FR3015258A1 - SOLID COMPOSITION WITH CARBOSILOXANE DENDRIMER VINYLIC POLYMER, HYDROCARBONIC VOLATILE OILS AND PROCESSING METHOD - Google Patents

Abstract

The present invention relates to an anhydrous, solid cosmetic composition comprising: a) at least one vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer; b) at least two volatile hydrocarbon oils. It also relates to a makeup process and / or care of the lips in which is applied to the lips, the above composition.

Description

The subject of the present invention is a composition in the form of a solid, anhydrous cosmetic composition comprising a particular film-forming polymer, at least two volatile oils, and a composition comprising at least two volatile oils. hydrocarbon, and a method of makeup and / or care of the lips implementing it. The solid cosmetic make-up and / or skincare and / or lip care compositions must fulfill several conditions concerning their mechanical characteristics, and obviously concerning their performance at the time of application of the composition, as well as their evolution at the course of time once the composition is in place. Thus, the solid care and / or make-up compositions generally contain one or more fatty substances structured by a "structuring" or "gelling" agent, conventionally a wax or a polymer, to improve the rigidity of the compositions and in particular to obtain solid compositions, preferably in the form of rods, which remain stable. Of course, the dosage form of these compositions must meet the requirements on the one hand of mechanical order to ensure the sliding and holding rod during application and prevent it breaks and other on the other hand, transfer qualities to ensure a comfortable application as well as a sufficient deposit and good quality on the lips. In addition, the deposited film must be sufficiently thin, non-sticky and must not be greasy or cause feelings of tightness. It must finally have an appropriate level of gloss and have good performance.

It is known to use in cosmetic compositions, vinyl polymers having at least one unit derived from carbosiloxane dendrimer, the presence of which improves the holding of the deposited film. The raw material is available in the form of a mixture in a volatile oil, silicone or hydrocarbon. The solid anhydrous compositions prepared comprising this film-forming polymer usually contain a volatile silicone oil, a volatile hydrocarbon oil or the mixture of these two oils. However, it was found at the application that the slipperiness of the composition could be further improved as well as the comfort of the deposit thus obtained. The present invention therefore aims to solve the disadvantages described above.

These objects are achieved by the present invention which therefore relates to an anhydrous, solid cosmetic composition, comprising: a) at least one vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer; b) at least two volatile hydrocarbon oils.

It also relates to a makeup process and / or care of the lips in which is applied to the lips, the above composition. The composition according to the invention has the advantage of being slippery and very easy to apply. It delivers a thin film, homogeneous, non-greasy and non-sticky composition, which remains comfortable after application. The deposit is also good. The present invention will appear more clearly on reading the description and examples which follow.

Note that in the following description, unless otherwise indicated, the terminals indicated for a domain are included in this area. The expressions "at least one" and "several" are used interchangeably. By "anhydrous" is meant in particular that the water is preferably not added deliberately in the compositions but may be present in trace amounts in the various compounds used in the compositions. The temperatures indicated below are indicated at atmospheric pressure (1.013, 105 Pa). The cosmetic composition according to the invention is a composition intended more particularly for the make-up and / or care of the skin, lips. Preferably, the composition according to the invention is intended for makeup and / or care of the lips, and even more preferably for lip makeup. As indicated above, the composition according to the invention is in a solid form. In particular, it can be in the form of a stick (stick, pen) or in a molded form in a cup or in a pot.

Preferably, it is a balm for the lips and / or a lipstick, being even more preferably in the form of a stick (stick). Note that in the following description, unless otherwise indicated, the terminals indicated for a domain are included in this area.

The expressions "at least one" and "several" are used interchangeably. By "anhydrous" is meant in particular that the water is preferably not added deliberately in the compositions but may be present in trace amounts in the various compounds used in the compositions. The cosmetic composition according to the invention is a composition intended more particularly for the make-up and / or care of the skin, lips. Preferably, the composition according to the invention is intended for makeup and / or care of the lips, and even more preferably for lip makeup.

As indicated above, the composition according to the invention is in a solid form. In particular, it can be in the form of a stick (stick) or in a molded form in a cup or in a pot. Preferably, it is a lip balm and / or a lipstick, being even more preferably in the form of a stick (stick). The hardness of the composition is measured according to the following protocol: Protocol for measuring the hardness The lipstick is stored at 20 ° C. for 24 hours before measuring the hardness.

The hardness can be measured at 20 ° C. by the so-called "butter-cutting thread" method, which consists in transversely cutting a stick of product, preferably cylindrical of revolution, with the aid of a rigid tungsten wire. diameter 250 lm by moving the wire relatively to the stick at a speed of 100 mm / min. The hardness of the samples of compositions of the invention, expressed in Nm-1, is measured by means of a DFGS2 dynamometer marketed by INDELCOCHATILLON. The measurement is repeated three times and averaged. The average of the three values read using the dynamometer mentioned above, denoted Y, is given in grams. This average is converted to Newton and then divided by L which represents the highest dimension traversed by the wire. In the case of a cylindrical stick, L is equal to the diameter (in meters). The hardness is converted to Nm-1 by the following equation: (Y x 10-3 x 9.8) / L For measurement at a different temperature, the stick is held for 24 hours at this new temperature before measurement. According to this measurement method, the composition according to the invention advantageously has a hardness at 20 ° C and at atmospheric pressure, greater than or equal to 40 Nm-1. In a particular embodiment, the hardness at 20 ° C. and at atmospheric pressure is greater than or equal to 60 Nm -1. Preferably, the composition according to the invention has a hardness at 20 ° C, less than 500 Nm-1 especially less than 400 Nm-1, preferably less than 300 Nm-1. Preferably, the composition has a hardness of between 60 and 150 Nm-1. VINYL POLYMER / CARBOSILOXANE DENDRIMER (S) PATTERN As indicated above, the composition according to the invention comprises at least one vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer. The vinyl polymer (s) have a backbone and at least one side chain, which comprises a carbosiloxane dendrimer derived unit having a carbosiloxane dendrimer structure. The term "carbosiloxane dendrimer structure" in the context of the present invention represents a molecular structure having branched groups having high molecular weights, said structure having a high regularity in the radial direction from the skeleton bond. Such carbosiloxane dendrimer structures are described in the form of a highly branched siloxane-silylalkylene copolymer in Japanese Patent Application JP 9-171,154. A vinyl polymer according to the invention may contain units derived from carbosiloxane dendrimers which may be represented by the following general formula (I): wherein R 1 represents an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms; carbon; X 'represents a silylalkyl group which, when i = 1, is represented by the formula (II): (OR3) al R2 Si R1 O Si X "R' 3-a '(II) in which: Ri is such as defined above in the formula (I), R2 represents an alkylene radical of 2 to 10 carbon atoms, R3 represents an alkyl group of 1 to 10 carbon atoms, X1 + 1 is chosen from: an atom of hydrogen, an alkyl group of 1 to 10 carbon atoms, an aryl group of 5 to 10 carbon atoms and a silylalkyl group defined above of formula (II) with i = i + 1, i is a whole number from 1 to 10 which represents the generation of said silylalkyl group, and a 'is an integer from 0 to 3; Y represents a radically polymerizable organic group selected from: organic groups containing a methacrylic group or an acrylic group said organic groups being represented by the formulas: R 4 O R 4 II II or H 2 C = CC-O-R 5-2 H in which: R 4 represents n hydrogen atom or an alkyl group of 1 to 10 carbon atoms; and R 5 represents an alkylene group of 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group, or a butylene group, with methylene and propylene groups being preferred; and. styryl-containing organic groups of the formula: wherein: R 6 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms, such as a methyl group, an ethyl group, a propyl group, or a butyl group, the methyl group being preferred; R7 represents an alkyl group of 1 to 10 carbon atoms; R8 represents an alkylene group of 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group, a butylene group, the ethylene group being preferred; * b is an integer from 0 to 4; and * c is 0 or 1, so that if c is 0, - (R), - represents a bond. In one embodiment, R 'may be an aryl group having 5 to 10 carbon atoms or an alkyl group having 1 to 10 carbon atoms. The alkyl group may preferably be methyl, ethyl, propyl, butyl, pentyl, isopropyl, isobutyl, cyclopentyl or cyclohexyl. The aryl group may preferably be represented by a phenyl group and a naphthyl group. The methyl and phenyl groups are more particularly preferred, and the methyl group is most preferred. According to one embodiment, R2 represents an alkylene group having 2 to 10 carbon atoms, especially a linear alkylene group, such as an ethylene, propylene, butylene or hexylene group; or a branched alkylene group, such as a methylmethylene, methylethylene, 1-methylpentylene or 1,4-dimethylbutylene group. ## STR2 ## Ethylene, methylethylene, hexylene, 1-methylpentylene and 1,4-dimethylbutylene are most preferred. According to one embodiment, R3 is chosen from methyl, ethyl, propyl, butyl and isopropyl groups.

In formula (II), i indicates the number of generations and thus corresponds to the number of repetitions of the silylalkyl group. For example, when the number of generations is equal to one, the carbosiloxane dendrimer may be represented by the general formula shown below, wherein Y, R 1, R 2 and R 3 are as defined above, R '2 represents a hydrogen atom or is identical to R1; a 'is identical to a'. Preferably, the total average number of OR3 groups in a molecule is in the range of 0 to 7. R1 (OR3) R1 I 2 I 12 Y-Si O-Si-R Si R Si O R1 3-a1 3 When number of generations is equal to 2, the carbosiloxane dendrimer may be represented by the general formula below, wherein Y, R 1, R 2, R 3 and R '2 are the same as defined above; a 'and a2 represent the a' of the indicated generation. Preferably, the total average number of OR3 groups in a molecule is in the range of from 0 to 25. 1 (OR 3) I 2 al O-Si-R Si R 1 (OR 3) 2 ORI 2 1 a Si Si R 1 R 1 O Si In the case where the number of generations is equal to 3, the carbosiloxane dendrimer is represented by the general formula below, in which Y, R 1, R 2, R 3 and R '2 are the same as defined above; al, a2 and a3 represent the a 'of the indicated generation. Preferably, the total average number of OR3 groups in a molecule is in the range of 0 to 79. YS R 1 (OR 3) I 2 1 a 2 O Si R Si R 1 R 1 (OR 3) R 12 a 3 SiR 'R Si 0 If a vinyl polymer having at least one unit derived from a carbosiloxane dendrimer has a side molecular chain containing a carbosiloxane dendrimer structure, and may be derived from the polymerization of (A) 0 to 99.9 parts by weight of a vinyl monomer; and (B) from 100 to 0.1 parts by weight of a radical-polymerizable organic group-containing carbosiloxane dendrimer represented by the general formula (I) as defined above. The vinyl monomer component (A) in the vinyl polymer having at least one carbosiloxane dendrimer-derived unit is a vinyl-type monomer which contains a radical-polymerizable vinyl group. There is no particular limitation with respect to such a monomer. The following are examples of this vinyl type monomer: methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, or a lower alkyl analogue methacrylate; glycidyl methacrylate; butyl methacrylate, butyl acrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate , 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, octyl methacrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, or a higher analogous methacrylate; vinyl acetate, vinyl propionate, or a lower analogous fatty acid vinyl ester; vinyl caproate, vinyl 2-ethylhexoate, vinyl laurate, vinyl stearate, or a higher analogous fatty acid ester; styrene, vinyltoluene, benzyl methacrylate, phenoxyethyl methacrylate, vinylpyrrolidone, or analogous aromatic vinyl monomers; methacrylamide, N-methylolmethacrylamide, N-methoxymethylmethacrylamide, isobutoxymethoxymethacrylamide, N, N-dimethylmethacrylamide, or analogous vinyl monomers which contain amide groups; hydroxyethyl methacrylate, hydroxypropyl alcohol methacrylate, or vinyl-like monomers which contain hydroxyl groups; acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, or vinyl-like monomers which contain a carboxylic acid group; tetrahydrofurfuryl methacrylate, butoxyethyl methacrylate, ethoxydiethyleneglycol methacrylate, polyethyleneglycolmethacrylate, polypropyleneglycol-1 (OR 3) 1 O-Si-R Si R 'Y-Si monomethacrylate, hydroxybutyl ether and vinyl, cetyl vinyl ether, 2-ethylhexyl vinyl ether, or a vinyl-like monomer with ether linkages; methacryloxypropyltrimethoxysilane, polydimethylsiloxane having a methacrylic group on one of its molecular ends, polydimethylsiloxane having a styryl group on one of its molecular ends, or a silicone-like compound having unsaturated groups; butadiene; vinyl chloride; vinylidene chloride; methacrylonitrile; dibutylfumarate; anhydrous maleic acid; anhydrous succinic acid; methacryl ether and glycidyl ether; an organic salt of an amine, an ammonium salt, and an alkali metal salt of methacrylic acid, itaconic acid, crotonic acid, maleic acid, or fumaric acid ; an unsaturated monomer polymerizable with radicals having a sulfonic acid group such as a styrene sulfonic acid group; a quaternary ammonium salt derived from methacrylic acid such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride; and an ester of methacrylic acid of an alcohol having a tertiary amine group such as an ester of methacrylic acid and diethylamine. The multifunctional vinyl-type monomers can also be used. The following are examples of such compounds: trimethylolpropane trimethacrylate, pentaerythritol trimethacrylate, ethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butanediol dimethacrylate, dimethacrylate of 1,6 hexanediol, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl methacrylate, tris- (2-hydroxyethyl) isocyanurate dimethacrylate, tris- (2-hydroxyethyl) isocyanurate trimethacrylate, styryl-capped polydimethylsiloxane having divinylbenzene groups on two ends, or analogous silicone compounds having unsaturated groups. A carbosiloxane dendrimer, which is the component (B), can be represented by the formula (I) as defined above. The following is the preferred examples of group Y of formula (I): acryloxymethyl group, 3-acryloxypropyl group, methacryloxymethyl group, 3-methacryloxypropyl group, 4-vinylphenyl group, 3-vinylphenyl group, a 4- (2-propenyl) phenyl group, a 3- (2-propenyl) phenyl group, a 2- (4-vinylphenyl) ethyl group, a 2- (3-vinylphenyl) ethyl group, a vinyl group, a allyl, a methallyl group, and a 5-hexenyl group. A carbosiloxane dendrimer according to the present invention may be represented by the following average structural formulas: ## STR2 ## 3 CH 3 O-Si-CH, CH 3 H 2 C = CH-C-O-C 3 HSi 0 3 3 CH, CH 3 CH 3 H 2 C = CC-O-C 3 HSi CH 3 I 3 Ol 1 -C 2 H 47 Si-Ol 1 -C 2 H 47 Si CH 3 CH 3 CH 3 1-12C = CC-O-C31-1Si o H3 O- i-05H12 Si CH3 CH3O-Si-CH CH3 _3 3 CHI 3 Î 8H17 0-S1 Oli-C81-117 CH3 3 _3 CH 3 1-12C = CC-O-C 31 -Si 3 -CH 3 CH 3 CH 3 CH 3 CH 3 Cl 3 Or-C21-17, wherein CH3 CH3 CH3 CH3 CH3 CH3I H2C = CCNC "H-Si I-CH3 II H CH3 CH, 3 o_3 Y-Si R1 (OR3) If R 2 I 2 I R 1 (OR 3) O-Si-R 1 R 1 Si O Si R 1 (O Si R 2 Si O-Si-R 2 C 3 R 1 1 LII R 1 3-a 3 -α 2 3-a 1 3 CH I 3 i -CH 3 CH 3 CH 3 CH 3 CH 3 H 3 CH 3 CH 3 CH 3 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 -CH, CH 3 CH 3 CH 3) 3 (O Me) CH, 1.1 CH, O-1-C 2 H 0. Si 0 Si-CH I 3 CH 3 CH 3 1.9 (OMe) CH 3 1 0.5 I 3 O-Si-C24 H Si 0 Si-CH3 ## STR2 ## wherein ## STR1 ## Thus, in one embodiment, the following are provided: ## STR1 ## wherein: ## STR2 ## embodiment, the carbosiloxane dendrimer of the composition according to the present invention is represented by the following formula: I Si 2 R (OR 3) R 1 2 R (OR 3) 3 to R 1 R 12 R 1 a 2 Si Si R 1 R 1 Si O Si 0 3- a3 3-a2 3-a1 3 Y-Si R 1 (OR 3) I 2 O-Si-R Si O in which: Y, R 1, R 2 and R 3 are as defined in formulas (I) and (II) above; . al, a2 and a3 are as defined in formula (II); and. Ru 'is H, an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms. According to one embodiment, the carbosiloxane dendrimer of the composition according to the present invention is represented by one of the following formulas: ## STR1 ## The vinyl polymer comprising the carbosiloxane dendrimer according to the invention can be manufactured according to the process for producing a branched silalkane siloxane described in US Pat. No. 3,170,159. Japanese Patent Hei 9-171 154.

For example, it can be produced by subjecting a hydrosilylation reaction to an organosilicon compound which contains a hydrogen atom connected to a silicon atom represented by the following general formula (IV): Y-Si 0-Si-H R 1 3 (IV) R 1 being as defined above in formula (I), and an organosilicon compound which contains an alkenyl group. In the above formula, the organosilicon compound may be represented by 3-methacryloxypropyltri-s (dimethyl siloxy) silane, 3-acryloxypropyltri-s (dimethyl siloxy) silane, and 4-vinylphenyltris- (dimethylsiloxy) silane. The organosilicon compound which contains an alkenyl group may be represented by vinyltris- (trimethylsiloxy) silane, vinyltris- (dimethylphenylsiloxy) silane, and 5-hexenyltri s- (trimethyl siloxy) silane. The hydrosilylation reaction is carried out in the presence of a chloroplatinic acid, a vinylsiloxane and platinum complex, or a transition metal-like catalyst.

A vinyl polymer having at least one unit derived from a carbosiloxane dendrimer may be chosen from polymers such that the unit of a derivative of a carbosiloxane dendrimer is a carbosiloxane dendritic structure represented by the formula (III): R 1 O-Si-X 3 (III) wherein Z is a divalent organic group, "p" is 0 or 1, R 1 is as defined above in formula (IV) and X 'is a silylalkyl group represented by formula (II) as as defined above.

In a vinyl polymer having at least one unit derived from a carbosiloxane dendrimer, the ratio of polymerization between components (A) and (B), in terms of weight ratio between (A) and (B), is in a range of 0 / 100 to 99.9 / 0.1, or even 0.1 / 99.9 to 99.9 / 0.1, and preferably in a range of 1/99 to 99/1. A ratio between components (A) and (B) of 0/100 means that the compound becomes a homopolymer of component (B). A vinyl polymer having at least one unit derived from carbosiloxane dendrimer can be obtained by the copolymerization of the components (A) and (B), or by the polymerization of the single component (B). The polymerization may be free-radical polymerization or ionic polymerization, however radical polymerization is preferred. The polymerization can be carried out by causing a reaction between components (A) and (B) in a solution for a period of 3 to 20 hours in the presence of a radical initiator at a temperature of 50 ° C to 150 ° C. A suitable solvent for this purpose is hexane, octane, decane, cyclohexane, or a similar aliphatic hydrocarbon; benzene, toluene, xylene, or a similar aromatic hydrocarbon; diethyl ether, dibutyl ether, tetrahydrofuran, dioxane, or ethers; acetone, methyl ethyl ketone, methyl isobutyl ketone, di-isobutyl ketone, or similar ketones; methyl acetate, ethyl acetate, butyl acetate, isobutyl acetate, or analogous esters; methanol, ethanol, isopropanol, butanol, or similar alcohols; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexamethyldisiloxane, octamethyltrisiloxane, or a similar organosiloxane oligomer. A radical initiator may be any compound known in the art for conventional radical polymerization reactions. Specific examples of such radical initiators are 2,2'-azobis (isobutyronitrile), 2,2'-azobis (2-methylbutyronitrile), 2,2'-azobis (2,4-dimethylvaleronitrile) or compounds azobic analogues; benzoyl peroxide, lauroyl peroxide, tert-butyl peroxybenzoate, tert-butyl peroxy-2-ethylhexanoate, or a similar organic peroxide. These radical initiators can be used alone or in a combination of two or more. The radical initiators can be used in an amount of 0.1 to 5 parts -Eztsi by weight per 100 parts by weight of the components (A) and (B). A chain transfer agent can be added. The chain transfer agent may be 2-mercaptoethanol, butyl mercaptan, n-dodecyl mercaptan, 3-mercaptopropyltrimethoxysilane, a polydimethylsiloxane having a mercaptopropyl group or a mercapto-like compound; methylene chloride, chloroform, carbon tetrachloride, butyl bromide, 3-chloropropyltrimethoxysilane, or a similar halogenated compound. In the manufacture of the vinyl polymer, after the polymerization, the unreacted residual vinyl monomer can be removed under vacuum heating conditions.

To facilitate the preparation of raw material for cosmetics, the number average molecular weight of the vinyl polymer which contains a carbosiloxane dendrimer may be selected in the range of from 3,000 to 2,000,000, preferably from 5,000 to 800,000. It can be a liquid, an eraser, a paste, a solid, a powder, or any other form. Preferred forms are solutions consisting of dilution in solvents, a dispersion, or a powder. The vinyl polymer may be a dispersion of a vinyl polymer having a carbosiloxane dendrimer structure in its side molecular chain, in a liquid such as a silicone oil, an organic oil, an alcohol, or water. The silicone oil may be a dimethylpolysiloxane having both trimethylsiloxy-terminated molecular ends, a copolymer of methylphenylsiloxane and dimethylsiloxane having both trimethylsiloxy-capped molecular ends, a methyl-3,3,3-trifluoropropylsiloxane copolymer and dimethylsiloxane having both trimethylsiloxy-terminated molecular ends, or analogous non-reactive linear silicone oils, as well as hexamethylcyclotrisiloxane, octamethylcyclo-tetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, or a similar cyclic compound. In addition to the nonreactive silicone oils, modified polysiloxanes having functional groups such as silanol groups, amino groups, and polyether groups on the ends or within the side molecular chains may be used. The organic oils may be isododecane, paraffin oil, isoparaffin, hexyl laurate, isopropyl myristate, myristyl myristate, cetyl myristate, 2-octyldodecyl myristate; isopropyl palmitate, 2-ethylhexyl palmitate, butyl stearate, decyl oleate, 2-octyldodecyl oleate, myristyl lactate, cetyl lactate, lanolin acetate, stearic alcohol, cetostearyl alcohol, oleic alcohol, avocado oil, almond oil, olive oil, cocoa oil, jojoba oil, gum, sunflower oil, soybean oil, camellia oil, squalane, castor oil, cottonseed oil, coconut oil, yellow oil egg, polypropylene glycol monooleate, neopentyl glycol 2-ethylhexanoate, or a similar glycol ester oil; triglyceryl isostearate, triglyceride of a coconut oil fatty acid, or a similar polyhydric alcohol ester oil; polyoxyethylene lauryl ether, polyoxypropylene cetyl ether, or a similar polyoxyalkylene ether.

The alcohol may be of any type suitable for use in conjunction with a raw material of cosmetics. For example, it may be methanol, ethanol, butanol, isopropanol or lower alcohols. A solution or dispersion of the alcohol should have a viscosity in the range of 10 to 109 mPa at 25 ° C. To improve the feel properties of use in a cosmetic product, the viscosity should be in the range of 100 to 5 x 108 mPa.s. The solutions and dispersions can easily be prepared by mixing a vinyl polymer having at least one carbosiloxane dendrimer derived unit, a silicone oil, an organic oil, an alcohol, or water. The liquids may be present in the polymerization step. In this case, the unreacted residual vinyl monomer should be completely removed by heat treatment of the solution or dispersion under atmospheric or reduced pressure. In the case of a dispersion, the dispersity of the vinyl polymer can be improved by adding a surfactant. Such an agent may be hexylbenzenesulfonic acid, octylbenzenesulfonic acid, decylbenzenesulfonic acid, dodecylbenzenesulfonic acid, cetylbenzenesulfonic acid, myristylbenzenesulfonic acid, or anionic surfactants of the salts. sodium of these acids; octyltrimethylammonium hydroxide, dodecyltrimethylammonium hydroxide, hexadecyltrimethylammonium hydroxide, octyldimethylbenzylammonium hydroxide, decyl dimethylbenzylammonium hydroxide, dioctadecyl dimethyl ammonium hydroxide, hydroxide beef-trimethylammonium tallow, coconut trimethylammonium oil hydroxide, or a similar cationic surfactant; a polyoxyalkylene alkyl ether, a polyoxyalkylene alkylphenol, a polyoxyalkylene alkyl ester, polyoxyalkylene sorbitol ester, polyethylene glycol, polypropylene glycol, a diethylene glycol trimethylnonanol ethylene oxide additive, and nonionic surfactants of the polyester type, as well as mixtures. In the dispersion, a mean diameter of the vinyl polymer particles may be in the range of 0.001 to 100 microns, preferably 0.01 to 50 microns. Indeed, beyond the recommended range, a cosmetic product mixed with the emulsion will not have a sufficiently good sensation, especially on the lips, or the touch, nor sufficient spreading properties nor a pleasant sensation. A vinyl polymer contained in the dispersion or solution may have a concentration in a range of between 0.1% and 95% by weight, preferably between 5% and 85% by weight. However, for ease of handling and mixing, the range should preferably be between 10% and 75% by weight. A vinyl polymer that is suitable for the invention may also be one of the polymers described in the examples of application EP 0 963 751.

According to a preferred embodiment, a vinyl polymer grafted with a carbosiloxane dendrimer may be derived from the polymerization: (A1) from 0 to 99.9 parts by weight of one or more monomer (s) acrylate or methacrylate; and (B 1) from 100 to 0.1 parts by weight of an acrylate or methacrylate monomer of a tri [tri (trimethylsiloxy) silylethyl dimethylsiloxy] silylpropyl carbosiloxane dendrimer. The monomers (A1) and (B1) correspond to particular monomers (A) and (B), respectively. According to one embodiment, a vinyl polymer having at least one unit derived from carbosiloxane dendrimer may comprise a unit derived from tri [tri (trimethylsiloxy) silylethyl dimethylsiloxy] silylpropyl carbosiloxane dendrimer having one of the following formulas: CH 3 H 2 C = CC- In a preferred embodiment, a vinyl polymer having at least one carbosiloxane dendrimer-derived unit used in the invention comprises at least one of at least one carboxy-siloxane dendrimer unit used in the present invention. minus a butyl acrylate monomer. According to one embodiment, a vinyl polymer may further comprise at least one fluorinated organic group. Particularly preferred are structures in which the vinyl polymerized units constitute the backbone and carbosiloxane dendritic structures as well as fluorinated organic groups are attached to side chains. The fluorinated organic groups can be obtained by substituting with 30 fluorine atoms all or part of the hydrogen atoms of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, cyclohexyl and heptyl groups. , octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecyl, and other alkyl groups of 1 to 20 carbon atoms, as well as alkyloxyalkylene groups of 6 to 22 atoms of carbon. The groups represented by the formula - (CH 2) '- (CF 2) 5, -R "are suggested by way of example of fluoroalkyl groups, obtained by substituting fluorine atoms for hydrogen atoms of alkyl groups. formula, the index "x" and 0, 1, 2 or 3 and "y" and an integer of 1 to 20. R13 is an atom or a group selected from a hydrogen atom, a fluorine atom, -CH (CF 3) 2- or CF (CF 3) 2 Such fluorine-substituted alkyl groups are exemplified by linear or branched polyfluoroalkyl or perfluoroalkyl groups represented by the formulas presented below: -CF 3, -C 2 F 5, -nC 3 F 7, - CF (CF3) 2, -NC4F9, CF2CF (CF3) 2, -NC5Fi, -NC6F13, -NC8F17, CH2CF3, - (CH (CF3) 2, CH2CH (CF3) 2-CH2 (CF2) 2F, -CH2 (CF2 ) 3F, -CH2 (CF2) 4F, CH2 (CF2) 6F, CH2 (CF2) 8F, -CH2CH2CF3, -CH2CH2 (CF2) 2F, -CH2CH2 (CF2) 3F, -CH2CH2 (CF2) 4F, -CH2CH2 (CF2 ) 6F, -CH2CH2 (CF2) 8F, -CH2CH2 (CF2) 10F, -CH2CH2 (CF2) 12F, CH2CH2 (CF2) 14F, -CH2CH2 (CF2) 16F, -CH2CH2CH2CF3, -CH2CH2CH2 (CF2) 2F, -CH 2CH2CH2 (CF2) 2H, -CH2 (CF2) 4H and -CH2CH2 (CF2) 3H. The groups represented by -CH2CH2- (CF2) .- - CFR1440CF2CF (CF3)] - OC3F7 are suggested as fluoroalkyloxyfluoroalkylene groups obtained by substituting fluorine atoms for hydrogen atoms of alkoxyoxyalkylene groups. In the formula, the index "m" is 0 or 1, "n" is 0, 1, 2, 3, 4, or 5, and R14 is a fluorine atom or CF3. Such fluoroalkyloxyfluoroalkylene groups are exemplified by perfluoroalkyloxyfluoroalkylene groups represented by the formulas set forth below: -CH2CH2CF (CF3) 40CF2CF (CF3) L-OC3F7, -CH2CH2CF2CF240CF2CF (CF3) L-OC3F7. The number average molecular weight of the vinyl polymer used in the present invention may range from 3,000 to 2,000,000, and more preferably from 5,000 to 800,000. This type of fluorinated vinyl polymer may be obtained by adding: a vinyl monomer (M2) without a fluorinated organic group, on a vinyl monomer (M1) containing fluorinated organic groups, and a carbosiloxane dendrimer (B) as defined above of general formula (I) as defined herein. above, subjecting them to copolymerization. Thus, according to one embodiment, a composition of the invention may comprise a vinyl polymer having at least one unit derived from carbosiloxane dendrimer and resulting from the copolymerization of a vinyl monomer (M1) as defined above, optionally a vinyl monomer (M2) as defined above, and a carbosiloxane dendrimer (B) as defined above, said vinyl polymer having a copolymerization ratio between the monomer (M1) and the monomer (M2 ) from 0.1 to 100: 99.9 to 0% by weight, and a copolymerization ratio between the sum of the monomers (M1) and (M2) and the monomer (B) from 0.1 to 99.9: 99 , 9 to 0.1% by weight. The vinyl monomers (M1) containing fluorinated organic groups in the molecule are preferably monomers represented by the general formula: (CH2) = CR15COORf. In this formula, R15 is a hydrogen atom or a methyl group, Rf is a fluorinated organic group exemplified by the fluoroalkyl and fluoroalkyloxyfluoroalkylene groups described above. The compounds represented by the formulas presented below are suggested as specific examples of the component (M1).

In the formulas present below, "z" is an integer of 1 to 4. CH 2 = CCH 3 CO-CF 3, CH 2 = CCH 3 CO-C 2 F 5, CH 2 = CCH 3 CO-n C 3 F 7, CH 2 = CCH 3 CO-CF (CF 3) 2, CH 2 = CCH 3 CO -NC4F9, CH2 = CCH3C00-CF (CF3) 2, CH2 = CCH3C00-nC5Fi, CH2 = CCH3C00-nC6F13, CH2 = CCH3COO-nC8F, 7, CH2 = CCH3C00-CH2CF3, CH2 = CCH3C00-CH (CF3) 2, CH2 = CCH3C00-CH2CH (CF3) 2, CH2 = CCH3C00-CH2 (CF2) 2F, CH2 = CCH3C00-CH2 (CF2) 2F, CH2 = CCH3C00-CH2 (CF2) 4F, CH2 = CCH3C00-CH2 (CF2) 6F, CH2 = CCH3C00-CH2 (CF2) 8F, CH2 = CCH3C00-CH2CH2CF3, CH2 = CCH3C00-CH2CH2 (CF2) 2F, CH2 = CCH3COO-CH2CH2 (CF2) 3F, CH2 = CCH3C00-CH2CH2 (CF2) 4F, CH2 = CCH3C00-CH2CH2 (CF2) 6F, CH2 = CCH3C00-CH2CH2 (CF2) 8F, CH2 = CCH3C00-CH2CH2 (CF2) 10F, CH2 = CCH3C00-CH2CH2 (CF2) 12F, CH2 = CCH3C00-CH2CH2 (CF2) 14F, CH2 = CCH3C00-CH2 -CH2- (CF2) 16F, CH2 = CCH3C00-CH2CH2CH2CF3, CH2 = CCH3C00-CH2CH2CH2 (CF2) 2F, CH2 = CCH3C00-CH2CH2CH2 (CF2) 2H, CH2 = CCH3C00-CH2 (CF2) 4H, CH2 = CCH3C00- (CF2 ) 3H, CH2 = CCH3C00-CH2CH2CF (CF3) 40CF2-CF (CF3) P-OC3F7, CH2 = CCH3C00-CH2CH2CF2CF240CF2-CF (CF3) P-OC3F7, CH2 = CHCOO-CF3, CH2 = CHCOO-C2F5, CH2 = CHCOO -nC3F7, CH2 = CHCOO-CF (CF3) 2, CH2 = CHCOO-nC4F9, CH2 = CHCOO-CF2CF (CF3) 2, CH2 = CHCOO-nC5Fi, CH2 = CHCOO-nC6F13, CH2 = CHCOO-nC8F17, CH2 = CHCOO-CH2CF3, CH2 = CHCOO-CH (CF3) 2, CH2 = CHCOO-CH2CH (CF3) 2, CH2 = CHCOO-CH2 (CF2) 2F, CH2 = CHCOO-CH2 (CF2) 3F, CH2 = CHCOO-CH2 (CF2) 4F, CH2 = CHCOO-CH2 (CF2) 6F, CH2 = CHCOO-CH2 (CF2) 8F, CH2 = CHCOO-CH2CH2CF3, CH2 = CHCOO-CH2CH2 (CF2) 2F, CH2 = CHCOO-CH2CH2 (CF2) 3F, CH2 = CHCOO-CH2CH2 (CF2) 4F, CH2 = CHCOO- CH2CH2 (CF2) 6F, CH2 = CHCOO-CH2CH2 (CF2) 8F, CH2 = HCOO-CH2CH2 (CF2) 10F, CH2-CHCOO-CH2CH2- (CF2) 12F, CH2 = CHCOO-CH2CH2 (CF2) 14F, CH2 = CHCOO -CH2CH2 (CF2) 16F, CH2 = CHCOO-CH2CH2CH2CF3, CH2 = CHCOO-CH2CH2CH2 (CF2) 2F, CH2 = CHCOO-CH2CH2CH2 (CF) 2H, CH2 = CHCOO-CH2 (CF2) 4H, CH2 = CHCOO-CH2CH2 (CF2 ) 3H, CH2 = CHCOO-CH2CH2CF (CF3) -, [OCF2-CF (CF3)] z-OC3F7, CH2 = CHCOO-CH2CH2CF2CF2 (CF3) - [OCF2-CF (CF3)] 2-C3F7.

Of these, the vinyl polymers represented by the formulas presented below are preferred: CH 2 = CHCOO-CH 2 CH 2 (CF 2) 6F, CH 2 = CHCOO-CH 2 CH 2 (CF 2) 8F, CH 2 = CCH 3 COO-CH 2 CH 2 (CF 2) 6F, CH 2 = CCH3COO-CH2CH2 (CF2) 8F, CH2 = CHCOO-CH2CF3, CH2 = CCH3COO-CH2CF3.

The vinyl polymers represented by the formulas presented below are particularly preferred: CH2 = CHCOO-CH2CF3, CH2 = CCHCOO-CH2CF3. The vinyl monomers (M2) which do not contain fluorinated organic groups in the molecule may be any monomers having radical-polymerizable vinyl groups which are exemplified, for example, by methyl acrylate, methyl methacrylate or acrylate. ethyl, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, and other lower alkyl acrylates or methacrylates; glycidyl acrylate, glycidyl methacrylate; n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl acrylate , hexyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, acrylate octyl, octyl methacrylate, lauryl acrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, and other higher acrylates and methacrylates; vinyl acetate, vinyl propionate, and other lower fatty acid vinyl esters; vinyl butyrate, vinyl caproate, vinyl 2-ethylhexanoate, vinyl laurate, vinyl stearate, and other higher fatty acid esters; styrene, vinyltoluene, benzyl acrylate, benzyl methacrylate, phenoxyethyl acrylate, phenoxyethyl methacrylate, vinylpyrrolidone, and other vinyl aromatic monomers; dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, and other amino vinyl monomers, acrylamide, methacrylamide, N-methylolacrylamide, N-methylolmethacrylamide, N methoxymethylacrylamide, N-methoxymethylmethacrylamide, isobutoxymethoxyacrylamide, sobutoxymethoxymethacrylamide, N, N-dimethylacrylamide, N, N-dimethylmethacrylamide, and other vinyl amide monomers; hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylic acid alcohol, methacrylic acid hydroxypropyl alcohol and other hydroxy vinyl monomers; acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, and other carboxylic acid vinyl monomers; tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, butoxyethyl acrylate, butoxyethyl methacrylate, ethoxydiethyleneglycol acrylate, ethoxydiethyleneglycol methacrylate, polyethyleneglycol acrylate, polyethyleneglycol methacrylate, polypropyleneglycol monoacrylate polypropylene glycol monomethacrylate, hydroxybutylvinylether, cetylvinylether, 2-ethylhexylvinylether and other ether-linked vinyl monomers; Acryloxypropyltrimethoxy silane, methacryloxypropyltrimethoxysilane, polydimethylsiloxanes containing acrylic or methacryl groups at one end, polydimethylsiloxanes containing alkenylaryl groups at one end and other silicone compounds with unsaturated groups; butadiene; vinyl chloride; vinylidene chloride, acrylonitrile, methacrylonitrile; dibutyl fumarate; maleic anhydride; dodecylsuccinic anhydride; acrylglycidyl ether, methacrylglycidyl ether, 3,4-epoxycyclohexylmethyl acrylate, 3,4-epoxycyclohexylmethyl methacrylate, alkali metal salts, ammonium salts and organic amine salts of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid and other radical-polymerizable unsaturated carboxylic acids, radical-polymerizable unsaturated monomers containing sulfonic acid groups such as styrenesulfonic acid as well as their alkali metal salts, their ammonium salts and their organic amine salts; quaternary ammonium salts derived from acrylic acid or methacrylic acid such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride, methacrylic acid esters of a tertiary amine alcohol, such as diethylamine ester, methacrylic acid and their quaternary ammonium salts. In addition, it is also possible to use, as vinyl monomers (M2), the polyfunctional vinyl monomers which are exemplified for example by trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate and diacrylate. ethylene glycol, ethylene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, diacrylate 1,6-hexanediol, 1,6-hexanediol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl acrylate, trimethylolpropanetrioxyethyl methacrylate, tris (2-hydroxyethyl) isocyanurate diacrylate, dimethacrylate tris (2-hydroxyethyl) isocyanurate, tris (2-hydroxyethyl) isocyanurate triacrylate, tris (2-hydroxyethyl) isocyanurate trimethacrylate, polydimethylsiloxane whose both ends of the molecular chain are blocked by alkenylaryl groups, and other silicone compounds with unsaturated groups. With respect to the above-mentioned ratio in which (M1) and (M2) are copolymerized, the weight ratio between (M1) and (M2) is preferably in the range 1:99 to 100: 0. Y may be chosen, for example, from organic groups containing acrylic or methacrylic groups, organic groups containing alkenylaryl groups, or alkenyl groups of 2 to 10 carbon atoms.

The organic groups with acrylic or methacrylic groups and the alkenylaryl groups are as defined above. Among the compounds (B), there may be mentioned, for example, the following compounds: ## STR2 ## wherein O-Si-CH 3 CH 3 CH 3 The carbosiloxane dendrimers (B) can be prepared using the process of preparation for the branched siloxane / silakylene copolymers described in EP 10555. For example, they can be prepared by subjecting organic silicone compounds to alkenyl and silicone compounds comprising silicon-bonded hydrogen atoms, represented by the formula (IV) as defined above, to a reaction of hydrosilylation. The copolymerization ratio (by weight) between the monomer (B) and the monomers (M1) and (M2) is preferably in the range of 1:99 to 99: 1, and even more preferably in the range of from 5:95 to at 95: 5.

Amino groups may be introduced into the side chains of the vinyl polymer using, included in the component (M2), vinyl monomers containing amino groups, such as dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate and diethylaminoethyl methacrylate, followed by modification with potassium acetate monochloride, ammonium acetate monochloride, monochloroacetic acid aminomethylpropanol salt, monobromoacetic acid triethanolamine salt, sodium monochloropropionate, and other alkali metal salts of halogenated fatty acids; otherwise, carboxylic acid groups can be introduced into the side chains of the vinyl polymer by using, included in the component (M2), vinyl monomers containing carboxylic acids, such as acrylic acid, methacrylic acid, itaconic acid. , crotonic acid, fumaric acid and maleic acid, and the like, then neutralizing the product with triethylamine, diethylamine, triethanolamine, and other amines. A fluorinated vinyl polymer may be one of the polymers described in the examples of application WO 03/045337. According to a preferred embodiment, a grafted vinyl polymer in the sense of the present invention may be carried in an oil or a mixture of oil (s), preferably volatile (s) in particular, chosen (s) from the oils of silicones and hydrocarbon oils and mixtures thereof. According to a particular embodiment, a silicone oil that is suitable for the invention may be cyclopentasiloxane.

According to another particular embodiment, a hydrocarbon oil suitable for the invention may be isododecane. The vinyl polymers grafted with at least one carbosiloxane dendrimer-derived unit that may be particularly suitable for the present invention are the polymers sold under the names TIB 4-100, TIB 4-101, TIB 4-120, TIB 4-130, TIB 4- 200, FA 4002 ID (TIB 4-202), TIB 4-220, FA 4001 CM (TIB 4-230) by Dow Corning. According to one embodiment, the composition according to the present invention comprises the vinyl polymer having at least one unit derived from carbosiloxane dendrimer with an active material content ranging from 0.5% to 20%, in particular from 1% to 15% by weight. weight, relative to the total weight of said composition. VOLATILE OILS As indicated above, the composition according to the invention comprises at least two volatile hydrocarbon oils.

Preferably, the volatile hydrocarbon oils are apolar. More particularly, the apolar volatile hydrocarbon oil may have a flash point ranging from 40 ° C. to 102 ° C., preferably ranging from 40 ° C. to 55 ° C., and preferably ranging from 40 ° C. to 50 ° C. The hydrocarbon-based volatile oil may especially be chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof, and in particular: C8-C16 branched alkanes, for example iso-alkanes (also known as isoparaffins) with C 8 -C 8 C16, isododecane, isodecane, isohexadecane, and for example the oils sold under the trade names of Isopars or permetyls; linear C8-C16 alkanes, for example such as n-dodecane and ntetradecane sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures, the undecane-tridecane mixture (Cetol UT), the n-undecane and n-tridecane mixtures obtained in Examples 1 and 2 of application WO2008 / 155059 from Cognis and their mixtures. Preferably, the volatile hydrocarbon oils are at least chosen from branched alkanes. According to this embodiment, the volatile hydrocarbon oil content (s) represents from 0.5 to 40% by weight, more particularly from 1 to 30% by weight, and preferably from 5 to 30% by weight. % by weight, based on the weight of the composition. The composition according to the invention may also comprise, in addition to volatile hydrocarbon oils, at least one volatile silicone or fluorinated oil.

For example, the silicone oils are chosen in particular from silicone oils having a flash point ranging from 40 ° C. to 102 ° C., preferably having a flash point greater than 55 ° C. and less than or equal to 95 ° C., and preferentially ranging from from 65 ° C to 95 ° C. As volatile silicone oils that can be used, mention may be made of linear or cyclic silicones having a viscosity at room temperature of less than 8 centistokes (cSt) (8 × 10 -6 m 2) and having, in particular, from 2 to 10 silicon atoms, and in particular, from 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. Volatile silicone oils that may be used include, in particular, dimethicones of viscosity 5 and 6 cSt, octamethyl cyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof. According to another embodiment, the volatile oil is a fluorinated oil, such as nonafluoromethoxybutane or perfluoromethylcyclopentane, and mixtures thereof.

Preferably, if one or more other volatile oils are used in addition to volatile hydrocarbon oils, they are chosen from volatile silicone oils. In addition, if the composition comprises at least one volatile silicone oil, its content is less than 5% by weight, relative to the weight of the composition. More particularly, when the composition comprises at least one volatile silicone oil, the weight ratio of the silicone or fluorinated volatile oils, and preferably silicone, on the volatile hydrocarbon oil (s), is between 0 and 1 excluded boundary. Preferably, the composition according to the invention does not comprise volatile silicone oil.

SOLID COMPOUNDS / WAXES The composition according to the invention may optionally comprise at least one solid compound chosen from solid fatty alcohols, waxes, in particular polar or apolar hydrocarbon waxes, or mixtures thereof. Solid fatty alcohols The composition according to the invention may thus comprise at least one linear or branched, preferably linear, saturated or unsaturated fatty alcohol, whose melting point is greater than or equal to 40 ° C., comprising from 16 to 60 carbon atoms, preferably from 18 to 60 carbon atoms. Preferably, the solid fatty alcohol is a monoalcohol. For example, Performacol 550-L Alcohol wax from New Phase Technology, stearic alcohol, cetyl alcohol, palmitic alcohol, behenyl alcohol, arachidyl alcohol, 1-triacontanol, or mixtures. Preferably, solid fatty alcohols having a melting temperature of at least 60 ° C., saturated and linear, comprising from 20 to 60 carbon atoms, are used. Advantageously, if the composition comprises, the content of solid fatty alcohol (s) whose melting temperature is greater than or equal to 40 ° C represents from 5 to 20% by weight, preferably from 5 to 15% by weight. weight, more particularly between 7 and 15% by weight, relative to the total weight of the composition. Additives Alcohols or Alcohol Derivatives According to an advantageous variant of the present invention, the composition further comprises at least one alcohol additive or alcohol derivative chosen from: solid fatty alcohols whose melting point is between 25 ° C. and below 40 ° C. More particularly, said alcohols are saturated or unsaturated, preferably saturated, preferably linear, and advantageously comprise at least 14 carbon atoms. By way of example, mention may be made of myristic alcohol and erucic alcohol. Fatty alcohols having at least 14 carbon atoms, linear or branched, saturated or unsaturated, mono-oxyalkylenated or poly-oxyalkylenated C2-C3, solids at 25 ° C. More particularly, said fatty alcohols are mono- or poly-oxyethylenated, and advantageously comprise from 14 to 30 carbon atoms, preferably from 16 to 30. They are preferably linear, saturated.

Preferably, the number of oxyalkylene units, preferably oxyethylenated, is between 1 and 100, more particularly between 1 and 50, preferably between 1 and 30. By way of examples, mention may be made of the ethoxylated derivatives of alcohol stearic, cetyl, cetostearyl, myristic, palmitic, in one form, and mixtures thereof. For example, mention may be made of stearic alcohol containing 20 moles of ethylene oxide, cetostearyl alcohol containing 20 moles of ethylene oxide and cetostearyl alcohol containing 30 moles of ethylene oxide. The liposoluble polyethers resulting from the polyetherification between one or more C2-C10 diols, preferably C2-050 diols. Among the liposoluble polyethers, the copolymers of ethylene oxide and / or of propylene oxide with diols comprising a C 6 -C 30 alkyl chain are particularly considered. Preferably these polyethers have a weight ratio of ethylene oxide and / or propylene oxide relative to the aforementioned diol ranging from 5:95 to 70:30. Preferably, these compounds are triblocks. In this family, mention will in particular be made of copolymers such as the alkyl chain-containing diol (s) are arranged in blocks having an average molecular weight of 1000 to 10,000, for example polyoxyethylene / polydodecyl glycol block copolymers, such as dodecanediol ethers ( 22 mol) and polyethylene glycol (45 0E) (INCI name: PEG-45 / Dodecyl Glycol copolymer, marketed under the tradename ELFACOS ST9 by AKZO NOBEL) or ethers of dodecanediol (9 mol) and polyethylene glycol (22 0E) (INCI name: PEG-22 / Dodecyl Glycol Copolymer, sold under the trademark ELFACOS ST 37 by AKZO NOBEL, or mixtures thereof, When the composition comprises one or more of these additives, and this corresponds to a particularly advantageous variant of the their content is between 1 and 10% by weight, preferably between 3 and 7.5% by weight, relative to the total weight of the composition, and preferably the weight ratio additive (s) alcohol u alcohol derivative / solid alcohol (s) solid (s) supra (s) is less than 1, preferably between 0 and 1 (limit excluded).

Waxes The composition according to the invention may optionally comprise at least one wax, different from solid fatty alcohols whose melting point is greater than or equal to 40 ° C. mentioned above, and different from the alcohol or alcohol derivative additives. More particularly, said waxes are chosen from polar, nonpolar hydrocarbon waxes, or mixtures thereof. The wax or waxes considered in the context of the present invention are, in general, lipophilic compounds, solid at room temperature (25 C), with reversible solid / liquid state change, having a melting point greater than or equal to at 30 ° C up to 200 ° C and in particular up to 120 ° C. In particular, the waxes that are suitable for the invention may have a melting point greater than or equal to 45 ° C., and in particular greater than or equal to 55 ° C. For the purposes of the invention, the melting temperature corresponds to the temperature of the peak. the most endothermic observed in thermal analysis (DSC) as described in ISO 11357-3; 1999. The melting point of the wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name "DSC Q2000" by the company TA Instruments. Preferably, the waxes have a melting enthalpy AHf greater than or equal to 70 J / g. Preferably, the waxes comprise at least one crystallizable part, visible by X-ray observations. The measurement protocol is as follows: A sample of 5 mg of wax placed in a crucible is subjected to a first temperature rise of -20. ° C at 120 ° C, at the heating rate of 10 ° C / minute, then is cooled from 120 ° C to -20 ° C at a cooling rate of 10 ° C / minute and finally subjected to a second rise in temperature ranging from -20 ° C to 120 ° C at a heating rate of 5 ° C / minute. During the second rise in temperature, the following parameters are measured: the melting point (Tf) of the wax, as previously mentioned, corresponding to the temperature of the most endothermic peak of the observed melting curve, representing the variation of the the difference in power absorbed as a function of the temperature; AHf: the melting enthalpy of the wax corresponding to the integral of the whole of the melting curve obtained. This enthalpy of fusion of the wax is the amount of energy required to pass the compound from the solid state to the liquid state. It is expressed in J / g. The wax may especially have a hardness ranging from 0.05 MPa to 15 MPa, and preferably ranging from 6 MPa to 15 MPa. The hardness is determined by measuring the compression force measured at 20 ° C. using the texturometer sold under the name TA-TX2i by the company RHEO, equipped with a stainless steel cylinder with a diameter of 2 mm. moving at the measuring speed of 0.1 mm / s, and penetrating into the wax at a penetration depth of 0.3 mm. If the composition comprises at least one wax, different from the solid fatty alcohols whose melting point is greater than or equal to 40 ° C. mentioned above, and different from the alcohol or alcohol derivative additives also described above, their content is preferably such that the weight ratio wax (es) / solid fatty alcohol (s) is less than 1, more particularly between 0 and 1 excluded limit.

Apolar waxes For the purposes of the present invention, the term "apolar wax" is intended to mean a wax whose solubility parameter at 25 ° C. as defined below, Sa is equal to 0 (J / cm 3) 1/4. The apolar waxes are in particular hydrocarbon waxes consisting solely of carbon and hydrogen atoms and free from heteroatoms such as N, O, Si and P. By "hydrocarbon wax" is meant a substantially formed wax, even constituted wax , carbon atoms and hydrogen, and optionally oxygen atoms, nitrogen, and not containing a silicon atom or fluorine. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

More particularly, the apolar wax may be chosen from microcrystalline waxes, paraffin waxes, ozokerite, polyethylene waxes, polymethylene waxes, microwaxes and mixtures thereof. As microcrystalline waxes that may be used, mention may be made of MULTIWAX W 445® sold by the company SONNEBORN and MICROWAX HW® and BASE WAX 20 30540 ° sold by PARAMELT. As ozokerite OZOKERITE WAX SP 1020 P may be mentioned. As polyethylene wax, there may be mentioned PERFORMALENE 500-L POLYETHYLENE and PERFORMALENE 400 POLYETHYLENE marketed by New Phase Technologies. As polymethylene wax, mention may be made of POLYMETHYLENE WAX (54 ° C) sold under the reference Cirebelle 303; POLYMETHYLENE WAX (80 ° C) sold under the reference Cirebelle 108 marketed by Cirebelle As microwaves that can be used in the compositions according to the invention as non-polar wax, mention may be made in particular of polyethylene microwaxes such as those sold under the names Micropoly 200®, 220®, 220L® and 2505® by the company MICRO POWDERS. Advantageously, if the composition comprises at least one apolar wax, their content represents from 0.1 to 5% by weight, relative to the weight of the composition. Polar waxes For the purposes of the present invention, the term "polar wax" means a wax whose solubility parameter at 25 ° C. Sa is different from 0 (J / cm 3) 1/4.

In particular, "polar wax" is understood to mean a wax whose chemical structure is formed essentially or even consisting of carbon and hydrogen atoms, and comprising at least one highly electronegative heteroatom such as an oxygen atom. , nitrogen, silicon or phosphorus.

The definition and calculation of the solubility parameters in the HANSEN three-dimensional solubility space are described in the article by C. M. HANSEN: "The three dimensionna" solubility parameters "J. Paint Technol. 39, 105 (1967). According to this Hansen space: - 8D characterizes the LONDON dispersion forces resulting from the formation of dipoles induced during molecular shocks; - 8p characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles; - Sh characterizes the specific interaction forces (hydrogen bond, acid / base, donor / acceptor type, etc.); - 8a is determined by the equation: 8a = (S1) 2 8h2) 1/4 The parameters 8p, 811, 8D and Sa are expressed in (J / cm3) 1/4. As hydrocarbon polar wax, a wax chosen from ester waxes is particularly preferred.

By "ester wax" is meant according to the invention a wax comprising at least one ester function. Ester waxes may be used especially as: - ester waxes such as those chosen from: i) waxes of formula R 1 COROR 2 in which R 1 and R 2 represent linear, branched or cyclic aliphatic chains whose number of atoms varies from 10 at 50, which may contain a heteroatom such as O, N or P and whose melting point temperature varies from 25 to 120 ° C. In particular, a C20-C40 alkyl (hydroxystearyloxy) stearate (the alkyl group comprising 20 to 40 carbon atoms), alone or as a mixture or a C20-C40 alkyl stearate, may be used as ester wax. Such waxes are sold, for example, under the names "Kester Wax K 82 P®", "Hydroxypolyester K 82 P®", "Kester Wax K 80 P®", or "Kester KSH WAX" by the company Koster Keunen. ii) montanate (octacosanoate) waxes of glycol and butylene glycol, such as the wax LICOWAX KPS FLAKES (INCI name: montanate glycol) marketed by Clariant. iii) di- (trimethylol-1,1,1 propane) tetrastearate, sold under the name Hest 2T-45® by the company Hetenere. iv) diester waxes of a dicarboxylic acid of general formula R3 - (- 000-R4-COO-R5), in which R3 and R5 are identical or different, preferably identical and represent a C4-C30 alkyl group (group alkyl comprising from 4 to 30 carbon atoms) and R4 represents a C4-C30 aliphatic group (alkyl group comprising from 4 to 30 carbon atoms) linear branched which may or may not contain 1 or more unsaturations, and preferably linear and unsaturated. v) There may also be mentioned waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains, for example such as hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil, and waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, such as those sold under the names Phytowax ricin 16L64® and 22L73® by the SOPHIM company. Such waxes are described in application FR-A-2792190 and the waxes obtained by hydrogenation of olive oil esterified with stearyl alcohol such as that sold under the name "PHYTOWAX Olive 18 L 57" or else. (vi) beeswax, synthetic beeswax, polyglycerolated beeswax, carnauba wax, candelilla wax, oxypropylene lanolin wax, rice bran wax, Ouricury wax , Alfa wax, cork fiber wax, sugar cane wax, Japanese wax; sumac wax; montan wax, orange wax, laurel wax, hydrogenated jojoba wax. Preferably, candelilla wax is used.

According to a particular embodiment of the invention, the composition comprises at least one polar wax. Advantageously, the polar wax or waxes are chosen from hydrocarbon polar waxes, more particularly from ester waxes, and preferably the aforementioned waxes vi) and mixtures thereof.

According to a particular embodiment of the invention, when it is present, the content of polar wax (es) in the composition is between 0.1% and 5% by weight, preferably between 0, 1% and 2% by weight, relative to the total weight of the composition.

Preferably, the composition comprises at least one solid fatty alcohol as described above. In addition, it comprises very advantageously, at least one alcohol additive or a derivative of alcohol mentioned above.

According to another variant of the invention, the composition comprises, in addition to the solid fatty alcohol, the alcohol additive or alcohol derivative, at least one polar wax, preferably chosen from waxes vi).

PASSIVE FATTY BODY The composition according to the invention may also comprise at least one pasty fatty substance. For the purposes of the present invention, the term "pasty fatty substance" is intended to mean a lipophilic fat compound with a reversible solid / liquid state change, having in the solid state an anisotropic crystalline organization and comprising at a temperature of 23.degree. liquid fraction and a solid fraction. In other words, the starting melting temperature of the pasty fatty substance may be less than 23 ° C. The liquid fraction of the pasty fatty substance measured at 23 ° C. can represent 9 to 97% by weight of the pasty fatty substance. This liquid fraction at 23 ° C is preferably between 15 and 85%, more preferably between 40 and 85% by weight. For the purposes of the invention, the melting temperature corresponds to the temperature of the most endothermic peak observed in thermal analysis (DSC) as described in ISO 11357-3; 1999. The melting point of a pasty fatty substance can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name "MDSC 2920" by the company TA Instruments. The measurement protocol is as follows: A sample of 5 mg of pasty fatty substance placed in a crucible is subjected to a first temperature rise ranging from -20 ° C to 100 ° C, at the heating rate of 10 ° C / minute, then is cooled from 100 ° C to -20 ° C at a cooling rate of 10 ° C / min and finally subjected to a second temperature rise from -20 ° C to 100 ° C at a heating rate 5 ° C / minute. During the second temperature rise, the variation of the power difference absorbed by the empty crucible and the crucible containing the pasty fatty substance sample is measured as a function of temperature. The melting point of the pasty fatty substance is the value of the temperature corresponding to the peak apex of the curve representing the variation of the difference in power absorbed as a function of temperature. The liquid fraction by weight of the pasty fatty substance at 23 ° C. is equal to the ratio of the enthalpy of fusion consumed at 23 ° C. on the heat of fusion of the pasty fatty substance. The enthalpy of melting of the pasty fatty substance is the enthalpy consumed by the latter to pass from the solid state to the liquid state. The pasty fatty substance is said in the solid state when the entirety of its mass is in crystalline solid form. The pasty fatty substance is said in the liquid state when the entirety of its mass is in liquid form. The enthalpy of melting of the pasty fatty substance is equal to the area under the curve of the thermogram obtained using a differential scanning calorimeter (DSC), such as the calorimeter sold under the name MDSC 2920 by the company TA instrument, with a temperature rise of 5 or 10 ° C per minute, according to ISO 11357-3; 1999. The enthalpy of melting of the pasty fatty substance is the amount of energy required to pass the pasty fatty substance from the solid state to the liquid state. It is expressed in J / g.

The heat of fusion consumed at 23 ° C is the amount of energy absorbed by the sample to change from the solid state to the state that it has at 23 ° C consisting of a liquid fraction and a solid fraction. The liquid fraction of the pasty fatty substance measured at 32 ° C. preferably represents from 30 to 100% by weight of the pasty fatty substance, preferably from 50 to 100%, more preferably from 60 to 100% by weight of the pasty fatty substance. When the liquid fraction of the pasty fatty substance measured at 32 ° C. is equal to 100%, the temperature of the end of the melting range of the pasty fatty substance is less than or equal to 32 ° C. The liquid fraction of the pasty fatty substance measured at 32 ° C. is equal to the ratio of the enthalpy of fusion consumed at 32 ° C. on the heat of fusion of the pasty fatty substance.

The enthalpy of fusion consumed at 32 ° C. is calculated in the same way as the heat of fusion consumed at 23 ° C. The pasty fatty substance may in particular be chosen from synthetic fats and vegetable fats. A pasty fatty substance can be obtained synthetically from starting materials of plant origin.

The pasty fatty substance may be chosen from: lanolin and its derivatives, petroleum jelly (also called petrolatum), polyol ethers chosen from pentaerythritol ethers and polyalkylene glycol ethers, fatty alcohol and sugar ethers. , and their mixtures, pentaerythritol ether and polyethylene glycol comprising 5 oxyethylenated units (50E) (CTFA name: PEG-5 Pentaerythrityl Ether), pentaerythritol ether and polypropylene glycol comprising 5 oxypropylene units (5 PO) ( CTFA name: PPG-5 Pentaerythrityl Ether), and their mixtures and more especially the PEG-5 Pentaerythrityl Ether mixture, PPG-5 Pentaerythrityl Ether and soya oil, sold under the name "Lanolide" by the company VEVY, a mixture in which the constituents are in a ratio by weight 46/46/8: 46% of PEG-5 Pentaerythrityl Ether, 46% of PPG-5 Pentaerythrityl Ether and 8% of soybean oil, - polymeric silicone compounds or not, - the compounds fluorinated polymers, whether or not polymers, vinyl polymers, in particular: homopolymers and copolymers of olefins, homopolymers and copolymers of hydrogenated dienes, linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C 8 -C 30 alkyl group, homo and copolymeric oligomers of vinyl esters having C 8 -C 30 alkyl groups, and homo- and copolymer oligomers of vinyl ethers having C 8 -C 30 alkyl groups; esters, and / or their mixtures.

Among the esters, mention is made in particular of: esters of an oligomeric glycerol, in particular the diglycerol esters, in particular the adipic acid and glycerol condensates, for which part of the hydroxyl groups of the glycerols have reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid, isostearic acid and 12-hydroxystearic acid, for example bis-diglyceryl polyacyladipate-2 sold under the reference SOFTISAN® 649 by the Sasol company, homopolymers of vinyl ester having C8-C30 alkyl groups, such as polyvinyl laurate (in particular sold under the reference Mexomère PP by the company Chimex), arachidyl propionate marketed under the trademark Waxenol 801 by ALZO, - phytosterol esters, - triglycerides of fatty acids and their derivatives, - esters of pentaerythritol, - esters of diol dimer and diacid dimer, where appropriate, esterified s on their (s) function (s) alcohol (s) or acid (s) open (s) by acid or alcohol radicals, in particular the dimer dilinoleate esters; such esters may in particular be chosen from the following INCI nomenclature esters: bis-behenyl / isostearyl / phytosteryl dimerdilinoleyl dimerdilinoleate (Plandool G), phytosteryl / isosteryl / cetyl / stearyl / behenyl dimerdilinoleate (Plandool H or Plandool S) and their mixtures, vegetable butters such as mango butter, such as that marketed under the reference Lipex 203 by the company Aharushkarlshamn, shea butter, in particular the one whose INCI name is Butyrospermum Parkii Butter, such as that marketed under the reference Sheasoft® by AARHUSKARLSHAMN, cupuacu butter (Rain forest RF3410 from Beraca Sabara), murumuru butter (RAIN FOREST RF3710 from Beraca Sabara), cocoa butter; as well as orange wax, for example, the one marketed under the reference Orange Peel Wax by the company Koster Keunen, - vegetable oils that are totally or partially hydrogenated, for example hydrogenated soybean oil, oil hydrogenated coconut oil, hydrogenated rapeseed oil, hydrogenated vegetable oil mixtures such as the hydrogenated vegetable oil mixture of soybean, coconut, palm and rapeseed, for example the mixture sold under the reference Akogel® by the company Aharushkarlshamn (INCI name Hydrogenated Vegetable Oil), trans isomerized partially hydrogenated jojoba oil manufactured or marketed by Desert Whale under the trade name Iso-Jojoba-50®, partially hydrogenated olive oil such as, for example, compound sold under the reference Beurrolive by the company Soliance, - esters of hydrogenated castor oil, such as hydrogenated castor oil, for example dilinoleate RISOCAST-DA-L sold by KOKYU ALCOHOL KOGYO, hydrogenated castor oil isostearate for example SALACOS HCIS (V-L) sold by NISSHIN OIL, and mixtures thereof.

According to a preferred embodiment, the pasty fatty substance is chosen from esters and in particular diglycerol esters and mixtures thereof. Among the pasty compounds, preference will be given to bisbehenyl / isostearyl / phytosteryl dimeric dilinoleyl, bis-diglyceryl polyacyladipate-2, hydrogenated castor oil dimer dilinoleate, for example RISOCAST-DA-L sold by KOKYU ALCOHOL KOGYO, hydrogenated castor oil isostearate, for example SALACOS HCIS (VL) sold by NISSHIN OIL, polyvinyl laurate, mango butter, shea butter, hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated rapeseed oil, or their mixture. Preferably, if the composition comprises at least one pasty fatty substance, then their content represents from 0.1 to 20% by weight, relative to the total weight of the composition. NON-VOLATILE SILICONE OILS According to a variant of the invention, the composition preferably comprises at least one nonvolatile silicone oil, phenylated, with at least one dimethicone fragment, at least one nonvolatile silicone oil, phenylated without a dimethicone fragment, or their mixtures. Phenylated Silicone Nonvolatile Oils Free of Dimethicone Fragment The composition according to the invention comprises at least one first phenyl silicone nonvolatile oil having no dimethicone moiety. By "silicone oil" is meant an oil containing at least one silicon atom, and in particular containing Si-O groups. The term "phenylated" specifies that said oil has in its structure a phenyl radical.

The term "dimethicone fragment" denotes a divalent siloxane group whose silicon atom bears two methyl radicals, this group not being at the ends of the molecule. It can be represented by the following formula: - (Si (CH3) 2-O) -.

By "non-volatile" is meant an oil whose vapor pressure at 25 ° C. and atmospheric pressure is non-zero and less than 0.02 mm Hg (2.66 Pa) and better still less than 10 -3 mm of Hg (0.13 Pa). As first phenylated silicone nonvolatile oil having no dimethicone moiety, suitable for the present invention, there may be mentioned the following oils, alone or in mixtures: a) the phenyl silicone oils corresponding to the following formula (I): RRR R-Si-O II If RRRR If RR (I) in which the monovalent or divalent R groups represent, independently of each other, a methyl or a phenyl, provided that at least one R is phenyl and that formula (I) does not include a dimethicone moiety. Preferably, in this formula, the phenylsilicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six. b) the phenyl silicone oils corresponding to the following formula (II): RRR R-Si-O-Si-O-Si-R RRR (II) in which the R groups represent, independently of one another, a methyl or a phenyl, provided that at least one R is phenyl and that formula (I) does not include a dimethicone moiety.

Preferably, in this formula, the compound of formula (II) comprises at least three phenyl groups, for example at least four or at least five. Mixtures of different phenylorganopolysiloxane compounds previously described may be used. Examples which may be mentioned include mixtures of triphenyl-, tetraphenyl- or pentaphenyl-organopolysiloxanes.

Among the compounds of formula (II), mention may be made more particularly of phenylated silicone oils having no dimethicone fragment corresponding to formula (II) in which at least 4 or at least 5 R radicals represent a phenyl radical, the radicals remaining representing methyl.

Such nonvolatile phenyl silicone oils are preferably trimethylpentaphenyltrisiloxane or tetramethyltetraphenyltrisiloxane. They are in particular marketed by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,1,5,5-pentaphenyltrisiloxane; INCI name: trimethyl- pentaphenyltrisiloxane), or tetramethyltetraphenyltrisiloxane sold under the reference Dow Corning 554 Cosmetic Fluid by Dow Corning can also be used. They correspond in particular to the following formulas (IIa), (IIb): Ph Ph Ph Me Ph Me Me-Si-O-Si-O-Si-Me Ph-Si-O-Si-O-Si-Ph 1 1 Ph Me Ph (IIa) Me Ph Me (Iib) wherein Me is methyl, Ph is phenyl. c) the phenyl silicone oils corresponding to the formula (III) below: ## STR2 ## in which R 8 R 1 RS 1 -O 2 R 3 Si-O R 4 S 0 Si-O O Si (R 10) 3 Si-R 7 R 6 m in which: R1 to R10, independently of one another, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon radicals; m, n, p and q are, independently of one another, integers understood; between 0 and 900, provided that the sum m + n + q is different from 0 and that p is equal to 0 if R3 and R4 represent methyl groups. Preferably, the sum m + n + q is between 1 and 100. Advantageously, the sum m + n + p + q is between 1 and 900 and preferably between 1 and 800. Preferably, q is equal to O More particularly, R1 to R10, independently of each other, represent a linear or branched, saturated or unsaturated, preferably saturated, C1-C30 hydrocarbon radical, and in particular a hydrocarbon radical, preferably saturated, C 1 -C 20 in particular Ci-Cis, or a C6-C14 aryl radical and in particular C10-C13, monocyclic or polycyclic, or an aralkyl radical preferably whose alkyl part is C 1 -C 3. Preferably, R 1 to R 10 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. R1 to R10 may in particular be identical, and may furthermore be a methyl radical. According to a first more particular embodiment of formula (III), it is possible for i) the phenyl silicone oils corresponding to formula (Mi) below: ## STR2 ## Si R 4 p H 3 C-Si-O R 2 Si-O Si In which: R1 to R6, independently of one another, are saturated or unsaturated, linear, cyclic or branched C 1 -C 30 hydrocarbon radicals, an aryl radical, of R 1 to R 6, preferably C6-C14, or an aralkyl radical whose alkyl part is C1-C3). - m, n and p are, independently of one another, integers between 0 and 100, provided that the sum n + m is between 1 and 100 and that p is equal to 0 if R3 and R4 represent groups methyl.

Preferably, R 1 to R 6, independently of one another, represent a hydrocarbon radical, preferably C 1 -C 20 alkyl, in particular C 1 -C 18, or a monocyclic C 6 -C 14 aryl radical (preferably C6) or polycyclic and in particular C10-C13, or an aralkyl radical (preferably the aryl part is C6, the alkyl part is C1-C3).

Preferably, R 1 to R 6 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. R1 to R6 may in particular be identical, and may furthermore be a methyl radical. Preferably, m = 1 or 2 or 3, and / or n = 0 and p = 0 may be applied in the formula (Mi).

According to a suitable variant, mention may be made of the compounds (B) derived from the formula (Mi) below: Me Me OR Me Me-Si [O-Si O] -M Me Me Ph Me (B) in which Me is methyl and Ph is phenyl, OR 'represents a group -OSiMe3, p is 0, and m is between 1 and 1000. In particular, m and p are such that the compound (B) is a non-volatile oil . It may be used, for example, phenyltrimethylsiloxytrisiloxane, sold in particular under the reference Dow Corning 556 Cosmetic Grade Fluid (DC556). ii) the nonvolatile phenyl silicone oils having no dimethicone fragment corresponding to the formula (IIIii) below: ## STR2 ## in which R 3 Si-CH 3 RS Si m - R, independently of one another, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon radicals, preferably R is a C1-C30 alkyl radical, an aryl radical, preferably a C6-C14 radical; , or an aralkyl radical whose alkyl part is C 1 -C 3). m and n are, independently of each other, integers between 0 and 100, provided that the sum n + m is between 1 and 100.

Preferably, R, independently of one another, represent a saturated or unsaturated, linear or branched, preferably saturated, C1-C30 hydrocarbon radical, and in particular a hydrocarbon radical, preferably saturated, Ci-C20, in particular in C 1 -C 10 and more particularly in C 4 -C 10, a C 6 -C 14 aryl radical which is monocyclic or polycyclic and in particular C 10 -C 13, or an aralkyl radical, preferably the aryl part is C 6 and the alkyl part is C 1 -C 3) . Preferably, the R may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical.

The R may in particular be identical, and furthermore may be a methyl radical. Preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may be applied, in formula (IIIii).

According to a preferred embodiment, n is an integer between 0 and 100 and m is an integer between 1 and 100, provided that the sum n + m is between 1 and 100, in the formula (IIIii). Preferably R is a methyl radical. According to one embodiment, a phenyl silicone oil of formula (IIIii) having a viscosity at 25 ° C of between 5 and 1500 mm 2 / s (i.e., from 5 to 1500 cSt), and preferably having a viscosity of between 5 and 1000 mm 2 / s (i.e. 5 to 1000 cSt) can be used. According to this embodiment, the nonvolatile phenyl silicone oil is preferably chosen from phenyltrimethicones (when n = 0) such as DC556 from Dow Corning (22.5 cSt), or from diphenylsiloxyphenyltrimethicone oil (when m and n are between 1 and 100) such as KF56 A from Shin Etsu, Silbione 70663V30 from Rhône-Poulenc (28 cSt). Values in parentheses represent viscosities at 25 ° C. (d) the phenyl silicone oils corresponding to the following formula (IV): ## STR1 ## in which: R1, R2, R5 and R6 are, identical or different, an alkyl radical containing 1 to 6 carbon atoms, R5 and R6 not simultaneously representing a methyl radical, R3 and R4 are, identical or different, an alkyl radical containing from 1 to 6 carbon atoms or an aryl (preferably C 6 -C 14) radical, provided that at least one of R 3 and R 4 is a phenyl radical, X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical, n and p being an integer greater than or equal to 1, chosen so as to give the oil a weight average molecular weight of less than 200 000 g / mol, preferably less than 150 000 g / mol and more preferably less than 100,000 g / mol. Preferably, the first oil is chosen from oils of formula (II) or (III), as well as mixtures thereof, and even more preferably, from silicone phenyl oils of formulas (IIa), (Mi), in particular formula (B), (IIIii), and mixtures thereof. When the composition comprises such non-volatile phenyl silicone oil (s) without dimethicone fragment, their content is between 10 and 50% by weight, preferably from 15 to 40% by weight, relative to the weight of the composition. Phenyl silicone nonvolatile oils comprising at least one dimethicone fragment According to another variant of the invention, the composition comprises at least one phenylated silicone nonvolatile oil having at least one dimethicone fragment. The definitions recalled in the context of the description of phenyl silicone oils without dimethicone fragment remains valid and will not be resumed again. As non-volatile silicone oil phenylated with at least one dimethicone fragment, suitable for the present invention, mention may be made of the following oils, alone or as mixtures: a) the phenyl silicone oils corresponding to the following formula (I '): Where R in which the monovalent or divalent R groups represent, independently of one another, a methyl or a phenyl, provided that at least one R group is present; represents a phenyl and that the formula (I ') comprises at least one dimethicone moiety. Preferably, in this formula, the phenylsilicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six. b) the phenyl silicone oils corresponding to the following formula (II '): RRR R-Si-O Si-O-Si-RRRR (II') in which the R groups represent, independently of one another, a methyl or phenyl, provided that at least one R is phenyl and that the formula (II ') comprises at least one dimethicone moiety.

Preferably, in this formula, the compound of formula (II ') comprises at least three phenyl groups, for example at least four or at least five. Mixtures of different phenylorganopolysiloxane compounds previously described may be used.

Examples which may be mentioned include mixtures of triphenyl-, tetraphenyl- or pentaphenyl-organopolysiloxanes. (III ') wherein Me is methyl, y is between 1 and 1000 and X is -CH2-CH (CH3) (Ph). c) the phenyl silicone oils corresponding to the following formula (III '): ## STR1 ## d) the phenyl silicone oils corresponding to formula (IV') below: ## STR1 ## Wherein R 1 to R 10, independently of one another, are C 1 -C 30 hydrocarbon radicals, wherein R 1 to R 10, independently of one another, are C 1 -C 30 hydrocarbon radicals; saturated or unsaturated, linear, cyclic or branched, - m, n, p and q are, independently of each other, integers between 0 and 900, provided that the sum m + n + q is different from 0; the formula (IV ') comprising at least one dimethicone fragment. Preferably, the sum m + n + q is between 1 and 100. Advantageously, the sum m + n + p + q is between 1 and 900 and preferably between 1 and 800. Preferably, q is equal to 0 More particularly, R1 to R10, independently of one another, represent a linear or branched, saturated or unsaturated, preferably saturated, C1-C30 hydrocarbon radical, and in particular a hydrocarbon radical, preferably saturated, C1-C20 in particular Ci-Cis, or a C6-C14 aryl radical and in particular C10-C13, monocyclic or polycyclic, or an aralkyl radical preferably whose alkyl part is C 1 -C 3. Preferably, R 1 to R 10 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. R1 to R10 may in particular be identical, and may furthermore be a methyl radical. According to a more particular embodiment of the formula (IV '), mention may be made of phenyl silicone oils corresponding to the formula (IV'i) below: H 3 C-Si-O R 2 Si-O O Si (CH 3) 3 Si-CH 3 R 6 m (IV '1) 3 Si-O R 4 p in which: R 1 to R 6, independently of one another, are saturated or unsaturated, linear, cyclic or branched C 1 -C 30 hydrocarbon radicals, aryl radical, preferably C6-C14, or an aralkyl radical whose alkyl part is C 1 -C 3). m, n and p are, independently of each other, integers between 0 and 100, provided that the sum n + m is between 1 and 100, the formula (IV'i) comprising at least one fragment dimethicone. Preferably, R 1 to R 6, independently of one another, represent a hydrocarbon radical, preferably C 1 -C 20 alkyl, in particular C 1 -C 18, or a monocyclic C 6 -C 14 aryl radical (preferably C6) or polycyclic and in particular C10-C13, or an aralkyl radical (preferably the aryl part is C6, the alkyl part is C1-C3); the formula (IV'i) comprising at least one dimethicone fragment. Preferably, R 1 to R 6 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical; the formula (IV'i) comprising at least one dimethicone fragment. R1 to R6 may in particular be identical, and may furthermore be a methyl radical. Preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may be applied, in the formula (IV'i). Preferably, the phenyl silicone oils that can be used as the second oil in the context of the invention, correspond to compounds of formula (IV'i) in which: A) m = 0 and n and p are independently of one another, integers between 1 and 100. From preferably R1 to R6 are methyl radicals. According to this embodiment, the silicone oil is preferably chosen from a diphenyldimethicone such as KF-54 from Shin Etsu (400 cSt), KF54HV from Shin Etsu (5000 cSt), KF-50-300CS from Shin Etsu (300 cSt) ), KF-53 from Shin Etsu (175cSt), KF-50-100CS from Shin Etsu (100 cSt). B) p is between 1 and 100, the sum n + m is between 1 and 100, and n = 0. These silicone phenylated oils with or without at least one dimethicone fragment more particularly correspond to the formula (B) below: ## STR2 ## in which Me Me is methyl and Ph is phenyl, OR 'represents a group -OSiMe3 and p is from 1 to 1000, and m is from 1 to 1000. In particular, m and p are such that the compound (B) is a non volatile.

According to a particular embodiment, the non-volatile phenyl silicone oil is such that p is between 1 and 1000, m being more particularly such that the compound (B) is a non-volatile oil. It can be used, for example, trimethylsiloxyphenyldimethicone, sold in particular under the reference Belsil PDM 1000 by the company Wacker. (e) the phenyl silicone oils corresponding to the following formula (V '): ## STR5 ## in which: R1, R2, R5 and R6 are identical; or not, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, identical or different, an alkyl radical containing from 1 to 6 carbon atoms or an aryl radical (preferably C6-C14), provided at least one of R3 and R4 is a phenyl radical, X is an alkyl radical containing 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical, n and p being an integer greater than or equal to 1, chosen so as to impart to the oil a weight average molecular weight of less than 200,000 g / mol, preferably less than 150,000 g / mol and more preferably less than 100,000 g / mol; the formula (V ') comprising at least one dimethicone moiety.

Preferably, the second oil is chosen from oils of formula (IV '), more particularly of formula (IV'i), and preferably oils according to variants (A) and (B), and mixtures thereof. When the composition comprises at least one non-volatile phenyl silicone oil, their content is between 5 and 20% by weight, preferably 5 to 15% by weight, relative to the weight of the composition. According to a particularly advantageous embodiment, the composition comprises at least one phenyl silicone oil free of a dimethicone moiety and at least one phenyl silicone oil with at least one dimethicone moiety. ADDITIONAL NON-VOLATILE OILS The composition according to the invention may also comprise at least one additional non-volatile oil. More particularly, this or these additional non-volatile oils may be chosen from non-volatile hydrocarbon oils, polar or apolar or from non-volatile silicone oils non-phenylated, and mixtures thereof. Non-volatile polar hydrocarbon oils The term "hydrocarbon-based oil" means an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and non-carbon atoms. atom of silicon or fluorine. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups. Preferably, the hydrocarbon oil is free, in addition to silicon, of fluorine; heteroatoms such as N, Si and P. The hydrocarbon oil is therefore distinct from a silicone oil and a fluorinated oil. In this case, the non-volatile hydrocarbon oil comprises at least one oxygen atom. In particular, this non-volatile hydrocarbon oil comprises at least one alcohol function (it is then an "alcohol oil") and / or at least one ester function (it is then an "ester oil") .

The ester oils that can be used in the compositions according to the invention can in particular be hydroxylated. The composition may comprise one or more non-volatile hydrocarbon oils, in particular chosen from: - C 1 -C 10 alcohols, preferably monoalcohols; More particularly, the C 10 -C 26 alcohols are saturated or unsaturated, branched or unbranched, and comprise from 10 to 26 carbon atoms. Preferably, the C 10 -C 26 alcohols are fatty alcohols, preferably branched when they comprise at least 16 carbon atoms. As examples of fatty alcohols that can be used according to the invention, mention may be made of linear or branched fatty alcohols of synthetic origin, or else natural, for example alcohols derived from vegetable matter (copra, palm kernel, palm ...) or animal (tallow ...).

Of course, other long-chain alcohols may also be used, such as, for example, ether-alcohols or even so-called Guerbet alcohols. Finally, it is also possible to use certain longer or shorter cuts of alcohols of natural origin, such as for example coco (C12 to C16) or tallow (C16 to C18) or diol or cholesterol type compounds.

It is preferable to use a fatty alcohol comprising from 10 to 24 carbon atoms, and more preferably from 12 to 22 carbon atoms. As particular examples of fatty alcohols that may be used as preferred, mention may be made especially of lauryl alcohol, isostearyl alcohol, oleic alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol and isoketyl alcohol. octyldodecanol and their mixtures. According to an advantageous embodiment of the invention, the alcohol is chosen from octyldodecanol. monoesters, diesters, triesters, optionally hydroxylated, of a C2-C8 mono or polycarboxylic acid and of a C2-C8 alcohol. In particular: monoesters of a C2-C8 carboxylic acid and of a C2-C8 alcohol, optionally hydroxylated, diesters of a C2-C8 dicarboxylic acid and of a C2-C8 alcohol, optionally hydroxylated; such as diisopropyl adipate, 2-diethylhexyl adipate, dibutyl adipate, or diisostearyl adipate, 2-diethylhexyl succinate, triesters of a C2-C8 triacidecarboxylic acid and a C2 alcohol. -C8, optionally hydroxylated, such as citric acid esters, such as trioctyl citrate, triethyl citrate, acetyl tributyl citrate, tributyl citrate, acetyl tributyl citrate, esters of a C2-C8 polyol and one or more C 2 -C 8 carboxylic acids, such as glycol and monoacid diesters, such as neopentyl glycol diheptanoate, or glycol and monoacid triesters such as triacetin. ester oils, in particular having at least 18 carbon atoms and even more particularly between 18 and 70 carbon atoms. By way of examples, mention may be made of mono-, di- or tri-esters.

The ester oils may be hydroxylated or not. The non-volatile ester oil may be chosen for example from: monoesters comprising at least 18 carbon atoms and even more particularly having from 18 to 40 carbon atoms in total, in particular monoesters, of formula R 1 COROR 2 in which R 1 represents the remainder of a linear or branched or aromatic fatty acid having from 4 to 40 carbon atoms, saturated or unsaturated, and R2 represents a particularly branched hydrocarbon-based chain containing from 4 to 40 carbon atoms, provided that the sum of the carbon atoms radicals R1 and R2 are greater than or equal to 18, such as, for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12-C15 alcohol benzoate, 2- ethyl palmitate, hexyl, octyledodecyl neopentanoate, octy1-2 dodecyl stearate, 2-octyldodecyl erucate, isostearyl isostearate, C12-C15 alkyl benzoate, such as octyl benzoate -2 dodecyl, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, 2-ethylhexyl palmitate, 2-hexyl-decyl laurate , 2-octyl decyl palmitate, 2-octyldodecyl myristate. Preferably, they are esters of formula R 1 COROR 2 in which R 1 represents the residue of a linear or branched fatty acid containing from 4 to 40 carbon atoms and R 2 represents a hydrocarbon chain, especially branched, containing from 4 to 40 carbon atoms. , R1 and R2 being such that the sum of the carbon atoms of the radicals R1 and R2 is greater than or equal to 18. Even more particularly, the ester comprises between 18 and 40 carbon atoms in total. As preferred monoesters, mention may be made of isononyl isononanoate, oleyl erucate and / or octy1-2-docecyl neopentanoate; fatty acid monoesters, in particular having at least 18 carbon atoms and even more particularly from 18 to 22 carbon atoms, and in particular lanolinic acid, oleic acid, lauric acid, stearic acid, , and diols, such as propylene glycol monoisostearate. diesters, especially having at least 18 carbon atoms and even more particularly comprising between 18 and 60 carbon atoms in total, in particular between 18 and 50 carbon atoms in total. Diesters of dicarboxylic acid and of monoalcohols, such as diisostearyl malate, or diesters of glycol and of monocarboxylic acids, such as neopentyl glycol diheptanoate, propylene glycol dioctanoate, diethylene glycol diisononanoate, or polyglyceryl-2-diisostearate (especially such as the compound sold under the commercial reference DERMOL DGDIS by the company Akzo); hydroxylated monoesters and diesters, preferably having a total carbon number of at least 18 carbon atoms and even more particularly ranging from 18 to 70, such as polyglyceryl-3-diisostearate, isostearyl lactate, octylhydroxystearate; octyldodecyl hydroxystearate, diisostearyl malate, glycerin stearate; * triesters, especially comprising between 35 and 70 carbon atoms in total, in particular such as triesters triacidecarboxylic acid, such as triisostearyl citrate, or tridecyl trimellitate, or triesters of glycol and monocarboxylic acids such as triisostearate polyglycerol-2; tetraesters, in particular having a total number of carbon ranging from 35 to 70, such as tetraesters of penthaerythritol or of polyglycerol and of a monocarboxylic acid, for example such as pentaerythrityl tetrapelargonate, pentaerythrityl of tetraisostearate, tetraisononate of pentaerythrityl, glyceryl 2-decyltetradecanoate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetra decyl-2 tetradecanoate; the polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and of diol, such as those described in the patent application FR 0 853 634, such as in particular dilinoleic acid and 1,4-diol. butanediol. Mention may in particular be made of the polymer marketed by Biosynthis under the name Viscoplast 14436H (INCI name: dilinoleic acid / butanediol copolymer), or the copolymers of polyols and diacid dimers, and their esters, such as Hailucent ISDA; esters and polyesters of diol dimer and mono- or dicarboxylic acid, such as diol dimer and fatty acid esters and diol dimer and dicarboxylic acid dimer esters, in particular obtainable from a dicarboxylic acid dimer derived in particular from the dimerization of an unsaturated fatty acid, especially from C8 to C34, in particular from C12 to C22, in particular from C16 to C20, and more particularly from C18, such as the esters of dilinoleic diacids and of dilinoleic diol dimers, for example such as those marketed by the company NIPPON FINE CHEMICAL under the trade name LUSPLAN DD-DA5® and DD-DA7®; the polyesters resulting from the esterification of at least one triglyceride of carboxylic acid (s) hydroxylated with an aliphatic monocarboxylic acid and with an optionally unsaturated aliphatic dicarboxylic acid, such as castor oil; succinic acid and isostearic acid sold under the reference Zénigloss by Zenitech; vegetable hydrocarbon-based oils such as triglycerides of fatty acids (liquid at room temperature), in particular of fatty acids having from 7 to 40 carbon atoms, such as triglycerides of heptanoic or octanoic acids or jojoba oil, in particular, there may be mentioned saturated triglycerides such as caprylic / capric triglyceride and mixtures thereof, for example such as that marketed under the reference Myritol 318 from Cognis, glyceryl triheptanoate, glycerin trioctanoate, acid triglycerides, C18-36 such as those marketed under the reference DUB TGI 24 marketed by Stéarineries Dubois), and unsaturated triglycerides such as castor oil, olive oil, ximenia oil, pracaxi oil. vinylpyrrolidone / 1-hexadecene copolymers, such as for example that sold under the name ANTARON V-216 (also called Ganex V216) by the company ISP (MW = 7300 g / mol). - C -C, preferably C 12 -C 22 fatty acids, preferably unsaturated, such as oleic acid, linoleic acid, linolenic acid, and mixtures thereof. The di-alkyl carbonates, the 2 alkyl chains being identical or different, such as the dicaprylyl carbonate sold under the name Cetiol CC®, by Cognis. - and their mixtures. Apolar Nonvolatile Hydrocarbon Oils The composition according to the invention may also comprise at least one apolar nonvolatile hydrocarbon oil. These oils can be of vegetable, mineral or synthetic origin. For the purposes of the present invention, the term "apolar oil" means an oil whose solubility parameter at 25 ° C., Sa, is equal to 0 (J / cm 3) 1/4. The definition and calculation of the solubility parameters in the HANSEN three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensional solubility parameters" J. Paint Technol. 39, 105 (1967).

According to this Hansen space: - 8D characterizes the LONDON dispersion forces resulting from the formation of dipoles induced during molecular shocks; - 8p characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles; - St, characterizes the specific interaction forces (hydrogen bond, acid / base, donor / acceptor type, etc.); and - 8a is determined by the equation: δa = (S1) 2 8h2) 1/4 The parameters 8p, 811, 8D and Sa are expressed in (J / cm3) 1/4.

By "hydrocarbon oil" is meant an oil formed essentially, or even constituted, of carbon and hydrogen atoms, and possibly of oxygen, nitrogen, and not containing a silicon atom or fluorine. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

Preferably, the non-volatile apolar hydrocarbon oil may be chosen from linear or branched hydrocarbons of mineral or synthetic origin such as: paraffin oil or its derivatives, squalane, isoeicosane, naphthalene oil, polybutenes such as INDOPOL H-100 (molar mass or MW = 965 g / mol), INDOPOL H-300 (MW = 1340 g / mol), INDOPOL H- 1500 (MW = 2160g / mol) sold or manufactured by the company AMOCO, polyisobutenes, hydrogenated polyisobutenes such as Parleam® sold by the company Nippon Oil Fats, PANALANE H-300 E marketed or manufactured by the company AMOCO ( MW = 1340 g / mol), the Viseal 20000 marketed or manufactured by SYNTEAL (MW = 6000 g / mol), the REWOPAL PIB 1000 marketed or manufactured by WITCO (MW = 1000 g / mol), or the PARLEAM LITE marketed by NOF Corporation, - decene / butene copolymers, polybutene copolymers polyisobutene, in particular Indopol L-14, polydecenes and hydrogenated polydecenes, such as PURESYN 10 (MW = 723 g / mol) and PURESYN 150 (MW = 9200 g / mol) marketed or manufactured by MOBIL. CHEMICALS, or PURESYN 6 sold by EXXONMOBIL CHEMICAL), and mixtures thereof. Non-phenylated Non-volatile Silicone Oils The term "non-phenyl silicone oil" refers to a silicone oil having no phenyl substituent. Representative examples of such non-volatile, non-phenolic silicone oils which may be mentioned include polydimethylsiloxanes; alkyldimethicones; vinylmethylmethicones; and also silicones modified with aliphatic groups and / or with functional groups such as hydroxyl, thiol and / or amine groups. Note that "dimethicone" (INCI name) corresponds to a poly (dimethylsiloxane) (chemical name).

The non-phenylated non-volatile silicone oil is preferably chosen from non-volatile dimethicone oils. In particular, these oils may be chosen from the following non-volatile oils: polydimethylsiloxanes (PDMSs), PDMSs comprising aliphatic groups, in particular alkyl, or alkoxy groups, which are pendant and / or at the end of the silicone chain ; these groups each comprising from 2 to 24 carbon atoms. By way of example, mention may be made of the cetyldimethicone sold under the trade name ABIL WAX 9801 from Evonik Goldschmidt, PDMSs comprising aliphatic groups, or functional groups such as hydroxyl, thiol and / or amine groups, and polyalkylmethylsiloxanes. substituted with functional groups such as hydroxyl, thiol and / or amine groups, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, and mixtures thereof.

Preferably, these non-volatile, non-phenyl silicone oils are chosen from polydimethylsiloxanes; alkyldimethicones and also PDMSs comprising aliphatic groups, in particular C 2 -C 24 alkyl, and / or functional groups such as hydroxyl, thiol and / or amine groups.

The non-phenyl silicone oil may be chosen in particular from silicones of formula (I): ## STR2 ## in which: R 1, R 1 R2, R5 and R6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, a vinyl radical, an amine radical or a hydroxyl radical, X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, n and p are integers chosen so as to have a fluid compound, in particular having a viscosity at 25 ° C. is between 9 centistokes (cSt) (9 x 10-6 m2 / s) and 800,000 cSt.

As non-volatile, non-phenyl silicone oils which can be used according to the invention, mention may be made of those for which: the substituents R 1 to R 6 and X represent a methyl group, and p and n are such that the viscosity is of 500 000 cSt, for example the product marketed under the name SE30 by the company General Electric, the product marketed under the name AK 500000 by the company Wacker, the product marketed under the name Mirasil DM 500 000 by the company Bluestar , and the product sold under the name Dow Corning 200 Fluid 500 000 cSt by Dow Corning, - substituents R1 to R6 and X are methyl, and p and n are such that the viscosity is 60,000 cSt, for example the product marketed under the name Dow Corning 200 Fluid 60000 CS by the company Dow Corning, and the product marketed under the name Wacker Belsil DM 60 000 by the company Wacker, - substituents R1 to R6 and X represents have a methyl group, and p and n are such that the viscosity is 100 cSt or 350 cSt, for example the products marketed under the trade names Belsil DM100, Dow Corning 200 Fluid 350 CS, by Dow Corning, respectively. the substituents R 1 to R 6 represent a methyl group, the X group represents a hydroxyl group, and n and p are such that the viscosity is 700 cSt, for example the product sold under the name Baysilone Fluid T0.7 by the Momentive company. Preferably, if the composition comprises at least one additional nonvolatile oil, the latter is chosen from polar nonvolatile oils, and in particular ester oils. If the composition comprises one or more additional nonvolatile oils, then their content represents from 2 to 20% by weight, preferably from 2 to 15% by weight, relative to the total weight of the composition. COLORING USES A composition according to the present invention may comprise at least one dyestuff which may be chosen from water-soluble or non-fat soluble or non-soluble, organic or inorganic dyestuffs, optical effect materials, and mixtures thereof.

For the purposes of the present invention, the term "dyestuff" means a compound capable of producing a colored optical effect when it is formulated in sufficient quantity in a suitable cosmetic medium. The water-soluble dyestuffs used according to the invention are more particularly water-soluble dyes.

For the purposes of the invention, the term "water-soluble dye" is intended to mean any generally organic compound, natural or synthetic, soluble in an aqueous phase or solvents that are miscible with water and capable of coloring. In particular, it is intended to characterize, by the term water-soluble, the ability of a compound to solubilize in water, measured at 25 ° C., at a concentration of at least 0.1 g / l (obtaining a macroscopically isotropic and transparent solution, colored or not). This solubility is in particular greater than or equal to 1 g / l. As water-soluble dyes that are suitable for the invention, water-soluble synthetic or natural dyes, such as, for example, FDC Red 4 (CI: 14700), DC Red 6 (Lithol Rubine Na, CI: 15850), DC can be mentioned. Red 22 (CI: 45380), DC Red 28 (CI: 45410 Na salt), DC Red 30 (CI: 73360), DC Red 33 (CI: 17200), DC Orange 4 (CI: 15510), FDC Yellow 5 (CI: 19140), FDC Yellow 6 (CI: 15985), DC Yellow 8 (CI: 45350 Na Salt), FDC Green 3 (CI: 42053), DC Green 5 (CI: 61570); ), FDC Blue 1 (CI: 42090). By way of non-limiting illustration of sources of water-soluble dye (s) that may be used in the context of the present invention, mention may be made especially of those of natural origin, such as extracts of carmine, cochineal, beetroot, grape, carrot, tomato, annatto, paprika, henna, caramel and curcumin. Thus, the water-soluble dyestuffs that are suitable for the invention are in particular carminic acid, betanine, anthocyanins, enocyanines, lycopene, beta-carotene, bixin, norbixin, capsanthin, capsulubin, flovoxanthine, lutein, cryptoxanthin, rubixanthine, violaxanthin, riboflavin, roudoxanthin, cantaxanthin, chlorophyll, and mixtures thereof. It may also be copper sulphate, iron, water-soluble sulphopolyesters, rhodamine, betaine, methylene blue, disodium salt of tartrazine and sodium salt of fuschine. Some of these water-soluble dyestuffs are in particular approved for food. As a representative of these dyes, mention may be made more particularly of the dyes of the family of carotenoids, referenced under the food codes E120, E162, E163, E160a-g, E150a, E101, E100, E140 and E141. According to a particularly preferred embodiment, the one or more water-soluble dyestuff (s) are chosen from the di-sodium salt of the brilliant yellow FCF marketed by the company LCW under the name DC Yellow 6, the di-sodium salt. -sodium acid fuchsin D sold by the company LCW under the name DC Red 33, the tri-sodium salt of Allura Red marketed by LCW under the name FD & C Red 40. By pigments, it is necessary to include white particles or colored, inorganic (mineral) or organic, insoluble in the liquid organic phase, intended to color and / or opacify the composition and / or the deposition carried out with the composition. The pigments may be chosen from inorganic pigments, organic pigments, and composite pigments (that is to say pigments based on mineral and / or organic materials).

The pigments may be chosen from monochromatic pigments, lacquers, pearlescent agents, optical effect pigments, such as reflecting pigments and goniochromatic pigments. The inorganic pigments may be chosen from metal oxide pigments, chromium oxides, iron oxides, titanium dioxide, zinc oxides, cerium oxides, zirconium oxides, manganese violet, prussian blue, ultramarine blue, ferric blue, and their mixtures. Organic lakes are organic pigments formed of a dye attached to a substrate.

Lacquers which are also called organic pigments can be chosen from the following materials and their mixtures: - cochineal carmine; organic pigments of azo, anthraquinone, indigo, xanthene, pyrenic, quinoline, triphenylmethane and fluoran dyes. Among the organic pigments, mention may be made of those known under the following names: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10, D & C Orange No. 11, D & C Red No. 6, D & C Red No. 7, D & C Red No. 17, D & C Red No. 21, D & C Red No. 22, D & C Red No. 27, D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40, FD & C Yellow No. 5, FD & C Yellow No. 6; organic lakes may be insoluble salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo, anthraquinone, indigo, xanthene, pyrenic dyes , quinoliniques, triphenylmethane, fluoran, these dyes may comprise at least one carboxylic or sulfonic acid group. Organic lacquers may also be supported by an organic carrier such as rosin or aluminum benzoate, for example. Among the organic lakes, mention may be made in particular of the following denominations: D & C Red No. 2 Aluminum Lake, D & C Red No. 3 Aluminum Lake, D & C Red No. 4 Aluminum Lake, D & C Red No. 6 Aluminum Lake, D & C Red # 6 Barium Lake, D & C Red # 6 Barium / Strontium Lake, D & C Red # 6 Strontium Lake, D & C Red # 6 Potassium Lake, D & C Red # 7 Aluminum Lake, D & C Red # 7 Barium Lake, D & C Red # 7 Calcium Lake, D & C Red # 7 Calcium / Strontium Lake, D & C Red # 7 Zirconium Lake, D & C Red # 8 Sodium Lake, D & C Red # 9 Aluminum Lake, D & C Red # 9 Barium Lake, D & C Red # 9 Barium / Strontium Lake, D & C Red # 9 Zirconium Lake, D & C Red # 10 Sodium Lake, D & C Red # 19 Aluminum Lake, D & C Red # 19 Barium Lake, D & C Red # 19 Zirconium Lake, D & C Red # 21 Aluminum Lake, D & C Red # 21 Zirconium Lake, D & C Red # 22 Aluminum Lake, D & C Red # 27 Aluminum Lake, D & C Red # 27 Aluminum / Titanium / Zirconium Lake, D & C Red # 27 Barium Lake , D & C Red # 27 Calcium Lake, D & C Red # 27 Zirconium Lake, D & C Red # 28 Aluminum Lake, D & C Red # 30 Lake, D & C Red # 31 Calcium Lake, D & C Red # 33 Aluminum Lake, D & C Red # 34 Calcium Lake, D & C Red # 36 Lake, D & C Red # 40 Aluminum Lake, D & C Blue # 1 Aluminum Lake, D & C Green # 3 Aluminum Lake, D & C Orange # 4 Aluminum Lake, D & C Orange # 5 Aluminum Lake, D & C Orange # 5 Zirconium Lake, D & C Orange No. 10 Aluminum Lake, D & C Orange No. 17 Barium Lake, D & C Yellow No. 5 Aluminum Lake, D & C Yellow No. 5 Zirconium Lake, D & C Yellow No. 6 Aluminum Lake, D & C Yellow No. 7 Zirconium Lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red # 40 Aluminum Lake, FD & C Yellow # 5 Aluminum Lake, FD & C Yellow # 6 Aluminum Lake. Mention may also be made of liposoluble dyes such as, for example, Sudan Red, DC Red 17, DC Green 6, (3-carotene, soya oil, Sudan Brown, DC Yellow 11, DC Violet 2 the orange DC 5, the yellow quinoline The chemical materials corresponding to each of the organic dyestuffs mentioned above are mentioned in the book "International Cosmetic Ingredient Dictionary and Handbook", Edition 1997, pages 371 to 386 and 524 to 528, published by The Cosmetic, Toiletry, and Fragrance Association, the contents of which are incorporated herein by reference The pigments may also have undergone a hydrophobic treatment The hydrophobic treatment agent may be chosen from silicones such as meticones, dimethicones, perfluoroalkylsilanes, fatty acids such as stearic acid, metal soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate, perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amino acids; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zin, sodium or potassium salts. The amino acid may be, for example, lysine, glutamic acid or alanine. The alkyl term mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 atoms. of carbon.

Hydrophobic-treated pigments are described in particular in patent application EP-A-1086683. For the purposes of the present application, "mother-of-pearl" means colored particles of any shape, iridescent or otherwise, in particular produced by certain shellfish in their shell or well synthesized and which exhibit a color effect by optical interference. Examples of pearlescent agents include pearlescent pigments such as iron oxide-coated titanium mica, bismuth oxychloride-coated mica, titanium mica coated with chromium oxide, titanium mica coated with a organic dye including the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.

It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection.

As an illustration of nacres that can be introduced as interference pigment in the first composition, mention may be made of gold-colored pearlescent agents marketed by ENGELHARD under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the name Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres sold especially by the company Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company Merck under the name Passion Orange (Colorona) and Matte Orange (17449) (Microna); brown-colored pearlescent agents marketed by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearlescent agents with a gold glint sold especially by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres sold especially by Engelhard under the name Tan opal G005 (Gemtone); the black nacres with gold reflection sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company Merck under the name Matte Blue (17433) (Microna), the white nacres with reflection silver sold in particular by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl marketed by Merck under the name Indian summer (Xirona) and their mixtures. Advantageously, the content of dyestuff (s) represents from 0.1 to 25% by weight, more precisely from 0.1 to 15% by weight, relative to the total weight of the composition. LOADS The composition according to the invention may optionally comprise at least one or more filler (s) of organic or mineral nature. By "filler" is meant colorless or solid white particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition. Of mineral or organic nature, they make it possible to impart body or stiffness to the composition and / or softness, and uniformity to makeup. The fillers used in the compositions according to the present invention may be of lamellar, globular, spherical, fiber or any other form intermediate between these defined forms. The fillers according to the invention may or may not be superficially coated, and in particular they may be surface-treated with silicones, amino acids, fluorinated derivatives or any other substance which promotes dispersion and compatibility of the filler. the composition. Examples of mineral fillers that may be mentioned include talc, mica, silica, hollow silica microspheres, kaolin, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, glass microcapsules or ceramic, composites of silica and titanium dioxide, such as the TSG series marketed by Nippon Sheet Glass. Examples of organic fillers that may be mentioned are polyamide powders (Nylon® Orgasol from Atochem), polyethylene, poly methyl methacrylate, polytetrafluoroethylene (Teflon) powders, copolymers of acrylic acid (Polytrap from the company). Dow Corning), lauroyl lysine, polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as Expancel (Nobel Industry), hexamethylene diisocyanate / Trimethylol hexyllactone copolymer powder (Toshiki Plastic Powder), microbeads silicone resin (Toshiba Tospearl, for example) synthetic or natural micronized waxes, metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example, zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate, Polypore® L 200 (Chemdal Corporation), powder cross-linked elastomeric organopolysiloxane coated with silicone resin, especially silsesquioxane resin, as described for example in US Pat. No. 5,538,793, polyurethane powders, in particular cross-linked polyurethane powders comprising a copolymer, said copolymer comprising trimethylol hexyllactone. In particular, it may be a hexamethylene diisocyanate / trimethylol hexyllactone polymer. Such particles are in particular commercially available, for example, under the name PLASTIC POWDER D-400® or PLASTIC POWDER D-800® from TOSHIKI, and mixtures thereof. According to one particular embodiment of the invention, the composition comprises at least one crosslinked elastomeric organopolysiloxane powder coated with silicone resin. The presence of this filler also makes it possible to thicken and / or gel the composition of the invention. Mention may in particular be made of crosslinked elastomeric organopolysiloxane powders coated with silicone resin, in particular with silsesquioxane resin, as described, for example, in US Pat. No. 5,538,793. Such elastomer powders are sold under the names KSP-100®. KSP-101®, KSP-102®, KSP-103®, KSP-104® and KSP-105® by SHIN ETSU; mention may also be made of crosslinked elastomeric organopolysiloxane powders coated with silicone resin such as hybrid silicone powders functionalized with fluoroalkyl groups, especially sold under the name "KSP-200" by the company Shin Etsu; or hybrid silicone powders functionalized with phenyl groups, especially sold under the name "KSP-300" by the company Shin Etsu. A composition used according to the invention may comprise one or more fillers, advantageously in a content ranging from 0.1% to 15% by weight, in particular from 1% to 10% by weight relative to the total weight of the composition. .

ADDITIVES The composition according to the invention may, in addition, comprise all the ingredients conventionally used as additives in the cosmetic and dermatological field.

These additives are advantageously chosen from surfactants, antioxidants, thickeners, sweeteners, alkalizing or acidifying agents of preservatives and mixtures thereof, and may advantageously be chosen from those proposed in Table 1 of the Codex Alimentarius. As an antioxidant, a composition according to the invention may advantageously comprise at least one pentaerythritol-di-tbutyl hydroxycinnamate. A composition according to the invention may further contain aromas and / or fragrances. As cosmetic active agents that can be used in the invention, mention may be made of solar filters, vitamins A, E, C, B3, provitamines such as D-panthenol, soothing active agents such as a-bisabolol, aloe vera, allantoin, plant extracts or essential oils, protective or restructuring agents, freshness active ingredients such as menthol and its derivatives, emollients, moisturizers, essential fatty acids, and mixtures thereof. The amounts of each of these different ingredients, if they are present, are those conventionally used in the fields concerned and for example vary from 0.01% to 10% by weight relative to the total weight of the composition. Of course, those skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, impaired by the addition considered. The following example is presented as an illustration and not a limitation of the scope of the invention. EXAMPLE 35 The solid lipstick composition was prepared, the ingredients and proportions of which are summarized in the table below (percentages are by weight of active ingredient): Phenyltrimethicone 44.98 C12-C15 alkyl benzoate 7 Polyphenyltrimethylsiloxy dimethylsiloxane (viscosity: 1000 cSt - MW: 3000 g / mole) 7.54 Butyl acrylate copolymer containing silicone dendritic side chains: Tri ((trimethylsiloxy) siloxyethyldimethylsiloxy) silylpropylmethacrylate in isododecane (40/60) sold under the reference Dow Corning FA 4002 ID by Dow Corning. Linear long chain fatty alcohol (C30-050) 8.8 Candelilla wax 0.2 Isohexadecane 2.00 Pigments 8.00 Perfume 0.08 The pigments are ground in part of the oily phase. Then, in a pan with moderate stirring is introduced at 100 ° C, the remaining oily phase, waxes, isohexadecane and Dow Corning acrylate polymer.

Stirring is maintained until homogenization of the mixture. The composition is then poured into molds and allowed to cool. We obtain a sticky lipstick sliding application, depositing a thin film, comfortable, non-sticky and good performance.

Claims (18)

REVENDICATIONS1. An anhydrous, solid cosmetic composition comprising: a) at least one vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer; b) at least two volatile hydrocarbon oils. 2. Composition according to the preceding claim, characterized in that the vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer has a side molecular chain containing a carbosiloxane dendrimer structure and is derived from the polymerization of: (A) from 0 to 99.9 parts by weight of a vinyl monomer; and (B) from 100 to 0.1 parts by weight of a carbosiloxane dendrimer of the following formula (I): R 1 O-Si-X 'Y-Si 3 (I) wherein: - R 1 represents an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms; X 'represents a silylalkyl group which, when i = 1, is represented by the formula (II): (OR3) al R2 Si R1 O Si X1 + 1 R' 3-a '(II) in which: R1 is as defined above in formula (I), 25. R2 represents an alkylene radical of 2 to 10 carbon atoms, R3 represents an alkyl group of 1 to 10 carbon atoms, X '+' is chosen from: a hydrogen atom, an alkyl group of 1 to 10 carbon atoms, an aryl group of 5 to 10 carbon atoms and a silylalkyl group defined above of formula (II) with i = i + 1, 30. i is an integer from 1 to 10 which represents the generation of said silylalkyl group, and a 'is an integer from 0 to 3; Y represents an organic group polymerizable with radicals chosen from: organic groups containing a methacrylic group or an acrylic group, said organic groups being represented by the following formulas: ## STR1 ## hydrogen or an alkyl group of 1 to 10 carbon atoms; and * R5 represents an alkylene group of 1 to 10 carbon atoms; and. styryl group-containing organic groups of the formula: wherein: R 6 represents a hydrogen atom or an alkyl group of 1 to 10 carbon atoms; R7 represents an alkyl group of 1 to 10 carbon atoms; R8 represents an alkylene group of 1 to 10 carbon atoms; * b is an integer from 0 to 4; and * c is 0 or 1, so that if c is 0, - (R), - represents a bond. 3. Composition according to the preceding claim, wherein the carbosiloxane dendrimer is represented by the following formula: ## STR2 ## If R Si R 1 -O Si R 12 R 1 R 1 R 1 3-a 3-a 2 3-a 1 -3 wherein: Y, R1, R2 and R3 are as defined in claim 4; . al, a2 and a3 are as defined in claim 24; and. R'2 is H, an aryl group of 5 to 10 carbon atoms or an alkyl group of 1 to 10 carbon atoms. 4. The composition according to claim 2, wherein the carbosiloxane dendrimer is represented by one of the following formulas: ## STR1 # Si-CH CH 3, 3H 2 C = CH-CO-C 3 H 6 Si II O CH 3 OH-CH 2 CH 3 CH 3 O-Si-CH 3 CH 3 5. Composition according to any one of the preceding claims, characterized in that the vinyl polymer (s) content (s) represents from 0.5% to 20%, in particular from 1% to 15%, relative to the weight of the composition. 6. Composition according to any one of the preceding claims, characterized in that the volatile hydrocarbon oils are apolar, comprise from 8 to 16 carbon atoms, and are linear or branched alkanes. 7. Composition according to the preceding claim, characterized in that the volatile oil content (s) represents 0.5 to 40% by weight, especially 1 to 30% by weight, relative to the total weight of said composition. . Composition according to any one of the preceding claims, characterized in that it comprises at least one volatile silicone or fluorinated oil, preferably silicone, and more particularly the content of volatile oil (s) silicone (s) or fluorinated (s) is less than 5% by weight, relative to the total weight of said composition; the weight ratio of the silicone or fluorinated volatile oils, and preferably silicone, on the volatile hydrocarbon oil (s), is between 0 and 1 excluded boundary. 8. Composition according to any one of the preceding claims, characterized in that the composition comprises at least at least one solid alcohol, saturated or unsaturated, linear or branched, preferably linear, whose melting temperature is greater than or equal to 40 ° C, comprising from 16 to 60 carbon atoms. 9. Composition according to the preceding claim, characterized in that the content of solid fatty alcohol (s) whose melting temperature is greater than or equal to 40 ° C, represents from 5 to 20% by weight, preferably from 5 to 20% by weight. 15% by weight, even more particularly 7 to 15% by weight, relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one alcohol additive or alcohol derivative selected from: Solid fatty alcohols whose melting temperature is between 25 ° C and lower at 40 ° C-fatty alcohols having at least 14 carbon atoms, linear or branched, saturated or unsaturated, mono-oxyalkylenated or poly-oxyalkylenated C2-C3, solids at 25 ° C. The liposoluble polyethers resulting from the polyetherification between one or more C2-C10, preferably C2-C50 diols, or mixtures thereof. 11. Composition according to the preceding claim, characterized in that the content of additive (s) alcohol or alcohol derivative (s) is between 1 and 10% by weight, preferably between 3 and 7.5% by weight, relative to the total weight of the composition. 12. Composition according to any one of the preceding claims, characterized in that it comprises at least one wax, different solid fatty alcohols whose melting temperature is greater than or equal to 40 ° C, and different additives alcohol or derivatives alcohol, more particularly, selected from polar polar waxes, apolar, or mixtures thereof. 13. Composition according to the preceding claim, characterized in that when the composition comprises, the content of apolar wax is between 0.1 and 5% by weight relative to the composition; and when the composition comprises, the polar wax content is between 0.1 and 5% by weight relative to the composition. 14. Composition according to any one of the preceding claims, characterized in that it comprises at least one nonvolatile silicone oil, phenylated, not comprising a dimethicone fragment, preferably in a content of between 10 and 50% by weight. preferably from 15 to 40% by weight, relative to the weight of the composition. 15. Composition according to any one of the preceding claims, characterized in that the composition comprises one or more additional non-volatile oils chosen from non-volatile hydrocarbon oils, polar or apolar or from non-volatile silicone oils non-phenylated, and mixtures thereof. . 16. Composition according to the preceding claim, characterized in that the content of nonvolatile oil (s) additional (s) is between 2 to 20% by weight, preferably 2 to 15% by weight, relative to the weight of the composition. 17. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one dyestuff, in particular chosen from water-soluble or non-fat soluble or non-liposoluble dyestuffs, organic or inorganic materials, optical effect materials, and their mixtures. 18. A process for making up and / or treating the lips in which the composition according to any one of the preceding claims is applied to the lips.