FR3042496A1 - USE OF FILLED ZIRCONIA - SPINELLE GRAINS FOR THE MANUFACTURE OF REFRACTORY PRODUCTS - Google Patents

Abstract

Use of molten grains for the manufacture of refractory materials, in which: - the said grains comprise a matrix of the zirconia-spinel eutectic coating inclusions consisting essentially of a zirconia phase or of a spinel phase, - the said grains have the composition following overall chemical, in weight percentages expressed as oxides: ○ more than 45.0% and less than 95.0% ZrO2, ○ more than 3.0% and less than 40.0% Al2O3 ○ more than 1.0% and less than 20.0% of MgO, ZrO2, Al2O3 and MgO together representing at least 95.0% of the weight of said grains.

Description

The invention relates to fused grains for ceramics applications consisting mainly of zirconia and spinel. The invention relates to the use of melted grains for the manufacture of refractory products used in particular, but not only, in the field of metallurgy, in particular for the manufacture of refractory parts for the manufacture or processing of metals or metal alloys. They can also be used as a coating for metal parts or in the case of contact between a ceramic part and a metal.

In the remainder of the description, for convenience and in accordance with the habits in the field of ceramics, said oxides comprising elements Al, Mg and Zr (or others) will be described with reference to the corresponding simple oxides, that is to say AI2O3, MgO , ZrC> 2. Thus, in the description which follows, unless otherwise mentioned, the proportions of the various elements in the overall chemical compositions of the grains according to the invention are given with reference to the weight of the corresponding simple oxides, reported as a percentage by weight with respect to all the oxides present in said grains, even if they are not necessarily present in this simple form in said grains. In contrast, in the present description, the term "composition" refers to a composition actually present with an oxide in said grains by "phase" or "oxide phase". The invention relates to the application, that is to say the advantageous use of melted grains of a specific composition in the specific field of refractory products used in metallurgy, that is to say for the elaboration of metals or metal alloys, in particular for the production of casting nozzle flanges or as insert in slide plates. However, it is understood that such grains, by the advantages they provide, are likely to be used advantageously in many other applications in the field of refractory ceramics, especially in any field for which a high thermal stability and resistance to corrosion. corrosion, especially at temperatures above 1000 ° C, are sought.

In particular, many areas of furnaces for manufacturing or processing metals or their alloys require the use of refractory products resistant to high temperatures.

For example, the slide plates, or "slide gates" according to the English term, are parts used during a continuous casting of the steel to open or close distributors or outlets of ladles in communication with fluid, via a sliding nozzle ("sliding nozzle" in English), with ingot molds.

The pouring nozzles and the slide plates presently comprise parts made of zirconia, most often partially stabilized.

The patent application CN101786889 for example describes nozzles made from bricks comprising from 12 to 87% of zirconia, 10 to 85% of a magnesium aluminum spinel and 3 to 15% of an additional material chosen from corundum, zircon, mullite or mixtures thereof, in combination with an organic binder.

The elementary bricks are obtained by sintering at a temperature greater than 1400 ° C. of an initial mixture of spinel, zirconium oxide with a purity greater than 94% and the additional material previously described.

The work carried out by the applicant company, however, has shown that such products can, as and when they are used, lose their initial properties of temperature resistance and in particular have cracks requiring replacement.

In particular, according to the research measured by the applicant company, it seems that this reduction in durability is directly related to structural modifications of the material constituting the refractory, and more particularly to the crystallographic transformation of zirconium oxide, even partially stabilized. , during the successive temperature cycles to which it is subjected. In particular, it has been found by the applicant company a gradual transformation of the cubic or tetragonal form of zirconia, even when it is partially stabilized, to the monoclinic form. In a known manner, such a transformation, of martensitic type, results in a microcracking of the constituent grains and consequently a degradation of the material during its return to lower temperature.

There is thus still at present a need for raw materials (especially in the form of grains) for the manufacture of such refractory materials, in particular used in the field of metallurgy, which make it possible to improve after shaping the stability thermal of said refractory materials.

The object of the present invention is to respond to such a need, that is to say to provide raw materials, in the form of grains, which make it possible to obtain and use, after shaping, materials having improved resistance to temperature variations imposed by their use especially for casting metals, and a longer life.

The present invention relates to the use of fused grains for the manufacture of refractory materials, wherein: said grains comprise a matrix of the zirconia-spinel eutectic coating inclusions consisting essentially of a zirconia phase or a spinel phase, said grains have the following overall chemical composition, in percentages by weight expressed in the form of oxides: o greater than 45.0% and less than 95.0% ZrO 2, o more than 3.0% and less than 40, 0% Al2O3, o more than 1.0% and less than 20.0% MgO,

ZrO 2, Al 2 O 3 and MgO together represent at least 95.0% of the weight of said grain.

In the present description, unless expressly otherwise specified, all percentages are by weight.

According to certain preferred embodiments of the present invention according to which, of course, they can be combined with one another if appropriate, the melted grains used have the following characteristics: said grains consisting essentially of a zirconia phase and an oxide of magnesium and aluminum spinel structure. The chemical composition comprises more than 68% by weight of ZrO 2. Said chemical composition comprises less than 25% by weight of Al 2 O 3 · - the Al 2C> 3 / MgO mass ratio is between 1.0 and 5.0, preferably between 1.5 and 3. - ZrO 2, Al 2 O 3 and MgO together represent more than 98.0% of the weight of said grains. The melted grains according to the invention further comprise, on the oxide basis, more than 0.2% by weight of Y 2 O 3. The melted grains according to the invention further comprise, on the basis of the oxide, less than 4% by weight of Y 2 O 3. - The melted grains according to the invention further comprise, on the oxide basis, more than 0.2% by weight of CaO. - The melted grains according to the invention further comprise on the basis of the oxide less than 4% by weight of CaO. More than 50% of the inclusions consisting essentially of zirconium oxide have a larger dimension of less than 500 micrometers. - The melted grains according to the invention comprise less than 5% by weight, preferably less than 3% by weight, of an additional phase of alumina. - The melted grains according to the invention comprise less than 5% by weight, preferably less than 3% by weight, of an additional phase of magnesia. The spinel phase (s) represent (s) between 5% and 50%, by weight, of said grains. ZrO2-spinel eutectic represents between 10% and 80%, by volume, of said grains, for example between 20 and 70% by volume, of said grains. Said melted grains comprise a zirconia-spinel eutectic matrix coating inclusions consisting essentially of a zirconia phase. The chemical composition of the grains comprises less than 92% ZrO 2, more preferably less than 90% ZrO 2. The chemical composition of the grains comprises more than 70% of ZrO 2, more preferably more than 72% of ZrO 2, even more than 75%, or even more than 80% of ZrO 2, or even more than 85% of ZrO 2. - The chemical composition of the grains comprises less than 20% Al 2 O 3, or even less than 18%, or even less than 15% or even less than 12% of Al 2 O 3. - The chemical composition of the grains comprises more than 7% of Al 2 O 3 or even more than 10% of Al 2 O 3. The chemical composition of the grains comprises less than 13% of MgO, or even less than 12% of MgO, or even less than 10% of MgO. The chemical composition of the grains comprises more than 2% MgO, even more than 4%, or even more than 5% or even more than 7%. The chemical composition of the melted grains according to the invention also comprises more 0.2% or more than 0.5% or more than 1.0% of Y203. The chemical composition of the melted grains according to the invention also comprises less than 4.0% or even less than 3.0% or even less than 2.0% of Y 2 O 3. The chemical composition of the melted grains according to the invention also comprises more than 0.2%, or even more than 0.5%, or even more than 1.0% of CaO. The chemical composition of the melted grains according to the invention also comprises less than 4.0% or even less than 3.0% or even less than 2.0% of CaO. The chemical composition of the melted grains according to the invention also comprises less than 2.0%, or even less than 1.5%, or even less than 1.0%, or even less than 0.5%, or even less than 0, 4% silica SiO2. - The melted grains comprise a zirconia phase, and a spinel phase, these two phases together representing more than 80%, preferably more than 90% or more than 95% of the weight of the grains according to the invention. The zirconia phase (s) comprise more than 90% by weight of ZrC equivalent> 2, or even more than 95% of ZrC> 2, or even more than 98% of ZrO 2. By "zirconia phases" is meant the sum of at least the zirconia present in the inclusions and the zirconia present in the eutectic. - The phase (s) zirconia inclusions further comprise more than 1% or more than 2% or more than 3% by weight of MgO. - The phase (s) zirconia inclusions is mainly or mainly in cubic form. By a majority, we mean more than 50% by weight, or even more than 60% by weight. By mainly means more than 80% weight or more than 90% weight. Said zirconia phase or phases represent more than 68%, even more than 70%, or even more than 80%, or even more than 85% or even more than 90% of the weight of the grains according to the invention. As previously described, the term "zirconia phases" means the sum of at least the zirconia present in the inclusions and the zirconia present in the eutectic. Said zirconia phase (s) represent less than 95% or even less than 92% or even less than 90% of the weight of the grains according to the invention, or even less than 85% or even less than 80% of the weight of the grains according to the invention. invention. - The spinel phase or phases represent more than 5% or even more than 7%, or even more than 10%, or even more than 15% or more than 20% of the weight of the grains according to the invention. By "spinel phases" is meant the sum of at least the spinel present in the eutectic and, if appropriate, the spinel present in the inclusions. - The spinel phase or phases represent less than 50%, or even less than 45%, or even less than 40% of the weight of the grains according to the invention. an additional phase of alumina is present and represents less than 5%, or even less than 3%, or even less than 1% of the weight of the grains according to the invention. an additional phase of magnesium oxide is present and represents less than 10% or even less than 5% or even less than 3% of the grains according to the invention.

The mass percentages as previously reported of the different crystalline phases present in the melted grains according to the invention, in particular of zirconia (in its various forms) and of spinel, can be conventionally measured by ray diffraction and Rietveld analysis.

A method of manufacturing molten grains according to the invention as described above, comprises the following steps: a) mixing of raw materials to form a feedstock, b) melting of the feedstock until a liquid is obtained melt, c) cooling said molten liquid so that the molten liquid is fully solidified to a solid mass, d) division, in particular by grinding, of said mass so as to obtain a mixture of grains.

According to the invention, steps c) and d) previously described are not necessarily performed in this order. The order of steps c) and d) depends in particular on the technique used to obtain the grains. For example, proceed first to step c), for example using CS molds as described in US Pat. No. 3,993,119, then in step d) in the case where the division of the melt consists of grinding. Alternatively, proceed first to step d) and then to step c) in the case where the division of the melt consists of a molding such as for example described in application WO2012 / 045302.

The raw materials are chosen in step a) so that the grains finally obtained are in accordance with the invention.

Any conventional process for producing molten grains may be implemented, provided that the composition of the feedstock makes it possible to obtain grains having a composition in accordance with that of the grains according to the invention. In step b), an electric arc furnace is preferably used, but all known furnaces are conceivable, such as an induction furnace or a plasma furnace, provided that they allow the initial charge to be completely melted. The firing is preferably carried out under neutral conditions, for example under argon, or oxidizing, preferably at atmospheric pressure. In step c), the molten liquid is preferably cooled slowly, for example in one to several hours, until a solid mass solid mass. In step d), the solid mass is ground according to conventional techniques, until a particle size suitable for its subsequent use is obtained.

Said feedstock may also include unavoidable impurities.

By "impurities" is meant inevitable constituents necessarily introduced with the raw materials or resulting from reactions with these constituents.

The impurities can in particular be introduced during the preliminary step of manufacturing the melted grains. Impurities are not necessary constituents, but only tolerated. It is considered that a total content of impurities of less than 2%, preferably less than 1%, does not substantially modify the results obtained.

The refractory products used according to the invention are advantageously obtained by sintering or consolidation of raw materials comprising or constituted by the melted grains previously described in the invention, said grains being sintered or consolidated together, in particular in the form of bricks, to constitute the refractory materials. constituents of the said products. The use of refractory materials or products according to the invention thus more particularly applies in the field of metallurgy, said products or materials being advantageously obtained by sintering or consolidation of raw materials comprising or consisting of melted grains previously described.

In an alternative mode the invention relates to a use of melted grains for the manufacture of refractory materials or products, in particular in the field of metallurgy, obtained by sintering or consolidation of raw materials comprising a zirconia powder and a powder of melted grains according to the invention. the invention, said zirconia powder and said powder of melted grains together representing more than 90% by weight of said raw materials, or even more than 95% by weight of said raw materials.

The following definitions are given:

Refractory material means, in accordance with ISO 836: 2001 (paragraph 107), a material or non-metallic product (but not excluding materials or products containing a certain proportion of metal), the chemical and physical properties of which allow its use in a high temperature environment.

For example, such high temperatures may be greater than 600 ° C., especially greater than 800 ° C., or even greater than 1000 ° C.

Zirconium oxide ZrC> 2 is generally referred to as "zirconia"; it most often comprises a small amount of hafnium oxide HfO 2, in the form of unavoidable impurity, this amount being up to 2% of the total amount of zirconia. In the overall chemical composition of the grains according to the invention, especially as previously described, the percentages "ZrCU" correspond in particular to the amount of zirconium oxide added and the unavoidable impurity HfO 2.

By contrast, the term "zirconia phase" or "zirconium oxide phase" refers to a phase consisting of zirconia (including unavoidable impurities, especially HfC> 2), or of zirconia which is partially or completely stabilized, in particular by magnesium or yttrium.

The term "spinel" refers to the compounds formed by the reaction between magnesium oxide and alumina, often expressed as MgAl 2 O 4, and whose crystallographic structure can be described as a cubic stack of O 2 - ions in which half of the octahedral sites are occupied by Al cations and a quarter of the tetrahedral sites occupied by Mg cations. Such a crystallographic structure can also accept an excess of Al or Mg cations in solid solution while remaining a "spinel" compound within the meaning of the present invention.

In other words, a spinel phase in a molten grain according to the present invention can depart substantially from the conventional MgAl 2 O 4 spinel formulation, i.e., a 1: 1 stoichiometry of the molar ratio of Al 2 O 3 to MgO.

A zirconia-spinel eutectic is a microstructure obtained from the corresponding eutectic point, in the pseudo-ternary ZrO 2 / MgAl 2 O 4 diagram, at a composition point close to 59 mol% of zirconia and 41 mol% of MgAl 2 O 4 spinel, and whose melting temperature is close to 1830 ° C. (invariant point of the phase diagram for which the liquid to solid reaction is complete).

The crystallographic structure of such a eutectic is visible on the two electron microscopy photos reported in Figures 1 and 2 attached.

FIG. 1 is a first electronic microscopy snapshot of the microstructure of a molten grain used according to the invention.

Figure 2 is a first electron microscopy microstructure of the same molten grain as in Figure 1, but at higher magnification. At very high magnification (FIG. 2), it is observed that the matrix made of the preceding eutectic composition and having a crystallographic structure, the zirconia phase is dispersed very finely, in the form of rods or fibers, in the spinel phase. Such a structure is characteristic of a eutectic phase obtained from two crystalline types.

"Melted grains" are grains obtained by a manufacturing process comprising at least one melting step, a solidification step and a dividing step, in particular by grinding, molding or any other equivalent known means. The use according to the invention is generally implemented from a powder consisting of a set of grains as described above, whose particle size is suitable for the manufacture of said refractory material.

The term "melting" of a mixture of precursors or oxides, a heat treatment at a sufficiently high temperature so that all the constituents of the mixture are found in the molten state (liquid).

Conventionally in the field of ceramics, the term "sintering" of a set of grains, a heat treatment allowing the junction and the development of their contact interfaces by movement of the atoms inside and between the grains, in the sense indicated in ISO 836: 2001 (paragraph 120).

The sintering temperature of the melted grains is normally between 1100 ° C. and 1500 ° C., in particular between 1300 ° and 1500 ° C.

Alternatively, consolidation means a thermal treatment of the grains at a more moderate temperature specific to the simple shaping of a ceramic part, without however strong bonds between the grain interfaces, as opposed to the sintering method previously described, the connection which can be provided by a binder, for example a phenolic resin.

The consolidation temperature of the melted grains is normally between 500 ° C. and 1100 ° C., in particular between 600 ° C. and 1000 ° C.

The size of the grains is measured according to the well-known techniques of laser granulometry up to 20 micrometers and then by conventional sieving techniques beyond 20 micrometers. The invention and its advantages will be better understood on reading the following nonlimiting examples. In the examples, all percentages are given by weight.

Examples: Comparative Example 1 is a zirconia powder partially stabilized with magnesium oxide. This example is characteristic of the raw materials used today for the manufacture of refractory elements in the field of metallurgy, in particular for the casting of steels. Comparative Example 2 is a mixture of the partially stabilized zirconia powder used in Example 1 with a spinel powder comprising about 72% Al 2 O 3 and 28% MgO.

Examples 3 and 4 according to the invention are prepared from the necessary proportions of the following raw materials: AR75 alumina containing more than 98% of Al2C 3, marketed by Alcan, MgO marketed by Altichem, comprising more 98% MgO, - Zirconia with a purity level greater than 98%.

The mixture of the initial reactants thus obtained is electro-fired in an electric arc furnace, under air. The molten mixture is cast in ingot. The cooled ingot obtained is crushed and sieved to obtain a powder of melted grains whose diameter is similar to that of the powders used in Examples 1 and 2.

The samples according to Examples 1 to 4 are then analyzed. The overall chemical composition of the grains, indicated in weight percentages on the basis of the oxides, was determined by X-ray fluorescence. The results are summarized in Table 1 which follows.

Table 1 The qualitative analysis of the phases present in the grains according to Examples 1 to 4 is then determined by X-ray diffraction. The results are summarized in Table 2 which follows:

Table 2

The temperature resistance is evaluated by comparing the detected phases before and after having placed the samples of Examples 1 to 4 for 1 hour at 1400 ° C., that is to say at a temperature below the minimum sintering temperature described in FIG. patent application CN101786889, paragraph [0012].

Such conditions also appear to be representative of the conditions experienced by a material

made from different grains during its use in particular as a refractory piece in metallurgy.

As indicated above, the temperature resistance of said material is related to the rate of transformation of the zirconia phase from the cubic or tetragonal form to the monoclinic form during a cycle comprising a rise and a fall in temperature, this transformation resulting in a known manner. microcracking constituent grains of the material and therefore a degradation of the macroscopic properties thereof, as explained above.

More precisely, for each example, the amount of monoclinic zirconia before and after the test is determined by X-ray diffraction. The results are summarized in Table 3 which follows.

Table 3

The results reported in Table 3 show that the melted grains used according to the invention have a very improved stability compared to the comparative examples. By reducing the phase changes, in particular the passage of cubic zirconia or tetragonal zirconia monoclinic, avoids the associated dimensional variations and thus the risk of cracking refractory products comprising or constituted by these grains.

The microstructure of the grains obtained according to Example 4 was observed by electron microscopy.

The composition of the different phases constituting the grains can be obtained by spectrometry of wavelength (microprobe of Castaing ΕΡΜΑ). This measurement makes it possible to confirm the visual observations and to specify the compositions of the various phases and inclusions observed on the electron microscope slides of FIGS. 1 and 2.

The images are shown in Figures 1 and 2. The microstructure, very different from those observed so far on grains obtained by sintering in the solid state, has two very different regions and perfectly observable under the microscope: - A matrix (1 ) having an alternating arrangement of zirconia phase and spinel phase, in the form of fibers or rods of very small thickness. This very fine structure is characteristic of a eutectic phase obtained from two crystalline types. - Occlusions (2) of a zirconia phase, embedded in said matrix of eutectic.

Without this explanation being considered definitive, the stabilization of the zirconia observed could therefore be related to this particular microstructure obtained thanks to the overall chemical composition of the various oxides as described above and in particular to the presence of the eutectic phase ZrCt. -Spinel surrounding occlusions of zirconia or spinel, preferably zirconia. Thanks to such a microstructure, it becomes possible to use materials comprising very high levels of zirconia for the manufacture of refractory materials.

Claims (12)

1. Use of melted grains for the manufacture of refractory materials, in which: said grains comprise a matrix of the zirconia-spinel eutectic coating inclusions consisting essentially of a zirconia phase or a spinel phase, said grains presenting the following overall chemical composition, in percentages by weight expressed as oxides: o more than 45.0% and less than 95.0% Zr02, o more than 3.0% and less than 40.0% Al203 o more than 1.0% and less than 20.0% of MgO, ZrO 2, Al 2 O 3 and MgO together represent at least 95.0% by weight of said grains. 2. Use of melted grains according to claim 1 for the manufacture of refractory materials for metallurgy. 3. Use of fused grains according to one of the preceding claims for the manufacture of refractory materials, especially for metallurgy, said material being obtained by sintering raw materials comprising said melted grains or constituted by said melted grains. 4. Use of fused grains according to one of the preceding claims for the manufacture of refractory materials including metallurgy, said material being obtained by consolidation of raw materials comprising said melted grains or constituted by said melted grains. 5. Use of melted grains according to one of the preceding claims for the manufacture of refractory materials or products especially in the field of metallurgy, obtained by sintering or consolidation of raw materials comprising a zirconia powder and a powder of said melted grains, said zirconia powder and said powder of fused grains together accounting for more than 90% weight of said raw materials. 6. Use of melted grains according to one of the preceding claims, wherein the chemical composition of the melted grains comprises more than 68% by weight of ZrC> 2. 7. Use of melted grains according to one of the preceding claims, wherein the chemical composition of the melted grains comprises less than 25% by weight of Al 2 O 3. 8. Use of melted grains according to one of the preceding claims, wherein the weight ratio Al203 / Mg0 in the melted grains is between 1.0 and 5.0, preferably is between 1.5 and 3. 9. Use of melted grains according to one of the preceding claims, wherein ZrO 2, Al 2 O 3 and MgO together represent more than 98.0% of the weight of said grains. Use of molten grains according to one of the preceding claims, wherein said melted grains further comprise on the oxide basis more than 0.2% and less than 4% by weight of Y 2 O 3. 11. Use of melted grains according to one of the preceding claims, wherein said melted grains further comprise, on the oxide basis, more than 0.2% and less than 4% by weight of CaO. 12. Use of melted grains according to one of the preceding claims, wherein the spinel phase is between 5% and 50% by weight of said grains.