FR2970425B1 - Traitement d'un flux gazeux contenant des mercaptans - Google Patents

Traitement d'un flux gazeux contenant des mercaptans

Info

Publication number
FR2970425B1
FR2970425B1 FR1150315A FR1150315A FR2970425B1 FR 2970425 B1 FR2970425 B1 FR 2970425B1 FR 1150315 A FR1150315 A FR 1150315A FR 1150315 A FR1150315 A FR 1150315A FR 2970425 B1 FR2970425 B1 FR 2970425B1
Authority
FR
France
Prior art keywords
treatment
gaseous flow
flow containing
containing mercaptans
mercaptans
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1150315A
Other languages
English (en)
Other versions
FR2970425A1 (fr
Inventor
Renaud Cadours
Didier Anglerot
Catherine Leroi
Francis Luck
Andrey Ryzhikov
Edouard Huguet
Robert Durand
Bernard Coq
Vasile Hulea
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
TotalEnergies Onetech SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Total SE
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Total SE, Ecole Nationale Superieure de Chimie de Montpellier ENSCM filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1150315A priority Critical patent/FR2970425B1/fr
Priority to PCT/EP2012/050448 priority patent/WO2012095494A1/fr
Publication of FR2970425A1 publication Critical patent/FR2970425A1/fr
Application granted granted Critical
Publication of FR2970425B1 publication Critical patent/FR2970425B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/04Raw material of mineral origin to be used; Pretreatment thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • B01D2255/504ZSM 5 zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR1150315A 2011-01-14 2011-01-14 Traitement d'un flux gazeux contenant des mercaptans Active FR2970425B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1150315A FR2970425B1 (fr) 2011-01-14 2011-01-14 Traitement d'un flux gazeux contenant des mercaptans
PCT/EP2012/050448 WO2012095494A1 (fr) 2011-01-14 2012-01-12 Traitement d'un flux gazeux contenant des mercaptans

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1150315A FR2970425B1 (fr) 2011-01-14 2011-01-14 Traitement d'un flux gazeux contenant des mercaptans

Publications (2)

Publication Number Publication Date
FR2970425A1 FR2970425A1 (fr) 2012-07-20
FR2970425B1 true FR2970425B1 (fr) 2017-04-07

Family

ID=44484094

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1150315A Active FR2970425B1 (fr) 2011-01-14 2011-01-14 Traitement d'un flux gazeux contenant des mercaptans

Country Status (2)

Country Link
FR (1) FR2970425B1 (fr)
WO (1) WO2012095494A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3006604B1 (fr) * 2013-06-11 2016-09-16 Total Sa Traitement energetiquement ameliore d'un flux gazeux contenant des mercaptans
FR3006603B1 (fr) * 2013-06-11 2015-06-05 Total Sa Procede de traitement d'un flux gazeux comprenant des mercaptans sans tamis d'adsorption
CN111804293B (zh) * 2020-05-26 2023-06-16 中琉科技有限公司 一种多孔氧化铝负载过渡金属的制备方法及其在脱除cos中的应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060118465A1 (en) * 2004-12-02 2006-06-08 The University Of Western Ontario Catalytic sulfur removal from a hydrocarbon stream
WO2007065765A1 (fr) * 2005-11-04 2007-06-14 Shell Internationale Research Maatschappij B.V. Procede de production d'un flux de gaz purifie
FR2896244B1 (fr) 2006-01-18 2013-04-12 Total Sa Procede de purification de melanges gazeux contenant des mercaptans et autres gaz acides
FR2896509B1 (fr) * 2006-01-24 2008-04-04 Inst Francais Du Petrole Procede de capture des mercaptans contenus dans un gaz naturel par concentration.
FR2937887B1 (fr) 2008-11-04 2011-04-29 Total Sa Procede de purification de melanges gazeux contenant des mercaptans et autres gaz acides

Also Published As

Publication number Publication date
WO2012095494A1 (fr) 2012-07-19
FR2970425A1 (fr) 2012-07-20

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Owner name: ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPE, FR

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