FR2992229B1 - ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT - Google Patents

ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT

Info

Publication number
FR2992229B1
FR2992229B1 FR1201812A FR1201812A FR2992229B1 FR 2992229 B1 FR2992229 B1 FR 2992229B1 FR 1201812 A FR1201812 A FR 1201812A FR 1201812 A FR1201812 A FR 1201812A FR 2992229 B1 FR2992229 B1 FR 2992229B1
Authority
FR
France
Prior art keywords
aminoethylmorpholines
diamins
tertiary
belonging
family
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1201812A
Other languages
French (fr)
Other versions
FR2992229A1 (en
Inventor
Bruno Delfort
Pennec Dominique Le
Julien Grandjean
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR1201812A priority Critical patent/FR2992229B1/en
Priority to PCT/FR2013/051128 priority patent/WO2014001664A1/en
Publication of FR2992229A1 publication Critical patent/FR2992229A1/en
Application granted granted Critical
Publication of FR2992229B1 publication Critical patent/FR2992229B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
    • C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20452—Cyclic amines containing a morpholine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/502—Combinations of absorbents having two or more functionalities in the same molecule other than alkanolamine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0233—Other waste gases from cement factories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
FR1201812A 2012-06-26 2012-06-26 ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT Expired - Fee Related FR2992229B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1201812A FR2992229B1 (en) 2012-06-26 2012-06-26 ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT
PCT/FR2013/051128 WO2014001664A1 (en) 2012-06-26 2013-05-23 Absorbent solution made from tertiary diamines belonging to the hindered aminoethyl morpholine family and method for eliminating acid compounds from a gaseous effluent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1201812A FR2992229B1 (en) 2012-06-26 2012-06-26 ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT

Publications (2)

Publication Number Publication Date
FR2992229A1 FR2992229A1 (en) 2013-12-27
FR2992229B1 true FR2992229B1 (en) 2015-10-30

Family

ID=46889117

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1201812A Expired - Fee Related FR2992229B1 (en) 2012-06-26 2012-06-26 ABSORBENT SOLUTION BASED ON TERTIARY DIAMINS BELONGING TO THE AMINOETHYLMORPHOLINES FAMILY AND METHOD FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT

Country Status (2)

Country Link
FR (1) FR2992229B1 (en)
WO (1) WO2014001664A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA036128B1 (en) 2016-04-25 2020-10-01 Басф Се Process for removing acid gases from a fluid stream by using morpholine-based hindered amine compounds
CN106496041B (en) * 2016-10-09 2018-08-07 杭州新德环保科技有限公司 Synthesize N, the method for N- diisopropyls -2-chloroethyl amine
WO2018146233A1 (en) 2017-02-10 2018-08-16 Basf Se Process for removal of acid gases from a fluid stream
CN107081052B (en) * 2017-06-13 2019-10-25 中国石油工程建设有限公司 Acid gas absorbent and application containing bis- (3- aminopropyl) polyethylene glycol
JP7101759B2 (en) 2017-09-04 2022-07-15 ビーエーエスエフ ソシエタス・ヨーロピア Absorbents and methods for the selective removal of hydrogen sulfide
CN107935917A (en) * 2017-10-30 2018-04-20 广东莱佛士制药技术有限公司 A kind of synthetic method of 1 (2 chloroethyl) 4 piperidinecarboxylic acid ester
EP3927450B1 (en) 2019-02-18 2023-06-07 Basf Se Process for removal of acid gases from a fluid stream with a liquid absorbent comprising a piperazine ring
CN114173908A (en) 2019-09-10 2022-03-11 巴斯夫欧洲公司 Process for removing acid gases from a fluid stream
CN116745018A (en) * 2021-01-27 2023-09-12 三菱瓦斯化学株式会社 carbon dioxide absorbent
WO2022197605A1 (en) 2021-03-15 2022-09-22 Exxonmobil Upstream Researh Co. Absorbent regeneration processes and units that use diabatically heated stripping plates

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5862374A (en) 1981-10-08 1983-04-13 Ngk Spark Plug Co Ltd Controller for internal-combustion engine
US4405811A (en) 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Severely sterically hindered tertiary amino compounds
US4483833A (en) 1982-01-18 1984-11-20 Exxon Research & Engineering Co. Process for selective removal of H2 S from mixtures containing H22 with heterocyclic tertiary aminoalkanols
EP0124835A3 (en) * 1983-05-04 1987-09-30 Air Products And Chemicals, Inc. Bis tertiary amino alkyl derivatives as solvents for acid gas removal from gas streams
IT1191805B (en) 1986-06-11 1988-03-23 Snam Progetti PROCESS FOR SELECTIVE REMOVAL OF SULPHIDIC ACID
GB2191449A (en) 1986-06-14 1987-12-16 Britax P M G Ltd Motor vehicle with occupant's protection system
DE19947845A1 (en) 1999-10-05 2001-04-12 Basf Ag Processes for removing COS from a hydrocarbon fluid stream and wash liquid for use in such processes
FR2877858B1 (en) * 2004-11-12 2007-01-12 Inst Francais Du Petrole METHOD FOR DEACIDIFYING A GAS WITH A FRACTIONED REGENERATION ABSORBENT SOLUTION
FR2898284B1 (en) * 2006-03-10 2009-06-05 Inst Francais Du Petrole METHOD FOR DEACIDIFYING GAS BY ABSORBENT SOLUTION WITH HEATED FRACTIONAL REGENERATION.
FR2953735B1 (en) * 2009-12-16 2013-03-29 Inst Francais Du Petrole PROCESS FOR REMOVING ACIDIC COMPOUNDS FROM A GASEOUS EFFLUENT WITH AN ABSORBENT SOLUTION BASED ON DIAMINS I, II / III

Also Published As

Publication number Publication date
WO2014001664A1 (en) 2014-01-03
FR2992229A1 (en) 2013-12-27

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Year of fee payment: 4

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Effective date: 20170228