FR2946052B1 - PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE. - Google Patents

PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE.

Info

Publication number
FR2946052B1
FR2946052B1 FR0953531A FR0953531A FR2946052B1 FR 2946052 B1 FR2946052 B1 FR 2946052B1 FR 0953531 A FR0953531 A FR 0953531A FR 0953531 A FR0953531 A FR 0953531A FR 2946052 B1 FR2946052 B1 FR 2946052B1
Authority
FR
France
Prior art keywords
pressure
sensitive adhesive
polymer containing
adhesive polymer
tetrahydrofurfuryl methacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0953531A
Other languages
French (fr)
Other versions
FR2946052A1 (en
Inventor
Alain Riondel
Jean Luc Zeh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR0953531A priority Critical patent/FR2946052B1/en
Priority to PCT/FR2010/050951 priority patent/WO2010136697A1/en
Publication of FR2946052A1 publication Critical patent/FR2946052A1/en
Application granted granted Critical
Publication of FR2946052B1 publication Critical patent/FR2946052B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention a pour objet un polymère adhésif sensible à la pression contenant du carbone bioressourcé et présentant un bon compromis entre ses différentes caractéristiques applicatives. Plus particulièrement, l'invention concerne l'utilisation de méthacrylate de tétrahydrofurfuryle à une teneur allant de 0,1 à 5% pour améliorer la résistance au cisaillement de polymères adhésifs sensibles à la pression obtenus par polymérisation en émulsion d'un mélange de monomères comprenant de 40 à 95% en poids d'au moins un monomère (méth)acrylique ou vinylique capable de conduire à un homopolymère ayant une Tg inférieure ou égale à - 40°C, les monomères (méth)acryliques étant préférentiellement des composés bioressourcés.The present invention relates to a pressure-sensitive adhesive polymer containing bioresourced carbon and exhibiting a good compromise between its various application characteristics. More particularly, the invention relates to the use of tetrahydrofurfuryl methacrylate at a content ranging from 0.1 to 5% for improving the shear strength of pressure-sensitive adhesive polymers obtained by emulsion polymerization of a mixture of monomers comprising from 40 to 95% by weight of at least one (meth) acrylic or vinyl monomer capable of producing a homopolymer having a Tg less than or equal to - 40 ° C, the (meth) acrylic monomers preferably being bioresourced compounds.

FR0953531A 2009-05-28 2009-05-28 PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE. Expired - Fee Related FR2946052B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR0953531A FR2946052B1 (en) 2009-05-28 2009-05-28 PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE.
PCT/FR2010/050951 WO2010136697A1 (en) 2009-05-28 2010-05-18 Pressure-sensitive adhesive polymer containing tetrahydrofurfuryl methacrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0953531A FR2946052B1 (en) 2009-05-28 2009-05-28 PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE.

Publications (2)

Publication Number Publication Date
FR2946052A1 FR2946052A1 (en) 2010-12-03
FR2946052B1 true FR2946052B1 (en) 2011-05-27

Family

ID=41508038

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0953531A Expired - Fee Related FR2946052B1 (en) 2009-05-28 2009-05-28 PRESSURE - SENSITIVE ADHESIVE POLYMER CONTAINING TETRAHYDROFURFURYL METHACRYLATE.

Country Status (2)

Country Link
FR (1) FR2946052B1 (en)
WO (1) WO2010136697A1 (en)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58187476A (en) 1982-04-27 1983-11-01 Kanzaki Paper Mfg Co Ltd Pressure-sensitive adhesive composition
IE54465B1 (en) 1982-05-26 1989-10-25 Loctite Ltd Two-part self-indicating adhesive composition
DE3817452A1 (en) * 1988-05-21 1989-11-30 Basf Ag MELT-ADHESIVE GLUE ADHESIVE IN THE AIR WITH ULTRAVIOLET RAYS
FR2751974B1 (en) 1996-07-31 1998-09-18 Atochem Elf Sa PRESSURE SENSITIVE ADHESIVE POLYMERS
JP5006507B2 (en) 2004-01-30 2012-08-22 株式会社日本触媒 Acrylic acid production method
WO2005095320A1 (en) 2004-04-02 2005-10-13 Ciba Specialty Chemicals Water Treatments Limited Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids
FR2882053B1 (en) 2005-02-15 2007-03-23 Arkema Sa METHOD FOR DEHYDRATING GLYCEROL IN ACROLENE
FR2882052B1 (en) 2005-02-15 2007-03-23 Arkema Sa PROCESS FOR THE DEHYDRATION OF GLYCEROL IN ACROLEIN
NL1028411C2 (en) 2005-02-25 2006-08-29 Nat Starch & Chemical B V Pressure sensitive adhesive composition as well as methods for applying and preparing thereof.
TWI522092B (en) 2005-02-28 2016-02-21 贏創德固賽有限責任公司 Acrylic acid and water-absorbing polymer structures based upon renewable raw materials and process for their preparation
FR2884818B1 (en) 2005-04-25 2007-07-13 Arkema Sa PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL
FR2909999B1 (en) 2006-12-19 2009-04-03 Arkema France PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL

Also Published As

Publication number Publication date
WO2010136697A1 (en) 2010-12-02
FR2946052A1 (en) 2010-12-03

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Effective date: 20130131