FR2975693A1 - Preparation, useful for conditioning and stabilizing e.g. physical and mechanical properties of soil and/or culture media, comprises mineral components comprising phyllosilicates, and organic carbon comprising plant and/or animal materials - Google Patents
Preparation, useful for conditioning and stabilizing e.g. physical and mechanical properties of soil and/or culture media, comprises mineral components comprising phyllosilicates, and organic carbon comprising plant and/or animal materials Download PDFInfo
- Publication number
- FR2975693A1 FR2975693A1 FR1101590A FR1101590A FR2975693A1 FR 2975693 A1 FR2975693 A1 FR 2975693A1 FR 1101590 A FR1101590 A FR 1101590A FR 1101590 A FR1101590 A FR 1101590A FR 2975693 A1 FR2975693 A1 FR 2975693A1
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- Prior art keywords
- phyllosilicates
- soil
- culture media
- organic
- plant
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052615 phyllosilicate Inorganic materials 0.000 title claims abstract description 24
- 239000002689 soil Substances 0.000 title claims abstract description 19
- 239000001963 growth medium Substances 0.000 title claims abstract description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 13
- 239000011707 mineral Substances 0.000 title claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 4
- 229910052799 carbon Inorganic materials 0.000 title claims description 4
- 239000000463 material Substances 0.000 title description 3
- 230000000087 stabilizing effect Effects 0.000 title description 3
- 230000003750 conditioning effect Effects 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 20
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011591 potassium Substances 0.000 claims abstract description 5
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 239000011575 calcium Substances 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 241000196324 Embryophyta Species 0.000 claims description 17
- 239000011368 organic material Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000005416 organic matter Substances 0.000 claims description 9
- 230000035699 permeability Effects 0.000 claims description 8
- 239000003864 humus Substances 0.000 claims description 5
- 235000013311 vegetables Nutrition 0.000 claims description 4
- 230000031018 biological processes and functions Effects 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 claims description 3
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 239000011121 hardwood Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 238000009738 saturating Methods 0.000 claims description 2
- 239000011343 solid material Substances 0.000 claims description 2
- 239000007790 solid phase Substances 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- 239000003575 carbonaceous material Substances 0.000 abstract 1
- 238000011177 media preparation Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 241000195940 Bryophyta Species 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 206010020649 Hyperkeratosis Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 244000166071 Shorea robusta Species 0.000 description 1
- 235000015076 Shorea robusta Nutrition 0.000 description 1
- 241000736285 Sphagnum Species 0.000 description 1
- 240000003864 Ulex europaeus Species 0.000 description 1
- 235000010730 Ulex europaeus Nutrition 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cultivation Of Plants (AREA)
Abstract
Description
i La présente invention a pour objet la formulation d'une composition destinée à structurer mécaniquement, physiquement et chimiquement et à régénérer biologiquement les sols et/ou les supports de culture peu réactifs, en particulier ceux ayant perdu leur humus et/ou leur argile ou pouvant présenter une perméabilité excessive ou une dureté /compaction liée à l'agrégation des particules du sol et/ou étant constitué pour partie ou exclusivement par des matériaux peu réactifs comme par exemple dans leurs phases minérales : les pouzzolanes, les schistes expansés, les mousses de verre, etc. et/ou dans leurs phases organiques les tourbes, les io sphaignes, les écorces etc. et/ou les broyats de matière plastique etc. La présente invention a pour fonction de remodeler et de stabiliser l'assemblage des particules macroscopiques et microscopiques et de développer le processus biologique. Plus précisément l'invention se propose de modifier la structure existante 15 en apportant une composition constituée de minéraux stables modifiant les espaces poraux entre les particules du sol et/ou des supports de culture peu réactifs et des carbones organiques riches en microorganismes destinés à nourrir le sol et/ou les supports de culture peu réactifs. La composition peut être dopée en nutriments assimilables par les plantes. 20 Ces buts sont atteints par l'invention en ce sens qu'elle apporte une composition pouvant renfermer un ou plusieurs composants minéraux: un premier composant minéral choisi parmi les phyllosilicates à feuillets discontinus. un deuxième composant minéral choisi parmi les phyllosilicates 1:1 25 dioctaédrique. un troisième composant minéral choisi parmi les phyllosilicates 2:1 dioctaédrique stable à compensation potassique et de charge tétraédrique. un quatrième composant minéral choisi parmi les phyllosilicates gonflant à feuillets déséquilibrés compensés par le sodium ou par le calcium. un cinquième composant minéral choisi parmi les phyllosilicates 2:1 stable dioctaédrique. un sixième composant qui est une matière organique choisie entre les matières organiques d'origine végétale, les matières organiques d'origine 5 animale et leurs mélanges. Les quatre premiers composants sont de nature colloïdale. A l'état isolé, ces composants colloïdaux sont très fragiles et sensibles à l'érosion. Le cinquième composant est un assemblage microdivisé sous forme de plaquettes stables servant d'entretoises pour prévenir la compaction du sol io et /ou des supports peu réactifs. Le ou les cations qui constituent le sixième composant qui sont, par définition, chargés positivement, assurent une liaison stable entre les composants colloïdaux, chargés négativement, pour former avec eux un complexe argilo-humique. 15 L'effet régénérateur des cinq premiers composants de la composition, selon l'invention, met en jeu de façon durable quatre facteurs indispensables à la fertilité des sols et/ou des supports de culture peu réactifs à savoir : - La surface externe 20 - La surface interne - La capacité d'échange cationique - La capacité d'échange anionique, Le carbone organique riche en micro-organismes, issu de la matière organique, constitue le sixième composant. 25 De préférence, la composition, selon l'invention peut renfermer un ou plusieurs des cinq constituants minéraux associés au carbone organique en entrant dans la formule à des pourcentages étudiés et variables en poids. A titre d'exemple, la composition selon l'invention peut renfermer des 30 constituants minéraux dans la gamme des concentrations indiquées : - 1 à 70 % de phyllosilicates à feuillets discontinus - 1 à 70 % de phyllosilicates 1:1 dioctaédrique - 1 à 70 % de phyllosilicates 2:1 dioctaédrique stable à compensation potassique et de charge tétraédrique - 1 à 100 % de phyllosilicates gonflant à feuillets déséquilibrés compensés par le sodium ou par le calcium - 1 à 100 % de phyllosilicates 2:1 stable dioctaédrique. Ces phyllosilicates sont généralement associés séparément ou à plusieurs au sixième composant dans des pourcentages contrôlés. io Dans une forme d'exécution préférée le premier, le deuxième et le troisième composant pourront être mis en oeuvre séparément ou en mélange dans des proportions déterminées pour augmenter les réserves hydriques du sol et/ou des supports de culture peu réactifs sans influencer sa perméabilité, chacun d'eux libérant l'eau liquide à des pressions 15 osmotiques différentes. Dans une autre forme le quatrième composant peut être utilisé seul dans le but de rendre étanche une zone destinée à former un bassin de rétention, ou en mélange avec un ou plusieurs des trois premiers composants pour augmenter les réserves hydriques et réduire en même temps la 20 perméabilité du sol et/ou des supports de culture peu réactifs. Dans une autre formule, le cinquième composant, utilisé seul, régulera les propriétés mécaniques comme la plasticité et l'élasticité. Associé à un ou plusieurs des trois premiers composants il régule les mêmes propriétés et permet d'obtenir une augmentation des réserves hydriques disponibles. 25 En ce qui concerne le sixième composant, il provient avantageusement du compostage ou de la transformation : de matière organique d'origine végétale de matière organique d'origine animale La matière organique d'origine végétale renferme avantageusement 30 environ 50% d'humus. The present invention relates to the formulation of a composition for mechanically, physically and chemically structuring and biologically regenerating soils and / or low-reactive culture media, in particular those having lost their humus and / or clay or may have excessive permeability or hardness / compaction related to the aggregation of soil particles and / or consisting partly or exclusively of less reactive materials such as in their mineral phases: pozzolans, expanded shales, mosses glass, etc. and / or in their organic phases peat, sphagnum, bark etc. and / or shredded plastic material etc. The present invention has the function of reshaping and stabilizing the assembly of macroscopic and microscopic particles and of developing the biological process. More precisely, the invention proposes modifying the existing structure by providing a composition consisting of stable minerals modifying the porous spaces between the soil particles and / or the low reactive culture supports and the organic carbons rich in microorganisms intended to feed the plant. soil and / or low reactive culture media. The composition may be doped with nutrients that can be assimilated by the plants. These objects are achieved by the invention in that it provides a composition which can contain one or more mineral components: a first mineral component selected from discontinuous layer phyllosilicates. a second mineral component selected from 1: 1 dioctahedral phyllosilicates. a third mineral component selected from 2: 1 stable dioctahedral phyllosilicates with potassium compensation and tetrahedral charge. a fourth mineral component selected from the imbalanced fluffing phyllosilicates compensated by sodium or calcium. a fifth mineral component selected from dioctahedral stable 2: 1 phyllosilicates. a sixth component which is an organic material selected from organic materials of vegetable origin, organic materials of animal origin and mixtures thereof. The first four components are colloidal in nature. In the isolated state, these colloidal components are very fragile and sensitive to erosion. The fifth component is a microdivised assembly in the form of stable platelets serving as spacers to prevent soil compaction and / or poorly reactive carriers. The one or more cations which constitute the sixth component which are, by definition, positively charged, provide a stable bond between the colloidal components, negatively charged, to form with them a clay-humic complex. The regenerative effect of the first five components of the composition, according to the invention, involves, in a sustainable manner, four factors essential for soil fertility and / or low-reactive culture media, namely: the outer surface; The internal surface - The cation exchange capacity - The anion exchange capacity, The organic carbon rich in microorganisms, derived from organic matter, is the sixth component. Preferably, the composition according to the invention may contain one or more of the five inorganic constituents associated with organic carbon by entering into the formula at studied and variable percentages by weight. By way of example, the composition according to the invention may contain mineral constituents in the range of the concentrations indicated: 1 to 70% of discontinuous layer phyllosilicates 1 to 70% of 1: 1 dioctahedral phyllosilicates 1 to 70 % of 2: 1 stable dioctahedral phyllosilicates with potassium compensation and tetrahedral charge - 1 to 100% of imbalanced flaky phyllosilicates balanced by sodium or calcium - 1 to 100% dioctahedral stable 2: 1 phyllosilicates. These phyllosilicates are generally associated separately or in combination with the sixth component in controlled percentages. In a preferred embodiment, the first, second and third components may be used separately or in admixture in specific proportions to increase the soil's water reserves and / or low-reactivity culture media without affecting its permeability. each of them releasing liquid water at different osmotic pressures. In another form, the fourth component may be used alone to seal a zone for forming a retention pond, or in admixture with one or more of the first three components to increase water reserves and at the same time reduce soil permeability and / or low reactive culture media. In another formula, the fifth component, used alone, will regulate the mechanical properties such as plasticity and elasticity. Associated with one or more of the first three components, it regulates the same properties and makes it possible to obtain an increase in available water reserves. With regard to the sixth component, it advantageously comes from the composting or the transformation of: organic material of plant origin of organic material of animal origin The organic matter of plant origin advantageously contains about 50% of humus.
Les matières organiques d'origine végétale, qui sont de préférence, tamisées (par exemple à 5 mm) sont constituées de débris végétaux provenant essentiellement de feuillus, de paille et d'herbe. La part de débris végétaux provenant de plantes acidifiantes qui pourraient entrer éventuellement dans la formule du sixième composant ne doit pas excéder 20% car ces plantes (résineux, callunes, ajoncs ; etc.) forment une matière organique contenant un humus de mauvaise qualité. Les matières organiques animales comprises dans le sixième composant sont constituées de déjections d'animaux d'élevage, ainsi que ce sous produits et des produits d'origine animale. Ces matières organiques d'origine animales sont avantageuses car les compléments qu'elles apportent, en particulier l'azote, le potassium et le phosphore, équilibrent et accélèrent la formation de l'humus à partir des débris végétaux. Les mélanges de matière organique d'origines végétale et animale comprennent bien entendu le fumier éventuellement composté. Le choix qualitatif et quantitatif entre les différents constituants de la composition du structurant 15 dépend de son objectif et de sa destination. Selon une caractéristique de l'invention la matière organique d'origine végétale entrant dans la formule de la matière organique est riche en groupements polaires par rapport aux chaines paraffiniques tel que cela peut être mesuré en comparant les vibrations d'élongation des groupes 0-H à celles des groupes CH2 et CH3.Organic materials of vegetable origin, which are preferably screened (for example at 5 mm) consist of plant debris mainly from hardwoods, straw and grass. The part of plant debris from acidifying plants that could eventually enter the sixth component formula should not exceed 20% because these plants (conifers, calluses, gorse, etc.) form an organic matter containing a poor quality humus. The animal organic matter included in the sixth component consists of farm animal manure, as well as this by-product and animal products. These organic materials of animal origin are advantageous because the supplements they provide, especially nitrogen, potassium and phosphorus, balance and accelerate the formation of humus from plant debris. Mixtures of organic matter of plant and animal origins naturally include manure optionally composted. The qualitative and quantitative choice between the different constituents of the structurer's composition depends on its purpose and destination. According to one characteristic of the invention, the organic material of vegetable origin entering into the organic matter formula is rich in polar groups with respect to the paraffinic chains, as can be measured by comparing the O-H elongation vibrations. to those of CH2 and CH3 groups.
20 A l'intérieur des objectifs à atteindre toutes les combinaisons sont possibles pour répondre aux besoins liés à la répartition de la matière solide avec les espaces formant les vides. Les combinaisons sont adaptées aux différents types de culture envisagés et aux situations géographiques. La composition selon l'invention peut renfermer à des pourcentages variables et 25 convenus des composants minéraux et organiques déterminés en fonction de la répartition dans l'espace de la matière solide et des vides pour conditionner et stabiliser l'ensemble des propriétés mécaniques physiques, chimiques et biologiques fondamentales du sol et/ou des supports de culture peu réactifs et pour répondre à l'un au moins des objectifs suivants : - Augmenter les réserves hydriques de sol et/ou des supports de culture peu réactifs sans 30 influencer la porosité ou en réduisant la porosité, - Fermer la porosité en saturant durablement les pores pour constituer une phase solide continue, - Ouvrir la perméabilité sans influencer les réserves hydriques du sol et/ou des supports de culture peu réactifs, 35 - Ouvrir la perméabilité tout en augmentant les réserves hydriques du sol et/ou des supports de culture peu réactifs, - Rétablir conjointement les processus biologiques pour stabiliser les associations organominérales. 20 Within the objectives to be achieved, all combinations are possible to meet the needs related to the distribution of the solid matter with the spaces forming the voids. The combinations are adapted to the different types of culture envisaged and geographical situations. The composition according to the invention may contain at variable and agreed percentages of the inorganic and organic components determined as a function of the spatial distribution of the solid material and of the voids for conditioning and stabilizing all the physical, chemical, mechanical properties. and basic biology of the soil and / or low-reactive culture media and to meet at least one of the following objectives: - Increase soil water reserves and / or low-reactive culture media without influencing the porosity or in reducing porosity, - Close the porosity by permanently saturating the pores to form a continuous solid phase, - Open the permeability without influencing the water reserves of the soil and / or low-reactive culture media, - Open the permeability while increasing the permeability water reserves of the soil and / or low-reactive culture media, - Joint restoration of biological processes es to stabilize organomineral associations. 20
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1101590A FR2975693B1 (en) | 2011-05-23 | 2011-05-23 | PHYSICO-CHEMICAL STRUCTURANTS AND BIOLOGICAL REGENERATORS OF SOIL AND / OR LOW-REACTIVE CULTURE MEDIA |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1101590A FR2975693B1 (en) | 2011-05-23 | 2011-05-23 | PHYSICO-CHEMICAL STRUCTURANTS AND BIOLOGICAL REGENERATORS OF SOIL AND / OR LOW-REACTIVE CULTURE MEDIA |
Publications (2)
Publication Number | Publication Date |
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FR2975693A1 true FR2975693A1 (en) | 2012-11-30 |
FR2975693B1 FR2975693B1 (en) | 2016-01-22 |
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FR1101590A Active FR2975693B1 (en) | 2011-05-23 | 2011-05-23 | PHYSICO-CHEMICAL STRUCTURANTS AND BIOLOGICAL REGENERATORS OF SOIL AND / OR LOW-REACTIVE CULTURE MEDIA |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1979000261A1 (en) * | 1977-11-04 | 1979-05-17 | Mallinckrodt Inc | Composition and process for a granular plant nutrient |
BE901038A (en) * | 1984-11-12 | 1985-03-01 | Callut Francois | Soil improvement agents - prepd. by concentrating suspension of rocks from between permian and devonian rocks |
DE4340050A1 (en) * | 1992-11-27 | 1994-06-01 | James Tillinghast | Agent for regeneration of ecologically dead soil, e.g., polluted with lignite residues - comprsies mixt. of silica sand, organic colloid and clay mineral |
WO1996006060A1 (en) * | 1994-08-19 | 1996-02-29 | Maehl Dieter | Process for preparing, utilising and pelletizing organic and inorganic compounds in solid and liquid form, in particular compounds in biomass and biogenic sludges such as sewage sludge |
US20070119222A1 (en) * | 2002-10-16 | 2007-05-31 | Valencia Jose L M | Granulated fertilizer composed of micronutrients and clay |
WO2010058425A2 (en) * | 2008-11-20 | 2010-05-27 | Chetan Navnithlal Shah | Soil conditioner |
-
2011
- 2011-05-23 FR FR1101590A patent/FR2975693B1/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1979000261A1 (en) * | 1977-11-04 | 1979-05-17 | Mallinckrodt Inc | Composition and process for a granular plant nutrient |
BE901038A (en) * | 1984-11-12 | 1985-03-01 | Callut Francois | Soil improvement agents - prepd. by concentrating suspension of rocks from between permian and devonian rocks |
DE4340050A1 (en) * | 1992-11-27 | 1994-06-01 | James Tillinghast | Agent for regeneration of ecologically dead soil, e.g., polluted with lignite residues - comprsies mixt. of silica sand, organic colloid and clay mineral |
WO1996006060A1 (en) * | 1994-08-19 | 1996-02-29 | Maehl Dieter | Process for preparing, utilising and pelletizing organic and inorganic compounds in solid and liquid form, in particular compounds in biomass and biogenic sludges such as sewage sludge |
US20070119222A1 (en) * | 2002-10-16 | 2007-05-31 | Valencia Jose L M | Granulated fertilizer composed of micronutrients and clay |
WO2010058425A2 (en) * | 2008-11-20 | 2010-05-27 | Chetan Navnithlal Shah | Soil conditioner |
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FR2975693B1 (en) | 2016-01-22 |
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