FR3036855B1 - COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY - Google Patents

COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY Download PDF

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Publication number
FR3036855B1
FR3036855B1 FR1554831A FR1554831A FR3036855B1 FR 3036855 B1 FR3036855 B1 FR 3036855B1 FR 1554831 A FR1554831 A FR 1554831A FR 1554831 A FR1554831 A FR 1554831A FR 3036855 B1 FR3036855 B1 FR 3036855B1
Authority
FR
France
Prior art keywords
sofc
fuel cell
burner
natural gas
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1554831A
Other languages
French (fr)
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FR3036855A1 (en
Inventor
Pierre Dumoulin
Stephane Colasson
Guillaume Montzieux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1554831A priority Critical patent/FR3036855B1/en
Priority to PCT/EP2016/062087 priority patent/WO2016189162A2/en
Publication of FR3036855A1 publication Critical patent/FR3036855A1/en
Application granted granted Critical
Publication of FR3036855B1 publication Critical patent/FR3036855B1/en
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04037—Electrical heating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04059—Evaporative processes for the cooling of a fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074—Heat exchange unit structures specially adapted for fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04291—Arrangements for managing water in solid electrolyte fuel cell systems
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04302—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

La présente invention concerne une installation (1) de cogénération de chaleur et d'électricité comprenant : -une pile à combustible (SOFC) (2); -un brûleur (3) pour brûler les gaz imbrûlés dans la pile, -une ligne d'alimentation en méthane (4), reliée à l'entrée d'anode de la pile SOFC; -une ligne d'alimentation en eau (5) reliée à l'entrée d'anode de la pile SOFC ; -une ligne d'alimentation en air ambiant (6), en tant que comburant de la pile SOFC, reliée à l'entrée de cathode de la pile SOFC; -une ligne d'évacuation des gaz (7) à la sortie d'anode de la pile SOFC, reliée à l'entrée du brûleur ; -une ligne d'alimentation en air ambiant (8), en tant que comburant du brûleur, reliée à l'entrée du brûleur; -une ligne d'évacuation de l'air (9) à la sortie de cathode de la pile SOFC, débouchant dans l'air ambiant.The present invention relates to an installation (1) for the cogeneration of heat and electricity comprising: a fuel cell (SOFC) (2); -a burner (3) for burning the unburned gases in the cell, -a methane supply line (4), connected to the anode inlet of the SOFC cell; -a water supply line (5) connected to the anode input of the SOFC stack; -an ambient air supply line (6), as oxidizer of the SOFC stack, connected to the cathode inlet of the SOFC stack; -a gas evacuation line (7) at the anode outlet of the SOFC stack, connected to the inlet of the burner; -an ambient air supply line (8), as burner oxidizer, connected to the burner inlet; -an air evacuation line (9) at the cathode outlet of the SOFC stack, opening out into the ambient air.

FR1554831A 2015-05-28 2015-05-28 COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY Active FR3036855B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1554831A FR3036855B1 (en) 2015-05-28 2015-05-28 COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY
PCT/EP2016/062087 WO2016189162A2 (en) 2015-05-28 2016-05-27 Combined heat and power plant comprising a natural-gas-fuelled sofc fuel-cell stack, which is easier to start-up and safer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1554831A FR3036855B1 (en) 2015-05-28 2015-05-28 COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY

Publications (2)

Publication Number Publication Date
FR3036855A1 FR3036855A1 (en) 2016-12-02
FR3036855B1 true FR3036855B1 (en) 2022-01-07

Family

ID=53758431

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1554831A Active FR3036855B1 (en) 2015-05-28 2015-05-28 COGENERATION INSTALLATION INCLUDING A SOFC FUEL CELL OPERATING ON NATURAL GAS, EASIER START-UP AND INCREASED SAFETY

Country Status (2)

Country Link
FR (1) FR3036855B1 (en)
WO (1) WO2016189162A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109140227B (en) * 2018-11-13 2024-03-08 中国石油集团工程股份有限公司 Small LNG distributed energy system and process method

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002005363A2 (en) * 2000-07-10 2002-01-17 Global Thermoelectric Inc. Integrated module for solid oxide fuel cell systems
DE10310642A1 (en) * 2003-03-12 2004-09-23 Forschungszentrum Jülich GmbH High temperature fuel cell system in modular structure with planar cell stack and at least one component, e.g. after burner, reformer and heat exchanger, which is fitted directly on side of cell stack
US7732084B2 (en) * 2004-02-04 2010-06-08 General Electric Company Solid oxide fuel cell with internal reforming, catalyzed interconnect for use therewith, and methods
US7659022B2 (en) * 2006-08-14 2010-02-09 Modine Manufacturing Company Integrated solid oxide fuel cell and fuel processor
JP5154030B2 (en) * 2006-05-18 2013-02-27 本田技研工業株式会社 Fuel cell system and operation method thereof
FR2909224B1 (en) * 2006-11-24 2010-09-24 Gaz De France ENERGY PRODUCTION UNIT INCORPORATING A BURNER AND A FUEL CELL.
FR2944094A1 (en) * 2009-04-07 2010-10-08 Dietrich Thermique CO-GENERATION SYSTEM AND INSTALLATION USING FUEL CELL FOR HEATING AND HOT WATER PRODUCTION
JP6167477B2 (en) * 2012-06-13 2017-07-26 日産自動車株式会社 Fuel cell system

Also Published As

Publication number Publication date
WO2016189162A2 (en) 2016-12-01
FR3036855A1 (en) 2016-12-02
WO2016189162A3 (en) 2017-01-26

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