 carbon atoms, even more preferably from 8 to 18, better still from 10 to 16, and even better still from 10 to 12;

group G is a saccharide residue;

a is a number ranging from 1 to 10, preferably from 1 to 5, in particular 1.2 to 3.

As examples of alkyl polyglucosides, mention may be made of decyl glucoside, for example the product sold under the name Mydol 10® by the company Kao Chemicals or the product sold under the name Plantacare 2000 UP® by the company Henkel or the product marketed under the name ORAMIX NS 10® by the company SEPPIC; caprylyl / capryl glucoside such as the product sold under the name Plantacare KE 3711® by the company Cognis or ORAMIX CG 110® by the company SEPPIC; laurylglucoside such as the product sold under the name Plantacare 1200 UP® by the company Henkel or Plantaren 1200 N® by the company Henkel; cetearyl glucoside optionally mixed with cetostearyl alcohol, sold for example under the name MONTANOV 68 by the company Seppic, under the name TEGO Care CG90 by the company Evonik Goldschmidt and under the names EMULGADE PL1618 or EMULGADE KE 3302 by the company Cognis ; cocoglucoside such as the product sold under the name Plantacare 818 UP® or Plantacare 818 UP: MB by the company BASF; methyl coco glucoside sold under the name Eumulgin GTS by the company Cognis; octyldodecyl xyloside sold for example under the names FLUIDANOV 20X or EASYNOV by the company SEPPIC; caprylylglucoside as the product sold under the name Plantacare 810 UP® by the company Cognis. According to a particular embodiment of the invention, the radical R! denotes a linear or branched alkyl radical, preferably linear, comprising from 8 to 18 carbon atoms, preferably from 10 to 12 carbon atoms.

According to another particular embodiment of the invention, (G) _a is a glucoside group comprising from 1 to 5, in particular 1.2 to 3 units of glucoside.

The saccharide residue can be chosen from glucose, dextrose, sucrose, fructose, galactose, maltose, maltotriose, lactose, cellobiose, mannose, ribose, dextran, talose, allose, xylose, levoglucane, cellulose or starch. More preferably, the saccharide residue denotes glucose.

It should also be noted that each unit of the polysaccharide part of the alkyl polyglycoside can be in isomeric form a or β, in form L or D and the configuration of the saccharide residue can be of the furanoside or pyranoside type.

It is of course possible to use mixtures of alkyl polysaccharides, which may differ from each other by the nature of the alkyl unit carried and / or the nature of the polysaccharide carrying chain.

According to a particular embodiment of the invention, the alkyl polyglucoside (s) are chosen from decyl glucoside, lauryl glucoside or coco glucoside. Preferably, they are chosen from decyl glucoside and coconut glucoside. Even more preferably, it is coconut glucoside.

The alkyl polyglucoside (s) may be present in the composition in accordance with the invention in an active material (AM) content ranging from 1% to 20% by weight, preferably from 1.5% to 15% by weight, even more preferably from 2% to 12% by weight, and even better from 2.5% to 10% by weight of the total weight of the composition.

In the composition according to the invention, the anionic surfactant (s) chosen from alkyl sulfate derivatives and the nonionic surfactant (s) chosen from alkyl polyglucosides are present in a mass ratio of alkyl sulfate / alkyl polyglucoside derivatives of between 0 , 5 and 2.5, preferably between 0.8 and 1.3, and even more preferably between 0.9 and 1.2.

Alkyl betaine derivatives

According to a particular embodiment of the invention, the composition comprises at least one additional surfactant chosen from alkyl betaine derivatives, which makes it possible to maximize the performance of the composition in terms of viscosity and cosmeticity, in particular transparency.

As betaine derivatives, mention may, for example, be made of cocobetaine, such as the product sold under the names DEHYTON AB-30® by the company Cognis; DEHYTON AB 30 or DEHYTON AB 30 / MB by BASF; BETAPAV A1214.30L by NIPAV; GALAXY COCOBETAINE or GALAXY COCOBETAINE-MB by GALAXY SURFACTANTS or GENAGEN KB by CLARIANT; MIRATAINE BB / FLA by RHODIA (SOLVAY); EMPIGEN BB / FL by INNOSPEC ACTIVE CHEMICALS; TEGO BETAIN AB 1214 by EVONIK GOLDSCHMIDT; COCO BETAINE by GUANGZHOU FLOWERS SONG FINE CHEMIC; ROKAMINA K30B by PCC EXOL; AMPHITOL 24B-2 by KAO, laurylbetaine as the product sold under the name GENAGEN KB® by the company Clariant; oxyethylenated lauryl betaine (10 EO), such as the product sold under the name LAURYLETHER (10 EO) BETAINE® by the company Shin Nihon Rica; oxyethylenated stearylbetaine (10 EO) such as the product sold under the name STEARYLETHER (10 EO) BETAINE® by the company Shin Nihon Rica; cocamidopropyl betaine sold for example under the name

VELVETEX BK 35® by the company Cognis; undecylenamidopropyl betaine sold for example under the name AMPHORAM U® by the company Ceca; and their mixtures.

According to a particular embodiment of the invention, the composition comprises at least one alkyl betaine, the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 8 to 24, even better from 8 to 16, or even from 10 to 14 carbon atoms.

According to a preferred embodiment, the alkyl betaine (s) are chosen from coco betaine, lauryl betaine. Preferably, the alkyl betaine is coco betaine.

The alkyl betaine derivative (s) are generally present in an active material content (AM) ranging from 0.5% to 10% by weight, preferably from 0.8% to 8% by weight, even more preferably from 1 % to 5% by weight, and even better from 1.2% to 3% by weight of the total weight of the composition.

Additional surfactants

The composition according to the invention can comprise, in addition to alkyl sulphate derivatives, alkyl polyglucosides and alkyl betaines, at least one so-called additional surfactant. The additional surfactants used in the composition according to the invention can be chosen from nonionic, amphoteric or zwitterionic, anionic or cationic surfactants. According to a particular embodiment, they are chosen from nonionic, amphoteric or anionic surfactants. Preferably, they are chosen from nonionic surfactants and anionic surfactants.

Reference may be made to the document “Encyclopedia of Chemical Technology, KIRKOTHMER”, volume 22, p. 333-432, 3 ^rd edition, 1979, WILEY, for the definition of the properties and functions (emulsifier) of surfactants, in particular p.347-377 of this reference, for anionic, amphoteric and nonionic surfactants.

According to a particular embodiment, the additional surfactant (s) are foaming.

In particular, the additional surfactant (s) different from the alkyl sulphate derivatives, alkyl polyglucosides and alkyl betaines can be chosen from the following surfactants.

a) Anionic surfactants

The anionic surfactants can be chosen, for example, from soaps (fatty acid salts), carboxylates such as for example sulfosuccinates, acylamino acids, amidoether carboxylates, alkyl polyaminocarboxylates, isethionates, alkyl methyltaurates, alkylphosphates (mono or dialkylphosphates), alkyl sulfoacetates, sulfonated fatty acids and sulfonated fatty acid esters, their salts, and mixtures thereof.

Soaps are obtained from a fatty acid which is partially or totally saponified (neutralized) by a basic agent. These are soaps of alkali or alkaline earth metal or organic bases. As fatty acids, saturated linear or branched fatty acids may be used, having from 8 to 30 carbon atoms, and preferably having from 8 to 22 carbon atoms. This fatty acid can in particular be chosen from palmitic acid, stearic acid, myristic acid, lauric acid and their mixtures.

As basic agents, it is possible, for example, to use alkali metal hydroxides (sodium hydroxide and potassium hydroxide or potassium hydroxide), alkaline earth metal hydroxides (for example magnesium), ammonium hydroxide, or alternatively organic bases such as triethanolamine, N-methylglucamine, lysine and arginine. The soaps may in particular be alkaline fatty acid salts, the basic agent being an alkali metal hydroxide, and preferably potassium or potassium hydroxide (KOH).

The amount of basic agent must be sufficient for the fatty acid to be at least partially neutralized.

As carboxylates, mention may in particular be made of alkyl glycol carboxylic acids (or 2- (2-hydroxyalkyloxy acetic acids)), and their salts such as for example sodium lauryl glycol carboxylate, sold under the names BEAULIGHT SHAA® or BEAULIGHT LCA-25N ® by the company SANYO (CTFA name: Sodium Lauryl Glycol Carboxylate), or its corresponding acid form marketed under the name BEAULIGHT SHAA (Acid Form) ® by the company SANYO.

As non-oxyalkylenated alkyl sulfosuccinates, mention may be made of lauryl alcohol sulfosuccinates (C12 / C14 70/30) (DISODIUM LAURYL SULFOSUCCINATE) such as that which is marketed under the name Rewopol® SB F 12 P by the company Evonik Goldschmidt, KOHACOOL L -40 by the company TOHO CHEMICAL, MACKANATE LO-FF by the company RHODIA.

As oxyalkylenated sulfosuccinates, there may be mentioned lauryl alcohol sulfosuccinates (C12 / C14 70/30) oxyethylenated (DISODIUM LAURETH SULFOSUCCINATE) such as those marketed under the names SETACIN 103 SPECIAL NP® by the company Zschimmer & Schwarz, REWOPOL SB FA 30 U by Evonik Goldschmidt, GOODWAY MES by SHANGHAI GOODWAY

CHEMICAL, REWOPOL SB FA 30 PH by the company Evonik Goldschmidt, ALKONIX SS K by the company ULTRA-OXITENO, DISODIUM LAURETH SULFOSUCCINATE by the company GUANGZHOU FLOWER'S SONG FINE CHEMICAL, KOHACOOL L300 by the company TOHO CHEMICALD EMPIC , the sodium salt of a hemi-sulfosuccinate of alcohols C12-C14, marketed under the name SETACIN F SPECIAL PASTE® by the company Zschimmer Schwarz, the oleamidosulfosuccinate di-sodium oxyethylenated (2 EO) marketed under the name STANDAPOL SH 135® by the company Cognis, the mono-sulfosuccinate of oxyethylenated lauric amide (5 EO) marketed under the name LEBON A5000® by the company Sanyo, the di-sodium salt of oxyethylenated lauryl citrate mono-sulfosuccinate (10 EO) under the name REWOPOL SB CS 50® by the company Witco, the mono-sulfosuccinate of ricinoleic mono-ethanolamide marketed under the name REWODE RM S 1333® by the company Witco. It is also possible to use polydimethylsiloxane sulfosuccinates such as the disodium PEG-12 dimethicone sulfosuccinate sold under the name MACKANATE-DC30® by the company Mac Intyre.

As acylamino acids, there may be mentioned, for example, sodium cocoylglycinate sold by the company Ajinomoto under the name Amilite GCS 12, sodium lauroyl glutamate sold by the company Ajinomoto under the name Amisoft LS11 and sodium lauroyl sarcosinate sold by the company Seppic under the name ORAMIX L 30.

As alkylphosphates, mention may, for example, be made of laurylphosphate sold by the company Kao under the name MAP 20.

The alkyl radical of the alkyl sulfoacetate (s) contain from 8 to 30 carbon atoms, preferably from 10 to 18 carbon atoms, and even more preferably from 10 to 16, better still from 10 to 14.

According to a particular embodiment, the alkyl sulfoacetate (s) correspond to the following formula (I):

MSO3-CH ₂ -CO-O- (CH ₂ ) x-CH3 in which:

x denotes an integer ranging from 7 to 29, preferably from 9 to 17, and even more preferably from 9 to 15, preferably from 9 to 13;

M denotes a hydrogen atom, an alkali or alkaline earth metal, an ammonium group or a cation derived from an amine.

When the alkyl sulfoacetate (s) are in salt form, they can be chosen from alkali metal salts such as the sodium or potassium and preferably sodium salt, ammonium salts, amine salts and in particular amino alcohols or alkaline earth metal salts such as magnesium salts. According to a particular embodiment of the invention, the alkyl sulfoacetate (s) are in the form of a salt. Preferably, they are chosen from alkali metal salts, and more particularly the sodium salt.

According to a particular embodiment of the invention, the anionic surfactant chosen from alkyl sulfoacetates is sodium lauryl sulfoacetate such as that which is marketed under the name LATHANOL LAL by the company STEPAN.

The sulfonated fatty acids and the sulfonated fatty acid esters which can then be used in the context of the invention comprise an alkyl radical of 8 to 30 carbon atoms, preferably from 10 to 18 carbon atoms, and even more preferably of 10 to 16, better from 10 to 14.

According to a particular embodiment, the sulfonated fatty acid (s) or sulfonated fatty acid esters correspond to the following formula (III):

CH ₃ - (CH ₂ ) x-CH (SO ₃ M) -CO-OY in which:

x denotes an integer ranging from 7 to 29, preferably from 9 to 17, and even more preferably from 9 to 15, and better still from 9 to 13;

M denotes a hydrogen atom, an alkali or alkaline earth metal, an ammonium group or a cation derived from an amine,

Y represents a hydrogen atom, a C1-C4 alkyl radical such as a methyl or ethyl radical, an alkali or alkaline earth metal.

When the sulfonate function of the sulfonated fatty acid (s) or sulfonated fatty acid esters is in salt form, it can be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium, the salts ammonium salts of amines and in particular amino alcohols or alkaline earth metal salts such as magnesium salts.

According to a particular embodiment of the invention, the sulfonate function of the sulfonated fatty acid (s) or esters of sulfonated fatty acid are in the form of a salt. Preferably, they are chosen from alkali metal salts, and even more particularly the sodium salt.

According to a particular embodiment, the sulfonated fatty acid (s) or sulfonated fatty acid esters used in the context of the invention are derived from lauric acid. Mention may in particular be made of sodium methyl-2-sulfolaurate (INCI name: SODIUM METHYL-2 SULFOLAURATE) and disodium 2-sulfolaurate (INCI name: DISODIUM 2-SULFOLAURATE), used alone or as a mixture.

According to a particular embodiment, these are sulfonated fatty acids and Y represents a hydrogen atom, an alkali or alkaline earth metal.

According to another particular embodiment, these are sulfonated fatty acid esters and Y represents a C1-C4 alkyl radical such as a methyl or ethyl radical.

The amount of anionic surfactants (in active material) preferably ranges from 0.1 to 15% by weight, better from 0.5 to 10% by weight and even better still from 0.5 to 5% by weight relative to the total weight of composition.

b) Nonionic surfactants

The composition according to the invention can also comprise a nonionic surfactant chosen for example from maltose esters, polyglycerolated fatty alcohols, glucamine derivatives such as 2-ethylhexyl oxy-carbonyl n-methyl glucamine, and their mixtures .

The maltose derivatives are for example those described in document EP-A-566 438, such as O-octanoyl-6'-D-maltose, or also O-dodecanoyl-6'-D-maltose described in the document FR-2,739,556.

Among the polyglycerolated fatty alcohols, mention may be made of polyglycerolated dodecanediol (3.5 moles of glycerol), a product sold under the name CHIMEXANE NF® by the company Chimex.

PEG-120 methylglucose dioleate, such as, for example, GLUCAMATE DOE 120 from the company Noveon or PEG150 pentaerythrityl tetrastearate, such as, for example, CROTHIX from the company Croda, can also be used as nonionic surfactants.

The amount of nonionic surfactants (in active material) preferably ranges from 0.1 to 10% by weight, better from 1 to 5% by weight and better still from 1 to 3% by weight relative to the total weight of the composition.

According to a particular embodiment of the invention, the total amount of active material of surfactants in the composition is between 1 and 40% by weight, preferably between 3 and 35% by weight, even more preferably between 5 and 30% by weight, and better still between 7 and 20% by weight of the total weight of the composition.

Polyol (s)

Polyols are defined as organic molecules comprising at least two hydroxyl functions (OH).

By polyol, within the meaning of the invention, is meant a linear, saturated or unsaturated, branched or unbranched hydrocarbon chain, comprising at least two hydroxyl functions. For example, the hydrocarbon chain is an alkyl radical.

According to a particular embodiment of the invention, the polyol or polyols present in the composition contain at least 4 carbon atoms and can be chosen in particular from C4-C9, preferably C ₄ -C _6, polyols.

Among the C4-C9 polyols, mention may be made in particular of 2-butene-1,4-diol, pentane-1,5diol, 2,2-dimethyl-propane-1,3-diol, 3-methyl- pentane-1,5-diol, pentane-1,2-diol, 2,2,4-trimethyl-pentane-1,3-diol, 2-methyl-propane-1,3-diol, hexylene glycol , 1,3butylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol.

According to a preferred embodiment, the polyol (s) are molecules of crude formula C _n H _m O _p in which the numbers n, m and p are integers with n is between 4 and 6, m is between 8 and 14 and p is between 2 and 5.

By way of example, mention may in particular be made of 1,2-pentane-diol sold under the name Pentiol Green + by the company Minasolve.

According to a particular embodiment of the invention, the mass concentration of polyols is between 0.01% and 10% by weight, preferably between 0.1% and 5% by weight, and even more preferably between 0 , 2% and 2% by weight relative to the total weight of the composition.

Organic acids

The composition according to the invention comprises at least one organic acid.

According to a particular embodiment of the invention, the organic monoacid (s) are mono carboxylic acids, the acid radical being a COOH carboxylic acid radical.

According to another particular embodiment of the invention, the organic acid or acids are monoacids, that is to say organic compounds comprising a single acid radical.

According to a preferred embodiment, the monoacid (s) are chosen from the compounds of formula (II) below, their stereoisomers, the organic or mineral salts, and the corresponding solvates:

O

(II) in which R represents a linear, branched or cyclic alkyl radical which comprises from 1 to 10 carbon atoms, a linear, branched or cyclic alkenyl radical which comprises from 2 to 10 carbon atoms, an aryl or aralkyl group which comprises from 6 to 10 carbon atoms, these groups being optionally substituted by one or more groups chosen from hydroxyl groups and C1-C4 alkoxy groups.

Preferably, the organic acid or acids present in the composition are chosen from the compounds of formula C _x H _y O _z in which the numbers x, y and z are whole numbers with x between 6 and 9, including between 5 and 9 and z between 2 and 4.

Examples include:

- salicylic acid sold under the name Salicylic acid Pharmaceutical Grade USP, ph. Eur by the company Novacyl, the benzoic acid sold under the name

PUROXB FLAKES PURE GRADE BENZOIC ACID by Emerald Performance Materials,

- the anisic acid sold under the name RONACARE 4-METHOXYBENZOIC ACID by the company Marck,

- the levulinic acid sold under the name Dermosoft 700 B by the company Lucas Meyer Cosmetics,

- sorbic acid sold under the name Sorbic acid by the company Daicel.

According to a preferred embodiment of the invention, the organic acid is salicylic acid.

The organic acid or acids are present in the composition at a mass concentration of between 0.1% and 1%, preferably between 0.2% and 0.6% by weight of the total weight of the composition.

Aqueous phase

The composition according to the invention comprises an aqueous phase.

According to a particular embodiment, the composition according to the invention comprises an amount of water of between 65% and 95% by weight, preferably between 70% and 90% by weight, and better still between 75% and 85% by weight. weight relative to the total weight of the composition.

The water used can be sterile demineralized water and / or floral water such as rose water, blueberry water, chamomile water or linden water, and / or natural thermal or mineral water, for example: water from Vittel, water from the Vichy basin, water from Uriage, water from Roche Posay, water from Bourboule, water d'Enghien-les-Bains, water from Saint Gervais-les-Bains, water from Néris-les-Bains, water from Allevar-les-Bains, water from Digne, water from Maizières, water from Neyrac-les-Bains, water from Lons-le-Saunier, Eaux Bonnes, water from Rochefort, water from Saint Christau, water from Fumades and water from Tercis -the baths, Avene water. The aqueous phase can also comprise reconstituted thermal water, that is to say water containing trace elements such as zinc, copper, magnesium, etc., reconstituting the characteristics of thermal water.

The aqueous (or hydrophilic) phase of the composition according to the invention may also contain any water-soluble or water-dispersible additive. As water-soluble additives, mention may in particular be made of polyols other than those defined above, such as, for example, glycerin and propylene glycol.

As water-soluble additives, mention may also be made of primary alcohols, that is to say an alcohol containing from 1 to 6 carbon atoms, such as ethanol and isopropanol. It is preferably ethanol. The addition of such an alcohol may in particular be suitable when the composition according to the invention is used as a product for the body or the hair.

The amount of water-soluble or water-dispersible additives in the composition of the invention can range, for example, from 0 to 50% by weight, preferably from 0.5 to 30% by weight, and even more preferably from 2 to 20% by weight. relative to the total weight of the composition.

The compositions of the invention may contain adjuvants usually used in the cosmetic field, and in particular those used in cleaning products. As adjuvants, mention may be made, for example, of perfumes, preservatives, sequestrants (EDTA), pigments, pearlescent agents, mineral or organic fillers, mattifying, whitening or exfoliating, soluble dyes, solar filters, cosmetic active agents or dermatological agents such as water-soluble or liposoluble vitamins, antiseptics, antiseborrheics, antimicrobials such as benzoyl peroxide, triclosan, azelaic acid, and also optical brighteners, nonionic polymers such as polyvinylpyrrolidone (PVP) , anionic polymers, amphoteric conditioner polymers such as polyquaternium such as for example polyquaternium-47 sold under the reference Merquat 2001 by the company Nalco, fatty substances incompatible with the aqueous medium, such as oils or waxes. The amounts of these various adjuvants are those conventionally used in the field under consideration, and for example from 0.01 to 25% of the total weight of the composition. These adjuvants and their concentrations must be such that they do not modify the property sought for the composition of the invention.

As active agents, mention may be made of any care or cleaning active agent usually used in the cosmetic field, and in particular antibacterials such as octopirox and triclosan, keratolytic agents such as lactic acid or glycolic acid, derivatives of salicylic acid such as n-octanoyl-5-salicylic acid, essential oils, fruit waters (for example apple, grape) or floral waters (for example rose), plant extracts (especially tea, mint, orchid, soy, aloe vera, honey), mineral salts (e.g. zinc, copper), vitamins like vitamin C (ascorbic acid, vitamin A (retinol), vitamin E, vitamin PP (niacinamide), vitamin B3 (panthenol) and their derivatives.

As fillers, mention may be made of mineral fillers such as talc or magnesium silicate (particle size: 5 microns) sold under the name LUZENAC 15 M00® by the company LUZENAC, kaolin or aluminum silicate such as for example that sold under name KAOLIN SUPREME® by the company IMERYS, or organic fillers such as starch such as for example the product marketed under the name AMIDON DE MAIS B ® by the company ROQUETTE, nylon microspheres like those marketed under the name ORGASOL 2002 UD NAT COS® by ATOCHEM, microspheres based on vinylidene chloride / Acrylonitrile / methacrylonitrile copolymer containing isobutane, expanded like those sold under the name EXPANCEL 551 DE® by the company EXPANCEL. It is also possible to add fibers to the composition of the invention, for example nylon fibers (POLYAMIDE 0.9 DTEX 0.3 MM sold by PAUL BONTE establishments, cellulose fibers or "Rayon" (RAYON FLOCK RCISE NOOO3 MO4® sold by CLAREMONT FLOCK CORPORATION).

According to a particular embodiment, the composition according to the invention contains as fillers, exfoliating particles which will allow the exfoliation of the skin. As exfoliating particles, one can use exfoliating or exfoliating particles of mineral, vegetable or organic origin. Thus, perlites such as those marketed under the names Imercare 270P-Scrub and Imercare 400P-Scrub by the company IMERYS can be used, for example, beads or polyethylene powder, such as those marketed under the name Microthene MN 727 or Microthene MN 71020 by the company Equistar or as the powder sold under the name Gotalene 120 Incolore 2 by the company Dupont; nylon particles such as those sold by the company Arkema under the name Orgasol 2002 EXD NAT COS; fibers such as polyamide fibers, such as those sold by the company Utexbel under the name PULPE POLYAMIDE 12185 SIZE 0.3 MM; polyvinyl chloride powder; pumice stone (INCI name: pumice) such as pumice 3 / B from Eyraud; crushed fruit kernel hulls such as apricot kernel or nut shell hulls; sawdust; glass beads; alumina (aluminum oxide) (INCI name: Alumina) as the product marketed under the name

Dermagrain 900 by Marketech International, sugar crystals; beads which melt during application to the skin, such as, for example, the spheres based on mannitol and cellulose sold under the names Unisphères by the company Induchem, the capsules based on agar sold under the names Primasponge by the Cognis, and the spheres based on jojoba esters sold under the names Florasphères by the company Floratech; diatom frustules such as those sold by the company Alban Muller under the reference Diatami 60/200 microns, polyethylene wax particles such as, for example, those which are sold by the company Sasol under the name Cirebelle.

The filler (s) and / or the exfoliating particle (s) are generally present in the composition at concentrations ranging from 0.01% to 10% by weight, preferably from 0.1% to 5% by weight, and even more preferably from 0.5% to 3% by weight of the total weight of the composition.

According to a preferred embodiment, the composition according to the invention comprises particles of perlite.

The perlites which can be used in the context of the invention may be expanded perlites. They are generally aluminosilicates of volcanic origin and they have as composition:

70.0-75.0% by weight of silica SiO ₂ ;

12.0-15.0% by weight of aluminum oxide oxide AI ₂ O ₃ ;

3.0-5.0% sodium oxide Na ₂ O;

3.0-5.0% potassium oxide K ₂ O;

0.5-2% iron oxide Fe ₂ O ₃ ;

0.2-0.7% magnesium oxide MgO;

0.5-1.5% calcium oxide CaO;

0.05-0.15% titanium oxide TiO ₂ .

The perlite is ground, dried and then calibrated in a first step. The product obtained, called Perlite Ore, is gray in color and around 100 pm in size.

Perlite Ore can then be expanded (1000 ° C / 2 seconds) to give more or less white particles. When the temperature reaches 850-900 ° C, the water trapped in the structure of the material vaporizes and causes the material to expand compared to its original volume. The expanded perlite particles which can be used in the context of the invention can be obtained by the expansion process described in US Pat. No. 5,002,698.

According to a particular embodiment of the invention, the expanded perlite particles used are ground; in this case they are called Expanded Milled Perlite (EMP). They preferably have a particle size defined by a median diameter D ₅₀ ranging from 0.5 to 1000 μm, preferably from 10 to 800 μm, and even more preferably from 100 to 500 μm.

D ₅₀ is the mean by volume size of 50% of the particles and is measured at 25 ° C. by laser diffraction with a device of the Malvern Mastersizer type.

As examples, mention may be made of the perlites marketed under the names Imercare 270P-Scrub and Imercare 400P-Scrub by the company IMERYS.

In this preferred embodiment, the perlite particles are generally present in the composition at concentrations ranging from 0.01% to 10% by weight, preferably from 0.1% to 5% by weight, and even more preferably from 0.5% to 3% by weight of the total weight of the composition.

The compositions according to the invention may especially constitute cleaning or make-up removing products for the skin (body, face, eyes), scalp and / or hair, preferably cleaning or make-up removing products for the skin (body , face, eyes).

Another object of the invention is a process for cleaning or removing makeup from keratin materials such as the skin, including the scalp, keratin fibers such as the eyelashes, the hair, and / or the lips, characterized by the fact which is applied to said keratin materials, a cosmetic composition as defined above. According to a particular embodiment, it is a process for cleaning or removing makeup from the skin.

Another object of the invention consists in the cosmetic use of the composition as defined above, as cleaning and / or make-up removing products for keratin materials.

The compositions according to the invention can also constitute a composition for treating oily skin and / or disinfecting the skin and / or scalp, in particular when they contain an antibacterial. In particular, specific active ingredients for the treatment of oily skin can be included, such as, for example, azelaic acid, triclosan, piroctone olamine, niacinamide (vitamin PP).

Another object of the invention is the use of the composition as defined above for the preparation of a composition intended for treating oily skin and / or disinfecting the skin and / or scalp.

Another object of the invention consists in a cosmetic process for cleaning keratin materials, in which the composition of the invention is applied to keratin materials, in the presence of water, and that the foam formed and the residues are removed. soiling by rinsing with water.

In the case of facial cleansing, the composition according to the invention can constitute a mask which is rinsed off after an exposure time of 1 to 3 minutes.

The examples which follow serve to illustrate the invention without, however, being limiting in nature. The quantities indicated are in% by weight of raw material (MP) and / or active material (MA).

Examples

The following compositions were carried out.

Composition 1 (invention) 2 (invention) 3 (comparative) 4 (comparative) Citric acid 0.19 0.19 0.19 0.19 Lauryl sulfate sodium solution 29% aqueous MY (TEXAPON LS 30 BASF) 26 (7.54 MA) 13.83 (4.01 MA) 6.9 (2.00 MA) 26 (7.54 MA) Alkyl (C8 / C16) polyglucoside (1,4) in solution 53% aqueous (PLANTACARE 818 UP from BASF) 15 (7.8 MA) 6.56 (3.41 MA) 10.58 (5.50 MA) 5 (2.6 MA) Pentane-1,2-diol 0.5 0.5 0.5 0.5 Glycerin 5 10 10 5 Coconut betaine in aqueous solution to 30 % (DEHYTON AB 30 BASF) 4.64 (1.39 MA) 4.64 (1.39 MA) 10 (3 MY) Salicylic acid 0.2 0.2 0.2 0.2 Plant extract 0.12 0.12 0.12 0.12 Sodium chloride 2.5 0.80 0.80 3.65 Perfume 0.5 0.5 0.5 0.5 Water Qsp 100 Qsp 100 Qsp 100 Qsp 100 Mass ratio alkyl derivatives sulfate / alkyl polyglucosides 0.96 1.17 0.36 2.94

Method of preparation :

The compositions defined above are prepared at room temperature by mixing and dissolving the various ingredients with stirring in the following order: water + citric acid and sodium chloride, then addition of glycerin, natural extract and perfume , and finally surfactants sodium lauryl sulfate, coco glucoside and coco betaine if used.

Results:

Composition 1 (invention) 2 (invention) 3 (comparative) 4 (comparative) Stability +++ +++ +++ +++ Transparency (NTU) 5.1 6.1 6.0 117.5 Viscosity (Pas.s) 1.19 0.98 0.312 0.123

Compositions 1 and 2 are homogeneous, transparent and meet the desired viscosity target. The viscosity of composition 3 has too low a viscosity, outside the viscosity range desired for the compositions of the invention.

These results show that only the compositions comprising an alkyl sulphate derivative and an alkylpolyglucoside in a ratio of mass concentrations [Alkyl Sulfate] / [Alkylpolyglucoside] of between 0.5 and 2.5, a polyol and an organic acid are stable, transparent and have a viscosity between 0.5 and 5 Pa.s without adding thickening polymer. These compositions also have a good quality of foam and good sensory properties on the skin, especially after rinsing.

For comparative composition 3 which does not meet the ratio of surfactant [Alkyl Sulfate] / [Alkylpolyglucoside] defined for our invention, the viscosity level does not meet our target (viscosity between 0.5 and 5 Pa.s) . The qualities of use, in particular in the application are not optimized because the composition is too fluid.

For comparative composition 4 which does not meet the ratio of surfactant [Alkyl Sulfate] / [Alkylpolyglucoside] defined for our invention, the viscosity level does not meet our target (viscosity between 0.5 and 5 Pa.s) . The qualities of use, in particular in the application are not optimized because the composition is too fluid. Furthermore, the level of transparency does not meet our target either (transparency between 0 and 50 NTU).

Claims (18)

1. Foaming cleaning composition in the form of an aqueous gel comprising at least one anionic surfactant chosen from alkyl sulphate derivatives, at least one non-surfactant 5 ionic chosen from alkyl polyglucosides, at least one polyol and at least one organic acid, the mass ratio derived from alkyl sulfate / alkyl polyglucosides being between 0.5 and 2.5, preferably between 0.8 and 1.3, and even more preferably between 0.9 and 1.2. 2. Composition according to Claim 1, in which the alkyl sulphate derivative (s) are chosen from the following compounds: aikylsulphates, alkylethersulphates, alkylamidoethersulphates, alkylarylpolyethersulphates, and mixtures thereof; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 8 to 16, even better from 10 to 14 carbon atoms; the group Aryl preferably denoting a phenyl or benzyl group; these compounds possibly being polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. 3. Composition according to any one of claims 1 and 2 in which the one or more 20 alkyl sulfate derivatives are chosen from (C8-C24) alkyl sulfates, preferably (C10-C20) alkyl sulfates; in particular in the form of alkali or alkaline earth metal, ammonium, or amino alcohol salts, and preferably in the form of alkali or alkaline earth metal, ammonium, or amino alcohol salts, preferably the alkyl sulfate derivatives are chosen from alkali or alkaline earth seis of lauryl sulfate, and 25 even more preferably it is su sodium lauryl sulfate. 4. Composition according to any one of claims 1 to 3 wherein the or alkylpolyglycosides have the formula _(I):: RîQ- (G) a 30 in which: the radical Ri denotes a linear or branched alkyl radical containing from 8 to 30 carbon atoms, preferably from 8 to 24 carbon atoms, even more preferably from 8 to 18, better from 10 to 16, and even better from 10 to 12 ; group G is a saccharide residue; 35 a is a number ranging from 1 to 10, preferably from 1 to 5, in particular 1.2 to 3. 5. Composition according to claim 4 in which the saccharide residue is chosen from glucose, dextrose, sucrose, fructose, galactose, maltose, maltotriose, lactose, cellobiose, mannose, ribose, dextran, talose, allose, xylose, levoglucane, cellulose or starch , preferably it is glucose. 6. Composition according to any one of claims 1 to 5 in which the alkyl polyglucoside (s) are chosen from deeyl glucoside, lauryl glucoside and coco glucoside, preferably from deeyl glucoside and coco glucoside, and even more preferably, it is the coconut glùcosidè. 7. Composition according to any one of claims 1 to 6 in which the polyol or polyols contain at least 4 carbon atoms and can be chosen in particular from C4-C9, preferably C4-C6, polyols. 15 8. Composition according to any one of claims 1 to 7 in which the polyol (s) are chosen from 2-butene-1,4-diol, pentane-1,5-dîôl, 2,2-dimethylpropanè-1 , 3-diol, 3-methyl-pentane-1,5-diol, pentane-1,2-diol, 2,2,4-trimethylpentane-1,3-diol, 2-methyl-propane-1 , 3-diol, hexylene glycol, 1,3-butylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, preferably it is 20 pentane-1,2-diol. 9. Composition according to any one of claims 1 to 8, in which the polyol (s) are molecules of crude formula C _n H _m Op in which the numbers n, m and p are integers with n is between 4 and 6, m is between 8 and 14 and p 25 is between 2 and 5. 10. Composition according to any one of claims 1 to 9 in which te or the organic acids are mono-carboxylic acids, the acid radical being a carboxylic acid radical -COQH. 11. Composition according to any one of claims 1 to 10 in which the organic acid or acids are chosen from the compounds of formula (II) below, their stereoisomers, the organic or mineral salts, and the corresponding solvates: O In which R represents a linear, branched or cyclic alkyl radical which comprises 1 to 10 carbon atoms, a linear, branched or cyclic alkenyl radical which comprises from 2 to 10 carbon atoms, an aryl or aralkyl group which comprises from 6 to 10 carbon atoms, these groups being optionally substituted by one or more groups chosen from hydroxyl groups and C1-C4 alkoxy groups. 12. Composition according to any one of claims 1 to 11 in which the organic acid or acids are chosen from the compounds of formula C _x HÿO _z in which the numbers x, y and z are whole numbers with x between 6 and 9, including between 5 and 9 and z between 2 and 4. 13. Composition according to any one of claims 1 to 12 in which the organic acid or acids are chosen from salicyic acid, benzoic acid, unnisic acid, levulinic acid, sorbic acid, preferably it is salicyiic acid. 14. Composition according to any one of claims 1 to 13 comprising at least one alkyl betaine derivative. 15. Composition according to Claim 14, in which the alkyl betaine derivative (s) are alkyl betaines, the alkyl groups of these compounds comprising from 6 to 20 30 carbon atoms, especially from 8 to 16, even better from 10 to 14 carbon atoms. 16. Composition according to any one of claims 14 and 15 in which the betaine derivative or derivatives are chosen from cocobetaine and lauryl betaine, preferably it is cocobetaine. 17. Composition according to any one of claims 1 to 16 further comprising perlite particles. 18. Non-therapeutic cosmetic method for cleaning and / or removing makeup from keratin materials in which a composition as defined in one of claims 1 to 17 is applied to said keratin materials. 19. Use of a composition as defined in any one of claims 1 to 17 in the non-therapeutic cosmetic field, and in particular for care, fa 35 protection and / or make-up of keratin materials, in particular of the skin of the body or of the face, or for the care of the hair, in particular for cleaning and / or removing make-up from keratin materials.