FR3059472B1 - Pile a cathode liquide specifique - Google Patents

Pile a cathode liquide specifique Download PDF

Info

Publication number
FR3059472B1
FR3059472B1 FR1661585A FR1661585A FR3059472B1 FR 3059472 B1 FR3059472 B1 FR 3059472B1 FR 1661585 A FR1661585 A FR 1661585A FR 1661585 A FR1661585 A FR 1661585A FR 3059472 B1 FR3059472 B1 FR 3059472B1
Authority
FR
France
Prior art keywords
liquid cathode
cathode battery
specific liquid
matrix
oxidizing solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1661585A
Other languages
English (en)
Other versions
FR3059472A1 (fr
Inventor
Benoit Chavillon
Lionel Blanc
Eric Mayousse
Remi Vincent
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1661585A priority Critical patent/FR3059472B1/fr
Priority to EP17203594.1A priority patent/EP3327840B1/fr
Priority to US15/823,198 priority patent/US20180151913A1/en
Publication of FR3059472A1 publication Critical patent/FR3059472A1/fr
Application granted granted Critical
Publication of FR3059472B1 publication Critical patent/FR3059472B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/368—Liquid depolarisers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40—Alloys based on alkali metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/806—Nonwoven fibrous fabric containing only fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/002—Inorganic electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

L'invention a trait à une pile à cathode liquide comprenant : -une anode en calcium ; -un électrolyte comprenant un solvant oxydant soufré et/ou phosphoré et au moins un sel ; -une cathode comprenant, comme matériau actif, un composé identique au solvant oxydant susmentionné et comprenant une matrice carbonée ; caractérisée en ce que la matrice carbonée est un matrice autosupportée comprenant des fibres de carbone enchevêtrées présentant une porosité d'au moins 92% et une surface spécifique inférieure à 5 m2/g.
FR1661585A 2016-11-28 2016-11-28 Pile a cathode liquide specifique Expired - Fee Related FR3059472B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR1661585A FR3059472B1 (fr) 2016-11-28 2016-11-28 Pile a cathode liquide specifique
EP17203594.1A EP3327840B1 (fr) 2016-11-28 2017-11-24 Pile à cathode liquide spécifique
US15/823,198 US20180151913A1 (en) 2016-11-28 2017-11-27 Specific liquid cathode battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1661585 2016-11-28
FR1661585A FR3059472B1 (fr) 2016-11-28 2016-11-28 Pile a cathode liquide specifique

Publications (2)

Publication Number Publication Date
FR3059472A1 FR3059472A1 (fr) 2018-06-01
FR3059472B1 true FR3059472B1 (fr) 2019-05-17

Family

ID=58228174

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1661585A Expired - Fee Related FR3059472B1 (fr) 2016-11-28 2016-11-28 Pile a cathode liquide specifique

Country Status (3)

Country Link
US (1) US20180151913A1 (fr)
EP (1) EP3327840B1 (fr)
FR (1) FR3059472B1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7742584B2 (ja) * 2021-04-19 2025-09-22 パナソニックＩｐマネジメント株式会社 固体電解質組成物、固体電解質材料および固体電解質組成物の製造方法
CN113437358A (zh) * 2021-07-19 2021-09-24 中国科学院青岛生物能源与过程研究所 一种电解液添加剂及其在可充锂亚硫酰氯电池中的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4167608A (en) * 1977-08-29 1979-09-11 Vincent Owen Catanzarite Additive for lithium anode, thionyl chloride active cathode electrochemical cell
IL55428A0 (en) * 1977-08-29 1978-10-31 Catanzarite Vincent Owen High energy electro-chemical power cells
IL77786A (en) * 1986-02-04 1990-02-09 Univ Ramot Electrochemical cell
US5415959A (en) * 1993-10-29 1995-05-16 Wilson Greatbatch Ltd. Woven synthetic halogenated polymer fibers as separator material for electrochemical cells
US7482096B2 (en) * 2003-06-04 2009-01-27 Polyplus Battery Company Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells
FR2872347B1 (fr) * 2004-06-25 2006-09-29 Accumulateurs Fixes Generateur electrochimique a cathode en aerogel de carbone
FR3032559B1 (fr) * 2015-02-10 2021-03-19 Commissariat Energie Atomique Pile a cathode liquide specifique pouvant fonctionner a hautes temperatures

Also Published As

Publication number Publication date
US20180151913A1 (en) 2018-05-31
EP3327840B1 (fr) 2019-10-02
EP3327840A1 (fr) 2018-05-30
FR3059472A1 (fr) 2018-06-01

Similar Documents

Publication Publication Date Title
AR121838A2 (es) Partícula de intercambio iónica recubierta y estructura porosa para intercambio iónico
WO2016057457A3 (fr) Cellule électrochimique de zinc-halogénure
MX2018002652A (es) Catodo y materiales de catodo para baterias de sulfuro de litio.
FR3032559B1 (fr) Pile a cathode liquide specifique pouvant fonctionner a hautes temperatures
WO2013170217A3 (fr) Pile à combustible microbienne
BRPI0418500A (pt) estrutura de célula eletroquìmica, célula de bateria, métodos para fornecer a inativação de uma célula eletroquìmica no evento de falha estrutural e para fabricar uma célula de bateria
SA518400457B1 (ar) جهاز وطريقة للاستخدام الكهروكيميائي لثاني أكسيد الكربون
JP2017535044A5 (fr)
BR112012018419A2 (pt) célula de combustível de redox, processo para operar uma célula de combustível de redox, uso de uma célula de combustível, sistema de calor e energia combinados, veículo, componente eletrônico, e, sistema de regeneração de católito.
CL2017002154A1 (es) Conjunto de diafragma-electrodo para uso en electrolizadores de agua alcalina
BR112018074702A2 (pt) método para reciclar baterias de íon de lítio
MX368218B (es) Estructuras fibrosas que contienen activos con multiples regiones.
MX352942B (es) Estructuras fibrosas que contienen activos y multiples regiones que tienen densidades diferentes.
WO2016048309A8 (fr) Solution de polymère, mat de fibres et ensemble membrane-électrode en nanofibres l'incluant, et son procédé de fabrication
FR3059472B1 (fr) Pile a cathode liquide specifique
BR112012031770A2 (pt) pano não tecido reforçado
EA201291193A1 (ru) Электрод для электрохлорирования
FR3063728B1 (fr) Composes ioniques redox bis(pyridinium)-naphthalene diimide comme materiaux actifs d'electrode
WO2012048032A3 (fr) Systèmes et procédés chimiques pour faire fonctionner une cellule électrochimique avec un anolyte acide
MX2022003255A (es) Aditivos de electrolitos fluorados.
TR201907654T4 (tr) Hidrofilik maddelere sahip bağlayıcılar içeren aside dirençli cam matlar.
Imbihl Electrochemical promotion of catalytic reactions
MX382113B (es) Conjunto de electrodos, estructuras de electrodo y electrolizadores.
RU2009104751A (ru) Установка для электролиза
SA519401765B1 (ar) خلية انحلال كهربي أو لوح إلكترود به إلكترود يعمل بانتشار الغاز، وطريقة لتشغيلها

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Search report ready

Effective date: 20180601

PLFP Fee payment

Year of fee payment: 4

ST Notification of lapse

Effective date: 20210705